Unraveling the heterogeneity of solid electrolyte interphase kinetically affecting lithium electrodeposition on lithium metal anode

The stability and uniformity of solid electrolyte interphase(SEI)are critical for clarifying the origin of capacity fade and safety issues for lithium metal anodes(LMA).However,understanding the interplay of SEI heterogeneity and Li electrodeposition is limited by the coupling of complex electrochemistry and mechanics processes.Herein,the correlation between the SEI failure behavior and Li deposition morphology is investigated through a quantitative electrochemical-mechanical model.The local deformation and stress of SEI during Li electrodeposition identify that the heterogeneous interface between different components first fails.Compared with the well-known mechanical strength,component uniformity plays the most important role in the initial SEI failure and uneven Li deposition,and a relative component uniformity(p>0.01)represents a proper balance to ensure the stability of the naturally heterogeneous SEI.Furthermore,the component regulation of SEI via the designed electrolyte experimentally demonstrates that improving component uniformity benefits SEI stability and the uniform Li electrodeposition for LMA,thereby increasing the capacity by~20%after 300 cycles.These fundamental understandings and proposed strategy can be not only used to guide the SEI optimization via the electrolyte regulation,but also extended to the rational designs of artificial SEI for high-performance LMA.

Bifunctional separator with high thermal stability and lithium dendrite inhibition toward high safety lithium-ion batteries

Coating inorganic ceramic particles on commercial polyolefin separators has been considered as an effective strategy to improve thermostability of separator.However,the introduction of the coating layer could induce pore blockage on the surface of the polyolefin separator.Herein,a ceramic composite layer that consists of alumina nanoparticles(n-Al_(2)O_(3))and halloysite nanotubes(HNTs)is designed to modify the polyethylene(PE)separator(the modified separator is denoted as AH-PE).The HNTs with hollow nanotubular structure construct a light skeleton and provide fast ion transport channels while Al_(2)O_(3)particles function as heat-resistant fillers to inhibit the shrinkage of the separator at elevated temperatures.The total thickness of AH-PE separator is only 14μm.Consequently,the mass increment of AH-PE separator decreases from 5 g/m^(2)to 3.5 g/m^(2),and the Gurley value reduces by 23%,compared with Al_(2)O_(3)coated PE separator(A-PE).Due to the synergistic effects of Al_(2)O_(3)and HNTs,AH-PE separator exhibits highly improved thermal stability(almost no shrinkage at 170℃for 30 min),high Li^(+)transference number(up to 0.47),and long cycle life of 450 h for Li|Li cells.Moreover,the Li Fe PO_(4)/Li cells assembled with AH-PE separators demonstrate improved rate capability and safety performance.

共结晶法制备具有多级增强光致发光的双羟萘酸分子晶体驱动器

高效的光致发光性能促进了晶体材料的发展.在本文中,我们通过引入溶剂分子报道了两例新的双羟萘酸多组分晶体.通过聚集诱导发射和共结晶诱导发射增强,双羟萘酸多组分晶体的绝对量子产率逐步增强,最高达52.99%,据我们所知,这是目前报道的最大值.此外,随着溶剂分子逃逸,该系统表现出温度依赖的荧光响应和热诱导的机械运动,包括跳跃、摆动、翻转、移动和旋转.本工作提出的引入共结晶组分实现材料发光性能逐级提高的方法对设计刺激响应型光学功能材料具有指导意义.

Adjoint-based robust optimization design of laminar flow wing under flight condition uncertainties

It is an inherent uncertainty problem that the application of laminar flow technology to the wing of large passenger aircraft is affected by flight conditions.In order to seek a more robust natural laminar flow control effect,it is necessary to develop an effective optimization design method.Meanwhile,attention must be given to the impact of crossflow(CF)instability brought on by the sweep angle.This paper constructs a robust optimization design framework based on discrete adjoint methods and non-intrusive polynomial chaos.Transition prediction is implemented by coupled Reynolds-Averaged Navier-Stokes(RANS)and simplified e^(N)method,which can consider both Tollmien-Schlichting(TS)wave and crossflow vortex instability.We have performed gradient enhancement processing on the general Polynomial Chaos Expansion(PCE),which is advantageous to reduce the computational cost of single uncertainty propagation.This processing takes advantage of the gradient information obtained by solving the coupled adjoint equations considering transition.The statistical moment gradient solution used for the robust optimization design also uses the derivatives of coupled adjoint equations.The framework is applied to the robust design of a 25°swept wing with infinite span in transonic flow.The uncertainty quantification and sensitivity analysis on the baseline wing shows that the uncertainty quantification method in this paper has high accuracy,and qualitatively reveals the factors that dominate in different flow field regions.By the robust optimization design,the mean and standard deviation of the drag coefficient can be reduced by 29%and 45%,respectively,and compared with the deterministic optimization design results,there is less possibility of forming shock waves under flight condition uncertainties.Robust optimization results illustrate the trade-off between the transition delay and the wave drag reduction.

Linewidth narrowing in free-space-running diamond Brillouin lasers

This study analyzes the linewidth narrowing characteristics of free-space-running Brillouin lasers and investigates the approaches to achieve linewidth compression and power enhancement simultaneously.The results show that the Stokes linewidth behavior in a free-space-running Brillouin laser cavity is determined by the phase diffusion of the pump and the technical noise of the system.Experimentally,a Stokes light output with a power of 22.5 W and a linewidth of 3.2 kHz was obtained at a coupling mirror reflectivity of 96%,which is nearly 2.5 times compressed compared with the linewidth of the pump(7.36 kHz).In addition,the theorical analysis shows that at a pump power of 60Wand a coupling mirror reflectivity of 96%,a Stokes output with a linewidth of 1.6 kHz and up to 80%optical conversion efficiency can be achieved by reducing the insertion loss of the intracavity.This study provides a promising technical route to achieve high-power ultra-narrow linewidth special wavelength laser radiations.

Penetrating remote sensing:Next-generation remote sensing for transparent earth

Building upon a unified theoretical framework(based on electromagnetic principles and considering interactions with the Earth’s subsurface materials),we consider a synergistic blend of high-spectral,electromagnetic,and diverse multi-physics techniques to introduce a new concept of penetrating remote sensing.By seamlessly amalgamating the interplay between multiple physical fields,penetrating remote sensing allows us to understand the Earth from its surface to its interior,effectively uncovering information about the planet’s internal composition.The outcome of this new concept encompasses detailed imagery and three-dimensional models,offering insights into the distribution,structure,properties,and dynamic behavior of materials residing within the Earth.It empowers us to delve into the profound layers of the Earth,unveiling its structural composition and evolutionary processes.This deeper understanding encompasses vital aspects concerning the Earth’s crust,mantle,and core,comprehending temperature distributions,flow patterns,and other crucial information that enriches our knowledge of the planet’s interior.

Wet-chemistry synthesis of cobalt carbide nanoparticles as highly active and stable electrocatalyst for hydrogen evolution reaction

转变金属碳化物(TMC ) nanomaterials 正在答应选择到磅，并且广泛地为电气化学的氢进化反应被用作异构的 electrocatalysts (她的) 。在这个工作，综合的导致溴化物的湿化学的策略公司 2 C nanoparticles (NP ) 被开发。如此的 NP 展出了高 electrocatalytic 活动(= 为 j = 的 181 mV 10

Transition prediction and sensitivity analysis for a natural laminar flow wing glove flight experiment

Natural laminar flow technology can significantly reduce aircraft aerodynamic drag and has excellent technical appeal for transport aircraft development with high aerodynamic efficiency.Accurately and efficiently predicting the laminar-to-turbulent transition and revealing the maintenance mechanism of laminar flow in a transport aircraft’s flight environment are significant for developing natural laminar flow wings.In this research,we carry out natural laminar flow flight experiments with different Reynolds numbers and angles of attack.The critical N-factor is calibrated as 9.0 using flight experimental data and linear stability theory from a statistical perspective,which makes sure that the relative error of transition location is within 5%.We then implement a simplified e^(N) transition prediction method with a similar accuracy compared with linear stability theory.We compute the sensitivity information for the simplified eN method with an adjointbased method,using the automatic differentiation technique(ADjoint).The impact of Reynolds numbers and pressure distributions on TS waves is analyzed using the sensitivity information.Through the sensitivity analysis,we find that:favorable pressure gradients not only suppress the development of TS waves but also decrease their sensitivity to Reynolds numbers;there exist three special regions which are very sensitive to the pressure distribution,and the sensitivity decreases as the local favorable pressure gradient increases.The proposed sensitivity analysis method enables robust natural laminar flow wings design.

Hyperelastic model for polyacrylamide‑gelatin double network shape‑memory hydrogels

A shape-memory double network hydrogel consists of two polymer networks:a chemically crosslinked primary network that is responsible for the permanent shape and a physically crosslinked secondary network that is used to fix the temporary shapes.The formation/melting transition of the secondary network serves as an effective mechanism for the double network hydrogel’s shape-memory effect.When the crosslinks in the secondary network are dissociated by applying an external stimulus,only the primary network is left to support the load.When the secondary network is re-formed by removing the stimulus,both the primary and secondary networks support the load.In the past,models have been developed for the constitutive behaviors of double network hydrogels,but the model of shape-memory double network hydrogels is still lacking.This work aims to build a constitutive model for the polyacrylamide-gelatin double network shape-memory hydrogel developed in our previous work.The model is first calibrated by experimental data of the double network shape-memory hydrogel under uniaxial loading and then employed to predict the shape-fixing performance of the hydrogel.The model is also implemented into a three-dimension finite element code and utilized to simulate the shape-memory behavior of the double network hydrogel with inhomogeneous deformations related to applications.