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巯基化活性炭靶向捕获电子废弃物酸浸液中金离子 被引量:2
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作者 李敏 姚子威 +8 位作者 陈以頔 李德伟 邵家创 董浩 孟竹 杨利明 任伟 罗旭彪 邵鹏辉 《Science Bulletin》 SCIE EI CAS CSCD 2023年第11期1095-1099,M0003,共6页
电子废弃物中回收金兼具污染治理、资源循环双重目的,是环境高水平保护、经济高质量发展的必要要求.吸附法是湿法回收金属资源的有效方法,但含金电子废弃物的浸出液都呈现强酸性和强氧化性;目前从该体系中靶向捕捉金离子仍存在巨大挑战... 电子废弃物中回收金兼具污染治理、资源循环双重目的,是环境高水平保护、经济高质量发展的必要要求.吸附法是湿法回收金属资源的有效方法,但含金电子废弃物的浸出液都呈现强酸性和强氧化性;目前从该体系中靶向捕捉金离子仍存在巨大挑战.本文报道了一种巯基功能化的秸秆基活性炭,在强酸、强氧化性体系中实现了金离子的靶向捕获,其最大吸附容量可达5309 mg/g,选择性系数达到1.21×10^(6);吸附后的材料经煅烧得到金单质,其纯度高达99.9%.机理研究表明,巯基电位选择性诱导金离子优先还原,并促发了吸附-还原过程自发进行.由于量子尺寸效应,被还原的金簇在炭材料表面积累,处于“激发状态”的纳米金簇,将进一步诱导还原体系中金离子,呈现一种自促进作用.研究实现了复杂苛刻酸浸液中金元素的靶向回收,为电子废弃物高质循环利用提供了新思路. 展开更多
关键词 电子废弃物 强氧化性 污染治理 资源循环 循环利用 选择性系数 量子尺寸效应 金离子
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Efficient removal and recovery of Cd^(2+)from aqueous solutions by capacitive deionization(CDI)method using biochars 被引量:1
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作者 Zhao Song Lingyu Li +2 位作者 yidi chen Xiaoguang Duan Nanqi Ren 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第17期10-18,共9页
Biochars are low-cost and sustainable materials for environmental technologies.In this work,we pre-pared three biochars using pomelo peel(P-BC),algae(A-BC),and corncob(C-BC)to recover Cd^(2+)from wastewater via capaci... Biochars are low-cost and sustainable materials for environmental technologies.In this work,we pre-pared three biochars using pomelo peel(P-BC),algae(A-BC),and corncob(C-BC)to recover Cd^(2+)from wastewater via capacitive deionisation(CDI).A-BC possesses the highest amount of mesopores and nitro-gen functionality and attains the highest removal of Cd^(2+)via physical adsorption.For the electro-sorption capacity,C-BC and A-BC perform better capacitive removal of Cd^(2+)than P-BC due to the smaller charge-transfer and mass-transfer resistances.Also,this work investigated the impacts of surface morphology,cell voltage,NaCl,initial pH,and Cd^(2+)concentrations on Cd^(2+)capacitive removal and electrode regen-eration performances.The results indicated that A-BC and C-BC may be prospective materials for Cd^(2+)removal from wastewater by CDI.However,the presence of competing cations at high concentrations may influence the removal of Cd^(2+)at a low level,requiring the modification of A-BC and C-BC in future work. 展开更多
关键词 BIOCHAR Cd removal Capacitive deionisation Heavy metals SELECTIVITY
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Analysis of total reaction cross sections for deuterons on 1p-shell-nuclei
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作者 yidi chen Yun Zhang +5 位作者 JianLing Lou DanYang Pang YanLin Ye Wei Liu Ying Jiang Gen Li 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2018年第11期30-35,共6页
This study aims to analyze the differential cross sections(DCSs) of elastic scattering and total reaction cross sections(TRCSs) of the loosely-bound deuteron projectile impinging on 1 p-shell nuclei, such as9 Be,12 C,... This study aims to analyze the differential cross sections(DCSs) of elastic scattering and total reaction cross sections(TRCSs) of the loosely-bound deuteron projectile impinging on 1 p-shell nuclei, such as9 Be,12 C, and16 O, at incident energies ranging between10.6 and 171 MeV using the continuum discretized coupled channel(CDCC) method. By fitting the experimental data for the DCSs and TRCSs, energy-dependent renormalization factors for the real and imaginary parts of the nucleon-nucleus opticalmodel potentials deduced from the studies proposed by Koning and Delaroche(KD02) and by Watson, Singh, and Segel(WSS),are obtained. It is found that with the WSS potential, which was obtained specifically for 1 p-shell nuclei, the CDCC calculations can simultaneously reproduce both the DCSs and the TRCSs. The results show that it is important to choose appropriate optical potentials to describe deuteron-induced reactions. 展开更多
关键词 十字节 反应 氢核 原子核 DCS 连续统 试验性 正常化
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