Realizing real-time monitoring of physiological signals is vital for preventing and treating chronic diseases in elderly individuals. However,wearable sensors with low power consumption and high sensitivity to both we...Realizing real-time monitoring of physiological signals is vital for preventing and treating chronic diseases in elderly individuals. However,wearable sensors with low power consumption and high sensitivity to both weak physiological signals and large mechanical stimuli remain challenges.Here, a flexible triboelectric patch(FTEP) based on porous-reinforcement microstructures for remote health monitoring has been reported. The porousreinforcement microstructure is constructed by the self-assembly of silicone rubber adhering to the porous framework of the PU sponge. The mechanical properties of the FTEP can be regulated by the concentrations of silicone rubber dilution. For pressure sensing, its sensitivity can be effectively improved fivefold compared to the device with a solid dielectric layer, reaching 5.93 kPa^(-1) under a pressure range of 0–5 kPa. In addition, the FTEP has a wide detection range up to 50 kPa with a sensitivity of 0.21 kPa^(-1). The porous microstructure makes the FTEP ultra-sensitive to external pressure, and the reinforcements endow the device with a greater deformation limit in a wide detection range. Finally, a novel concept of the wearable Internet of Healthcare(Io H) system for real-time physiological signal monitoring has been proposed, which could provide real-time physiological information for ambulatory personalized healthcare monitoring.展开更多
Continuous deforming always leads to the performance degradation of a flexible triboelectric nanogenerator due to the Young’s modulus mismatch of different functional layers.In this work,we fabricated a fiber-shaped ...Continuous deforming always leads to the performance degradation of a flexible triboelectric nanogenerator due to the Young’s modulus mismatch of different functional layers.In this work,we fabricated a fiber-shaped stretchable and tailorable triboelectric nanogenerator(FST-TENG)based on the geometric construction of a steel wire as electrode and ingenious selection of silicone rubber as triboelectric layer.Owing to the great robustness and continuous conductivity,the FST-TENGs demonstrate high stability,stretchability,and even tailorability.For a single device with ~6 cm in length and ~3 mm in diameter,the open-circuit voltage of ~59.7 V,transferred charge of ~23.7 nC,short-circuit current of ~2.67 μA and average power of ~2.13 μW can be obtained at 2.5 Hz.By knitting several FST-TENGs to be a fabric or a bracelet,it enables to harvest human motion energy and then to drive a wearable electronic device.Finally,it can also be woven on dorsum of glove to monitor the movements of gesture,which can recognize every single finger,different bending angle,and numbers of bent finger by analyzing voltage signals.展开更多
Progress has been developed in harvesting lowfrequency and irregular blue energy using a triboelectric–electromagnetic hybrid generator in recent years. However,the design of the high-efficiency, mechanically durable...Progress has been developed in harvesting lowfrequency and irregular blue energy using a triboelectric–electromagnetic hybrid generator in recent years. However,the design of the high-efficiency, mechanically durable hybrid structure is still challenging. In this study, we report a fully packaged triboelectric–electromagnetic hybrid generator(TEHG), in which magnets were utilized as the trigger to drive contact–separation-mode triboelectric nanogenerators(CS-TENGs) and coupled with copper coils to operate rotary freestanding-mode electromagnetic generators(RF-EMGs). The magnet pairs that produce attraction were used to transfer the external mechanical energy to the CS-TENGs, and packaging of the CS-TENGpart was achieved to protect it from the ambient environment. Under a rotatory speed of 100 rpm, the CS-TENGs enabled the TEHG to deliver an output voltage, current,and average power of 315.8 V, 44.6 μA, and ~ 90.7 μW,and the output of the RF-EMGs was 0.59 V, 1.78 m A, and 79.6 μW, respectively. The cylinder-like structure made the TEHG more easily driven by water flow and demonstrated to work as a practical power source to charge commercial capacitors. It can charge a 33μF capacitor from 0 to 2.1 V in 84 s, and the stored energy in the capacitor can drive an electronic thermometer and form a self-powered water-temperature sensing system.展开更多
Photoelectrochemical hydrogen generation is a promising approach to address the environmental pollution and energy crisis.In this work,we present a hybridized mechanical and solar energy-driven selfpowered hydrogen pr...Photoelectrochemical hydrogen generation is a promising approach to address the environmental pollution and energy crisis.In this work,we present a hybridized mechanical and solar energy-driven selfpowered hydrogen production system.A rotatory disc-shaped triboelectric nanogenerator was employed to harvest mechanical energy from water and functions as a su cient external power source.WO3/BiVO4 heterojunction photoanode was synthesized in a PEC water-splitting cell to produce H2.After transformation and rectification,the peak current reaches 0.1 m A at the rotation speed of 60 rpm.In this case,the H2 evolution process only occurs with sunlight irradiation.When the rotation speed is over 130 rpm,the peak photocurrent and peak dark current have nearly equal value.Direct electrolysis of water is almost simultaneous with photoelectrocatalysis of water.It is worth noting that the hydrogen production rate increases to 5.45 and 7.27μL min-1 without or with light illumination at 160 rpm.The corresponding energy conversion e ciency is calculated to be 2.43%and 2.59%,respectively.All the results demonstrate such a self-powered system can successfully achieve the PEC hydrogen generation,exhibiting promising possibility of energy conversion.展开更多
Projection-based embedded discrete fracture model(pEDFM)is an effective numerical model to handle the flow in fractured reservoirs,with high efficiency and strong generalization of flow models.However,this paper point...Projection-based embedded discrete fracture model(pEDFM)is an effective numerical model to handle the flow in fractured reservoirs,with high efficiency and strong generalization of flow models.However,this paper points out that pEDFM fails to handle flow barriers in most cases,and identifies the physical projection configuration of fractures is a key step in pEDFM.This paper presents and proves the equivalence theorem,which explains the geometric nature of physical projection configurations of fractures,that is,the projection configuration of a fracture being physical is equivalent to it being topologically homeomorphic to the fracture,by analyzing the essence of pEDFM.Physical projection configurations of fractures may be rigorously established based on this theorem,allowing pEDFM to obtain physical numerical results for many flow models,particularly those with flow barriers.Furthermore,a natural idea emerges of employing flow barriers to flexibly‘cut’the formation to quickly handle the flow problems in the formation with complex geological conditions,and several numerical examples are implemented to test this idea and application of the improved pEDFM.展开更多
The urgent demand for portable electronics has promoted the development of high-efficienc)9 sustainable, and even stretchable self-charging power sources. In this work, we propose a flexible self-charging power unit ...The urgent demand for portable electronics has promoted the development of high-efficienc)9 sustainable, and even stretchable self-charging power sources. In this work, we propose a flexible self-charging power unit based on folded carbon (FC) paper for harvesting mechanical energy from human motion and power portable electronics. The present unit mainly consists of a triboelectric nanogenerator (FC-TENG) and a supercapacitor (FC-SC), both based on folded carbon paper, as energy harvester and storage device, respectively. This favorable geometric design provides the high Young's modulus carbon paper with excellent stretchability and enables the power unit to work even under severe deformations, such as bending, twisting, and rolling. In addition, the tensile strain can be maximized by tuning the folding angle of the triangle-folded carbon paper. Moreover, the waterproof property of the packaged device make it washable, protect it from human sweat, and enable it to work in harsh environments. Finally, the as-prepared self-charging power unit was tested by placing it on the human body to harvest mechanical energy from hand tapping, foot treading, and arm touching, successfully powering an electronic watch. This work demonstrates the impressive potential of stretchable self-charging power units, which will further promote the development of high Young's modulus materials for wearable/portable electronics.展开更多
Energy collection ways using solar energy,wave,wind,or mechanical energy have attracted widespread attention for small selfpowered electronic devices with low power consumption,such as sensors,wearable devices,electro...Energy collection ways using solar energy,wave,wind,or mechanical energy have attracted widespread attention for small selfpowered electronic devices with low power consumption,such as sensors,wearable devices,electronic skin,and implantable devices.Among them,triboelectric nanogenerator(TENG)operated by coupling effect of triboelectrification and electrostatic induction has gradually gained prominence due to its advantages such as low cost,lightweight,high degree of freedom in material selection,large power,and high applicability.The device with a single energy exchange mechanism is limited by its conversion efficiency and work environment and cannot achieve the maximum conversion of energy.Thus,this article reviews the research status of different types of hybrid generators based on TENG in recent years.Hybrid energy generators will improve the output performance though the integration of different energy exchange methods,which have an excellent application prospect.From the perspective of energy complementation,it can be divided into harvesting mechanical energy by various principles,combining with harvesters of other clean energy,and converting mechanical energy or various energy sources into hydrogen energy.For integrating multitype energy harvesters,mechanism of single device and structural design of integrated units for different application scenarios are summarized.The expanding energy harvesting efficiency of the hybrid TENG makes the scheme of self-charging unit to power intelligent mobile electronic feasible and has practical significance for the development of self-powered sensor network.展开更多
Dear Editor,Lung cancer is the most commonly diagnosed cancer and the leading cause of cancer death in the world,but its therapeutic targets are still being explored.Genome instability as a key hallmark of cancer not ...Dear Editor,Lung cancer is the most commonly diagnosed cancer and the leading cause of cancer death in the world,but its therapeutic targets are still being explored.Genome instability as a key hallmark of cancer not only contributes to cancer initiation and progression,1 but also creates vulnerabilities that are relatively specific to cancer cells,which may be potential therapeutic targets for cancer patients.During DNA Double-Strand Breaks(DSBs)repair,BTR(BLM-Topo IIIα-RMI1/RMI2)complex promotes the dissolution of double Holliday junctions to form non-crossover products and is often considered as a tumor suppressor.2 However,the function of each individual component of this BTR complex in cancer remains largely unknown.展开更多
基金supported by the National Natural Science Foundation of China (62174115, U21A20147)the Natural Science Foundation of Jiangsu Province (BK20220284)+6 种基金the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province (22KJB510013)the Suzhou Science and Technology Development Planning Project: Key Industrial Technology Innovation (SYG201924)the University Research Development Fund (RDF-17-01-13)the Key Program Special Fund in XJTLU (KSF-T-03, KSF-A-07)partially supported by the XJTLU AI University Research Centre and Jiangsu (Provincial) Data Science and Cognitive Computational Engineering Research Centre at XJTLUthe Collaborative Innovation Center of Suzhou Nano Science & Technologythe 111 Project and Joint International Research。
文摘Realizing real-time monitoring of physiological signals is vital for preventing and treating chronic diseases in elderly individuals. However,wearable sensors with low power consumption and high sensitivity to both weak physiological signals and large mechanical stimuli remain challenges.Here, a flexible triboelectric patch(FTEP) based on porous-reinforcement microstructures for remote health monitoring has been reported. The porousreinforcement microstructure is constructed by the self-assembly of silicone rubber adhering to the porous framework of the PU sponge. The mechanical properties of the FTEP can be regulated by the concentrations of silicone rubber dilution. For pressure sensing, its sensitivity can be effectively improved fivefold compared to the device with a solid dielectric layer, reaching 5.93 kPa^(-1) under a pressure range of 0–5 kPa. In addition, the FTEP has a wide detection range up to 50 kPa with a sensitivity of 0.21 kPa^(-1). The porous microstructure makes the FTEP ultra-sensitive to external pressure, and the reinforcements endow the device with a greater deformation limit in a wide detection range. Finally, a novel concept of the wearable Internet of Healthcare(Io H) system for real-time physiological signal monitoring has been proposed, which could provide real-time physiological information for ambulatory personalized healthcare monitoring.
基金supported by National Natural Science Foundation of China (NSFC) (No. 61804103)National Key R&D Program of China (No. 2017YFA0205002)+8 种基金Natural Science Foundation of the Jiangsu Higher Education Institutions of China (Nos. 18KJA535001 and 14KJB 150020)Natural Science Foundation of Jiangsu Province of China (Nos. BK20170343 and BK20180242)China Postdoctoral Science Foundation (No. 2017M610346)State Key Laboratory of Silicon Materials, Zhejiang University (No. SKL2018-03)Nantong Municipal Science and Technology Program (No. GY12017001)Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University (KSL201803)supported by Collaborative Innovation Center of Suzhou Nano Science & Technology, the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the 111 ProjectJoint International Research Laboratory of Carbon-Based Functional Materials and Devices
文摘Continuous deforming always leads to the performance degradation of a flexible triboelectric nanogenerator due to the Young’s modulus mismatch of different functional layers.In this work,we fabricated a fiber-shaped stretchable and tailorable triboelectric nanogenerator(FST-TENG)based on the geometric construction of a steel wire as electrode and ingenious selection of silicone rubber as triboelectric layer.Owing to the great robustness and continuous conductivity,the FST-TENGs demonstrate high stability,stretchability,and even tailorability.For a single device with ~6 cm in length and ~3 mm in diameter,the open-circuit voltage of ~59.7 V,transferred charge of ~23.7 nC,short-circuit current of ~2.67 μA and average power of ~2.13 μW can be obtained at 2.5 Hz.By knitting several FST-TENGs to be a fabric or a bracelet,it enables to harvest human motion energy and then to drive a wearable electronic device.Finally,it can also be woven on dorsum of glove to monitor the movements of gesture,which can recognize every single finger,different bending angle,and numbers of bent finger by analyzing voltage signals.
基金funded by Natural Science Foundation of China (NSFC) (Grant No. U1432249)the National Key R&D Program of China (Grant 2017YFA0205002)+5 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)supported by Collaborative Innovation Center of Suzhou Nano Science & Technologythe support from China Postdoctoral Science Foundation (2017M610346)Natural Science Foundation of Jiangsu Province of China (BK20170343)Nantong Municipal Science and Technology Programthe support from Jiangsu University National Science Research Program (16KJB110021)
文摘Progress has been developed in harvesting lowfrequency and irregular blue energy using a triboelectric–electromagnetic hybrid generator in recent years. However,the design of the high-efficiency, mechanically durable hybrid structure is still challenging. In this study, we report a fully packaged triboelectric–electromagnetic hybrid generator(TEHG), in which magnets were utilized as the trigger to drive contact–separation-mode triboelectric nanogenerators(CS-TENGs) and coupled with copper coils to operate rotary freestanding-mode electromagnetic generators(RF-EMGs). The magnet pairs that produce attraction were used to transfer the external mechanical energy to the CS-TENGs, and packaging of the CS-TENGpart was achieved to protect it from the ambient environment. Under a rotatory speed of 100 rpm, the CS-TENGs enabled the TEHG to deliver an output voltage, current,and average power of 315.8 V, 44.6 μA, and ~ 90.7 μW,and the output of the RF-EMGs was 0.59 V, 1.78 m A, and 79.6 μW, respectively. The cylinder-like structure made the TEHG more easily driven by water flow and demonstrated to work as a practical power source to charge commercial capacitors. It can charge a 33μF capacitor from 0 to 2.1 V in 84 s, and the stored energy in the capacitor can drive an electronic thermometer and form a self-powered water-temperature sensing system.
基金supported by National Natural Science Foundation of China(NSFC)(Nos.61804103,U1932124)the National Science and Technology Major Project from Minister of Science and Technology of China(Grant No.2018AAA0103104)+8 种基金Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.18KJA535001)Natural Science Foundation of Jiangsu Province of China(Nos.BK20170343,BK20180242)Jiangsu Key Laboratory for Carbon Based Functional Materials and Devices,Soochow University(KJS1803)the XJTLU Key Programme Special Fund(KSF-A-18)Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipments,China University of Mining and Technology(CUMT)supported by Collaborative Innovation Center of Suzhou Nano Science and Technologythe Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the 111 ProjectJoint International Research Laboratory of Carbon-Based Functional Materials and Devices.
文摘Photoelectrochemical hydrogen generation is a promising approach to address the environmental pollution and energy crisis.In this work,we present a hybridized mechanical and solar energy-driven selfpowered hydrogen production system.A rotatory disc-shaped triboelectric nanogenerator was employed to harvest mechanical energy from water and functions as a su cient external power source.WO3/BiVO4 heterojunction photoanode was synthesized in a PEC water-splitting cell to produce H2.After transformation and rectification,the peak current reaches 0.1 m A at the rotation speed of 60 rpm.In this case,the H2 evolution process only occurs with sunlight irradiation.When the rotation speed is over 130 rpm,the peak photocurrent and peak dark current have nearly equal value.Direct electrolysis of water is almost simultaneous with photoelectrocatalysis of water.It is worth noting that the hydrogen production rate increases to 5.45 and 7.27μL min-1 without or with light illumination at 160 rpm.The corresponding energy conversion e ciency is calculated to be 2.43%and 2.59%,respectively.All the results demonstrate such a self-powered system can successfully achieve the PEC hydrogen generation,exhibiting promising possibility of energy conversion.
基金supported by the National Natural Science Foundation of China(No.52104017)National Key Research and Development Program of China(Grant No.2019YFA0705501)State Center for Research and Development of Oil Shale Exploitation,and Cooperative Innovation Center of Unconventional Oil and Gas(Ministry of Education&Hubei Province),Yangtze University(No.UOG2020-17).
文摘Projection-based embedded discrete fracture model(pEDFM)is an effective numerical model to handle the flow in fractured reservoirs,with high efficiency and strong generalization of flow models.However,this paper points out that pEDFM fails to handle flow barriers in most cases,and identifies the physical projection configuration of fractures is a key step in pEDFM.This paper presents and proves the equivalence theorem,which explains the geometric nature of physical projection configurations of fractures,that is,the projection configuration of a fracture being physical is equivalent to it being topologically homeomorphic to the fracture,by analyzing the essence of pEDFM.Physical projection configurations of fractures may be rigorously established based on this theorem,allowing pEDFM to obtain physical numerical results for many flow models,particularly those with flow barriers.Furthermore,a natural idea emerges of employing flow barriers to flexibly‘cut’the formation to quickly handle the flow problems in the formation with complex geological conditions,and several numerical examples are implemented to test this idea and application of the improved pEDFM.
文摘The urgent demand for portable electronics has promoted the development of high-efficienc)9 sustainable, and even stretchable self-charging power sources. In this work, we propose a flexible self-charging power unit based on folded carbon (FC) paper for harvesting mechanical energy from human motion and power portable electronics. The present unit mainly consists of a triboelectric nanogenerator (FC-TENG) and a supercapacitor (FC-SC), both based on folded carbon paper, as energy harvester and storage device, respectively. This favorable geometric design provides the high Young's modulus carbon paper with excellent stretchability and enables the power unit to work even under severe deformations, such as bending, twisting, and rolling. In addition, the tensile strain can be maximized by tuning the folding angle of the triangle-folded carbon paper. Moreover, the waterproof property of the packaged device make it washable, protect it from human sweat, and enable it to work in harsh environments. Finally, the as-prepared self-charging power unit was tested by placing it on the human body to harvest mechanical energy from hand tapping, foot treading, and arm touching, successfully powering an electronic watch. This work demonstrates the impressive potential of stretchable self-charging power units, which will further promote the development of high Young's modulus materials for wearable/portable electronics.
基金supported by the National Science and Technology Major Project from the Ministry of Science and Technology of China(Grant No.2018AAA0103104)National Natural Science Foundation of China(NSFC)(No.61804103)+2 种基金Natural Science Foundation of the Jiangsu Higher Education Institutions of China Program(19KJB510059)Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices,Soochow University(KJS1803)China Postdoctoral Science Foundation(No.2017 M610346)。
文摘Energy collection ways using solar energy,wave,wind,or mechanical energy have attracted widespread attention for small selfpowered electronic devices with low power consumption,such as sensors,wearable devices,electronic skin,and implantable devices.Among them,triboelectric nanogenerator(TENG)operated by coupling effect of triboelectrification and electrostatic induction has gradually gained prominence due to its advantages such as low cost,lightweight,high degree of freedom in material selection,large power,and high applicability.The device with a single energy exchange mechanism is limited by its conversion efficiency and work environment and cannot achieve the maximum conversion of energy.Thus,this article reviews the research status of different types of hybrid generators based on TENG in recent years.Hybrid energy generators will improve the output performance though the integration of different energy exchange methods,which have an excellent application prospect.From the perspective of energy complementation,it can be divided into harvesting mechanical energy by various principles,combining with harvesters of other clean energy,and converting mechanical energy or various energy sources into hydrogen energy.For integrating multitype energy harvesters,mechanism of single device and structural design of integrated units for different application scenarios are summarized.The expanding energy harvesting efficiency of the hybrid TENG makes the scheme of self-charging unit to power intelligent mobile electronic feasible and has practical significance for the development of self-powered sensor network.
基金supported by the National Key Research and Development Program of China(2016YFA0500304 to T.K.)the Fundamental Research Funds for the Central Universities(17ykjc27 to T.K.)the National Nature Science Foundation in China(NSFC)(81530081 to T.K.,81772922 to Y.W.).
文摘Dear Editor,Lung cancer is the most commonly diagnosed cancer and the leading cause of cancer death in the world,but its therapeutic targets are still being explored.Genome instability as a key hallmark of cancer not only contributes to cancer initiation and progression,1 but also creates vulnerabilities that are relatively specific to cancer cells,which may be potential therapeutic targets for cancer patients.During DNA Double-Strand Breaks(DSBs)repair,BTR(BLM-Topo IIIα-RMI1/RMI2)complex promotes the dissolution of double Holliday junctions to form non-crossover products and is often considered as a tumor suppressor.2 However,the function of each individual component of this BTR complex in cancer remains largely unknown.