To investigate the seismic performance of hollow reinforced concrete (RC) bridge columns of rectangular cross section under constant axial load and cyclically biaxial bending, five specimens were tested. A parametri...To investigate the seismic performance of hollow reinforced concrete (RC) bridge columns of rectangular cross section under constant axial load and cyclically biaxial bending, five specimens were tested. A parametric study is carried out for different axial load ratios, longitudinal reinforcement ratios and lateral reinforcement ratios. The experimental results showed that all tested specimens failed in the flexural failure mode and their ultimate performance was dominated by flexural capacity, which is represented by the rupture/buckling of tensile longitudinal rebars at the bottom of the bridge columns. Biaxial force and displacement hysteresis loops showed significant stiffness and strength degradations, and the pinching effect and coupling interaction effect of both directions severely decrease the structural seismic resistance. However, the measured ductility coefficient varying from 3.5 to 5.7 and the equivalent viscous damping ratio varying from 0.19 and 0.26 can meet the requirements of the seismic design. The hollow RC rectangular bridge columns with configurations of lateral reinforcement in this study have excellent performance under bidirectional earthquake excitations, and may be considered as a substitute for current hollow RC rectangular section configurations described in the Guideline for Seismic Design of Highway Bridges (JTG/T B02-01-2008). The length of the plastic hinge region was found to approach one sixth of the hollow RC rectangular bridge column height for all specimen columns, and it was much less than those specified in the current JTG/T. Thus, the length of the plastic hinge region is more concentrated for RC rectangular hollow bridge columns.展开更多
Use of stainless reinforcing steel (SRS) in reinforced concrete (RC) structures is a promising solution to corrosion issues. However, for SRS to be used in seismic applications, several mechanical properties need ...Use of stainless reinforcing steel (SRS) in reinforced concrete (RC) structures is a promising solution to corrosion issues. However, for SRS to be used in seismic applications, several mechanical properties need to be investigated. These include specified and actual yield strengths, tensile strengths, uniform elongations and low-cycle fatigue behavior. Three types of SRSs (Talley S24100, Talley 316LN and Talley 2205) were tested and the results are reported in this paper. They were compared with the properties of A706 carbon reinforcing steel (RS), which is typical for seismic applications, and MMFX II, which is a high strength, corrosion resistant RS. Low-cycle fatigue tests of the RS coupons were conducted under strain control with constant amplitude to obtain strain life models of the steels. Test results show that the SRSs have slightly lower moduli of elasticity, higher uniform elongations before necking, and better low-cycle fatigue performance than A706 and MMFX II. All five types of RSs tested satisfy the requirements of the ACI 318 code on the lower limit of the tensile to yield strength ratio. Except Talley 2205, the other four types of RSs investigated meet the ACI 318 requirement that the actual yield strength does not exceed the specified yield strength by more than 18 ksi (124 MPa). Among the three types of SRSs tested, Talley S24100 possesses the highest uniform elongation before necking, and the best low-cycle fatigue performance.展开更多
Covalent organic polymers(COPs)have emerged as a unique class of luminescent polymers with pre-designed quasi-ordered architectures.However,their layered stacks and limited solubility preclude further processing for l...Covalent organic polymers(COPs)have emerged as a unique class of luminescent polymers with pre-designed quasi-ordered architectures.However,their layered stacks and limited solubility preclude further processing for large-scale applications in devices,especially optoelectronic equipment.Herein,a universal strategy to adjust the electron donor–acceptor(D-A)moieties of the building blocks in COPs is proposed,achieved by in situ charge exfoliation of COP blocks into few-layer true solutions in(Lewis)acid and base media.The electron D-A moieties of the building blocks endow the COPs with the ability to accept or donate electrons,by altering the electron cloud distribution as well as the relative energy levels of the frontier molecular orbitals.The resultant soluble COPs can easily be processed into a uniform film by solution processing via the spin-coat method.The obtained COP-N achieves efficient and stable perovskite electroluminescence as a novel hole injection material on indium tin oxide,and the operating lifetime for a perovskite quantum dot light-emitting diodes device exceeds that of a poly(ethylene dioxythiophene):polystyrene sulphonate counterpart.This straightforward electronic regulation strategy provides a new avenue for the rational synthesis of processable reticular molecular polymers for practical electronic devices.展开更多
Electrocoagulation(EC)has been widely used to treat the heavymetal wastewater in industry.A novel process of sinusoidal alternating current electrocoagulation(SACC)is adopted to remove Ni2+in wastewater in this study....Electrocoagulation(EC)has been widely used to treat the heavymetal wastewater in industry.A novel process of sinusoidal alternating current electrocoagulation(SACC)is adopted to remove Ni2+in wastewater in this study.The morphology of precipitates and the distribution of the main functional iron configurations were investigated.Ferron timed complex spectroscopy can identify the monomeric iron configurations[Fe(a)],oligomeric iron configurations[Fe(b)]and polymeric iron configurations[Fe(c)].The optimal operating conditions of SACC process were determined through single-factor experiments.The maximum Ni2+removal efficiency[Re(Ni^(2+))]was achieved under the conditions of pH0=7,current density(j)=7 A/m^(2),electrolysis time(t)=25 min,c0(Ni^(2+))=100 mg/L.At pH=7,the proportion of Fe(b)and Fe(c)in the system was 50.4 at.% and 23.1 at.%,respectively.In the SACC process,Fe(b)and Fe(c)are themain iron configurations in solution,while Fe(c)are the vastmajority of the iron configurations in the direct current electrocoagulation(DCC)process.Re(Ni2+)is 99.56% for SACC and 98.75% for DCC under the same optimum conditions,respectively.The precipitates produced by SACC have a high proportion of Fe(b)configurations with sphericalα-FeOOH andγ-FeOOH structures which contain abundant hydroxyl groups.Moreover,it is demonstrated that Fe(b)has better adsorption capacity than Fe(c)through adsorption experiments of methyl orange(MO)dye.Fe(a)configurations in the homogeneous solution had no effect on the removal of nickel.展开更多
The high-strength Al-Zn-Mg-Cu alloy provides much better dent resistance and weight-reduction potential compared to the conventional Al alloys used for the automobile body panels.However,natural ageing(NA)significantl...The high-strength Al-Zn-Mg-Cu alloy provides much better dent resistance and weight-reduction potential compared to the conventional Al alloys used for the automobile body panels.However,natural ageing(NA)significantly reduces the formability of Al-Zn-Mg-Cu alloy.The reversion of natural ageing has been systematically investigated by hardness test,tensile test,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).Substantial reversion of natural ageing and thus hardness decrease occurs immediately upon thermal treatment at 120–210℃in an Al-Zn-Mg-Cu alloy.Although the hardness of the most reverted state decreases with increasing temperature,the lowest hardness is still higher than the as-quenched state by 30 HV.As revealed by the complementary DSC and TEM observations,this is ascribed to the synchronization of the dissolution and the re-precipitation of the solutes in the NA clusters during reversion ageing.Reversion at 180–210℃for less than 30 s leads to a hardness decline of 40 HV.The hardening kinetics during NA after reversion is slower than that during first-time NA due to the reduced vacancy concentration.Artificial ageing at 180℃for 30 min after secondary NA of less than 24 h induces intensive precipitation of plate-like pre-ηphases and a giant strength increase of 188–204 MPa.Potential use of high strength Al-Zn-Mg-Cu alloy in automobile body panels could be realized by appropriate reversion treatment improving the formability and the quick bake hardening response.展开更多
The ability of climate models to correctly reproduce clouds and the radiative effects of clouds is vitally important in climate simulations and projections.In this study,simulations of the shortwave cloud radiative ef...The ability of climate models to correctly reproduce clouds and the radiative effects of clouds is vitally important in climate simulations and projections.In this study,simulations of the shortwave cloud radiative effect(SWCRE)using the Chinese Academy of Meteorological Sciences Climate System Model(CAMS-CSM)are evaluated.The relationships between SWCRE and dynamic–thermodynamic regimes are examined to understand whether the model can simulate realistic processes that are responsible for the generation and maintenance of stratus clouds.Over eastern China,CAMS-CSM well simulates the SWCRE climatological state and stratus cloud distribution.The model captures the strong dependence of SWCRE on the dynamic conditions.Over the marine boundary layer regions,the simulated SWCRE magnitude is weaker than that in the observations due to the lack of low-level stratus clouds in the model.The model fails to simulate the close relationship between SWCRE and local stability over these regions.A sensitivity numerical experiment using a specifically designed parameterization scheme for the stratocumulus cloud cover confirms this assertion.Parameterization schemes that directly depict the relationship between the stratus cloud amount and stability are beneficial for improving the model performance.展开更多
A strategy for evaluating a global shallow water model based on aspects of kinetic energy spectra and nonlinear vorticity dynamics is proposed in this study.The kinetic energy spectra and nonlinear vorticity dynamics ...A strategy for evaluating a global shallow water model based on aspects of kinetic energy spectra and nonlinear vorticity dynamics is proposed in this study.The kinetic energy spectra and nonlinear vorticity dynamics of a recently developed global shallow water model on an unstructured mesh are evaluated in comparison with the benchmark solutions from a global high-resolution spectral model.The results show that the kinetic energy spectra,the rotational and divergent components,the stationary and transient components,and the nonlinear spectral fluxes of the developed shallow water model agree well with those generated by the reference model.In addition,the influence of different flux operators for transporting the potential vorticity(PV)is assessed specifically.It is indicated that the second-order flux operator leads to a spurious increase in the kinetic energy at the tail of the spectrum,whereas the upwind third-order flux operator does not support this behavior owing to implicit numerical diffusion.Moreover,the nonlinear vorticity dynamics is studied by using colliding modons.It is found that the grid-point model maintains the symmetrical pattern of vortices,and generates similar kinetic energy spectra and nonlinear spectral fluxes to the reference model.The evaluation provides a reference for assessing the shallow water model in terms of nonlinear dynamics,and the developed global shallow water model presents a good example.展开更多
基金National Natural Science Foundation of China under Grant No.51178008,No.50908005National Basic Research Program of China under Grant No.2011CB013600+1 种基金the International Cooperative Project of NSFC-JST under Grant No.51021140003a Joint Research Project between the Beijing University of Technology and the University at Buffalo with Partial Support from the U.S.Federal Highway Administration under Contract No.DTFH61-07-C-00020
文摘To investigate the seismic performance of hollow reinforced concrete (RC) bridge columns of rectangular cross section under constant axial load and cyclically biaxial bending, five specimens were tested. A parametric study is carried out for different axial load ratios, longitudinal reinforcement ratios and lateral reinforcement ratios. The experimental results showed that all tested specimens failed in the flexural failure mode and their ultimate performance was dominated by flexural capacity, which is represented by the rupture/buckling of tensile longitudinal rebars at the bottom of the bridge columns. Biaxial force and displacement hysteresis loops showed significant stiffness and strength degradations, and the pinching effect and coupling interaction effect of both directions severely decrease the structural seismic resistance. However, the measured ductility coefficient varying from 3.5 to 5.7 and the equivalent viscous damping ratio varying from 0.19 and 0.26 can meet the requirements of the seismic design. The hollow RC rectangular bridge columns with configurations of lateral reinforcement in this study have excellent performance under bidirectional earthquake excitations, and may be considered as a substitute for current hollow RC rectangular section configurations described in the Guideline for Seismic Design of Highway Bridges (JTG/T B02-01-2008). The length of the plastic hinge region was found to approach one sixth of the hollow RC rectangular bridge column height for all specimen columns, and it was much less than those specified in the current JTG/T. Thus, the length of the plastic hinge region is more concentrated for RC rectangular hollow bridge columns.
基金Federal Highway Administration Under Contract No.DTFH61-07-R-00121International Molybdenum Association,Nickel Institute,Talley Metals-A Carpenter Company,North American Stainless and Salit Specialty Steel Through MCEER,University at Buffalo
文摘Use of stainless reinforcing steel (SRS) in reinforced concrete (RC) structures is a promising solution to corrosion issues. However, for SRS to be used in seismic applications, several mechanical properties need to be investigated. These include specified and actual yield strengths, tensile strengths, uniform elongations and low-cycle fatigue behavior. Three types of SRSs (Talley S24100, Talley 316LN and Talley 2205) were tested and the results are reported in this paper. They were compared with the properties of A706 carbon reinforcing steel (RS), which is typical for seismic applications, and MMFX II, which is a high strength, corrosion resistant RS. Low-cycle fatigue tests of the RS coupons were conducted under strain control with constant amplitude to obtain strain life models of the steels. Test results show that the SRSs have slightly lower moduli of elasticity, higher uniform elongations before necking, and better low-cycle fatigue performance than A706 and MMFX II. All five types of RSs tested satisfy the requirements of the ACI 318 code on the lower limit of the tensile to yield strength ratio. Except Talley 2205, the other four types of RSs investigated meet the ACI 318 requirement that the actual yield strength does not exceed the specified yield strength by more than 18 ksi (124 MPa). Among the three types of SRSs tested, Talley S24100 possesses the highest uniform elongation before necking, and the best low-cycle fatigue performance.
基金This work was supported by the National Key Research and Devel-opment Program of China(2019YFA0210300)the NSF of China(21922802+4 种基金22220102003)the Beijing Natural Science Foundation(JQ19007)Talent cultivation of State Key Laboratory of Organic-Inorganic Composites“Double-First-Class”construction projects(XK180301,XK1804-02)Distinguished Scientist Program at BUCT(buctylkxj02).
文摘Covalent organic polymers(COPs)have emerged as a unique class of luminescent polymers with pre-designed quasi-ordered architectures.However,their layered stacks and limited solubility preclude further processing for large-scale applications in devices,especially optoelectronic equipment.Herein,a universal strategy to adjust the electron donor–acceptor(D-A)moieties of the building blocks in COPs is proposed,achieved by in situ charge exfoliation of COP blocks into few-layer true solutions in(Lewis)acid and base media.The electron D-A moieties of the building blocks endow the COPs with the ability to accept or donate electrons,by altering the electron cloud distribution as well as the relative energy levels of the frontier molecular orbitals.The resultant soluble COPs can easily be processed into a uniform film by solution processing via the spin-coat method.The obtained COP-N achieves efficient and stable perovskite electroluminescence as a novel hole injection material on indium tin oxide,and the operating lifetime for a perovskite quantum dot light-emitting diodes device exceeds that of a poly(ethylene dioxythiophene):polystyrene sulphonate counterpart.This straightforward electronic regulation strategy provides a new avenue for the rational synthesis of processable reticular molecular polymers for practical electronic devices.
基金supported by the National Natural Science Foundation of China (No. 51974115)the National Natural Science Foundation of Hunan Province of China (No. 2020JJ4145)the Key R & D Plan Project of Changsha (No. 2021-440)
文摘Electrocoagulation(EC)has been widely used to treat the heavymetal wastewater in industry.A novel process of sinusoidal alternating current electrocoagulation(SACC)is adopted to remove Ni2+in wastewater in this study.The morphology of precipitates and the distribution of the main functional iron configurations were investigated.Ferron timed complex spectroscopy can identify the monomeric iron configurations[Fe(a)],oligomeric iron configurations[Fe(b)]and polymeric iron configurations[Fe(c)].The optimal operating conditions of SACC process were determined through single-factor experiments.The maximum Ni2+removal efficiency[Re(Ni^(2+))]was achieved under the conditions of pH0=7,current density(j)=7 A/m^(2),electrolysis time(t)=25 min,c0(Ni^(2+))=100 mg/L.At pH=7,the proportion of Fe(b)and Fe(c)in the system was 50.4 at.% and 23.1 at.%,respectively.In the SACC process,Fe(b)and Fe(c)are themain iron configurations in solution,while Fe(c)are the vastmajority of the iron configurations in the direct current electrocoagulation(DCC)process.Re(Ni2+)is 99.56% for SACC and 98.75% for DCC under the same optimum conditions,respectively.The precipitates produced by SACC have a high proportion of Fe(b)configurations with sphericalα-FeOOH andγ-FeOOH structures which contain abundant hydroxyl groups.Moreover,it is demonstrated that Fe(b)has better adsorption capacity than Fe(c)through adsorption experiments of methyl orange(MO)dye.Fe(a)configurations in the homogeneous solution had no effect on the removal of nickel.
基金financial support from National Natural Science Foundation of China(Nos.U2032117,51675538,11872380)the National Key R&D Program of China(No.2017YFB0306300)+3 种基金Natural Science Foundation of Hunan Province(No.2018JJ3655)National Science and Technology Major Project(No.2017ZX04005001)the Fundamental Research Funds for the Central Universities of Central South University(2021zzts0638)the Innovation fund of National commercial aircraft manufacturing engineering technology centre(No.COMAC-SFGS-2019-4284)。
文摘The high-strength Al-Zn-Mg-Cu alloy provides much better dent resistance and weight-reduction potential compared to the conventional Al alloys used for the automobile body panels.However,natural ageing(NA)significantly reduces the formability of Al-Zn-Mg-Cu alloy.The reversion of natural ageing has been systematically investigated by hardness test,tensile test,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).Substantial reversion of natural ageing and thus hardness decrease occurs immediately upon thermal treatment at 120–210℃in an Al-Zn-Mg-Cu alloy.Although the hardness of the most reverted state decreases with increasing temperature,the lowest hardness is still higher than the as-quenched state by 30 HV.As revealed by the complementary DSC and TEM observations,this is ascribed to the synchronization of the dissolution and the re-precipitation of the solutes in the NA clusters during reversion ageing.Reversion at 180–210℃for less than 30 s leads to a hardness decline of 40 HV.The hardening kinetics during NA after reversion is slower than that during first-time NA due to the reduced vacancy concentration.Artificial ageing at 180℃for 30 min after secondary NA of less than 24 h induces intensive precipitation of plate-like pre-ηphases and a giant strength increase of 188–204 MPa.Potential use of high strength Al-Zn-Mg-Cu alloy in automobile body panels could be realized by appropriate reversion treatment improving the formability and the quick bake hardening response.
基金Supported by the National Key Research and Development Program of China(2017YFC1502202 and 2016YFA0602101)National Natural Science Foundation of China(41875135 and 91637210)
文摘The ability of climate models to correctly reproduce clouds and the radiative effects of clouds is vitally important in climate simulations and projections.In this study,simulations of the shortwave cloud radiative effect(SWCRE)using the Chinese Academy of Meteorological Sciences Climate System Model(CAMS-CSM)are evaluated.The relationships between SWCRE and dynamic–thermodynamic regimes are examined to understand whether the model can simulate realistic processes that are responsible for the generation and maintenance of stratus clouds.Over eastern China,CAMS-CSM well simulates the SWCRE climatological state and stratus cloud distribution.The model captures the strong dependence of SWCRE on the dynamic conditions.Over the marine boundary layer regions,the simulated SWCRE magnitude is weaker than that in the observations due to the lack of low-level stratus clouds in the model.The model fails to simulate the close relationship between SWCRE and local stability over these regions.A sensitivity numerical experiment using a specifically designed parameterization scheme for the stratocumulus cloud cover confirms this assertion.Parameterization schemes that directly depict the relationship between the stratus cloud amount and stability are beneficial for improving the model performance.
基金Supported by the National Key Research and Development Program of China(2017YFC1502202)National Natural Science Foundation of China(41875135)Basic Research and Operation Founds of Chinese Academy of Meteorological Sciences(2018Y004).
文摘A strategy for evaluating a global shallow water model based on aspects of kinetic energy spectra and nonlinear vorticity dynamics is proposed in this study.The kinetic energy spectra and nonlinear vorticity dynamics of a recently developed global shallow water model on an unstructured mesh are evaluated in comparison with the benchmark solutions from a global high-resolution spectral model.The results show that the kinetic energy spectra,the rotational and divergent components,the stationary and transient components,and the nonlinear spectral fluxes of the developed shallow water model agree well with those generated by the reference model.In addition,the influence of different flux operators for transporting the potential vorticity(PV)is assessed specifically.It is indicated that the second-order flux operator leads to a spurious increase in the kinetic energy at the tail of the spectrum,whereas the upwind third-order flux operator does not support this behavior owing to implicit numerical diffusion.Moreover,the nonlinear vorticity dynamics is studied by using colliding modons.It is found that the grid-point model maintains the symmetrical pattern of vortices,and generates similar kinetic energy spectra and nonlinear spectral fluxes to the reference model.The evaluation provides a reference for assessing the shallow water model in terms of nonlinear dynamics,and the developed global shallow water model presents a good example.