Microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg–xZn–0.2Ca alloys

The microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg xZn 0.2Ca (x=0, 1.0, 2.0, 3.0) alloys were investigated in this study. Findings from scanning electron microscope, X-ray diffraction and transmission electron microscopy results indicate that the amount of ternary Ca2Mg6Zn3 phase, as the only secondary phase in 1.0Zn, 2.0Zn, and 3.0Zn alloys, gradually increases with the addition of Zn, while the Mg2Ca phase was observed in the Mg 0.2Ca alloy only. Zn has a strong effect on the orientation and intensity of textures, which also influence mechanical behaviors, as revealed by electron back-scatter diffraction. Among all the alloys, the Mg 2.0Zn 0.2Ca alloy obtains the maximum tensile strength (278 MPa) and yield strength (230 MPa). Moreover, Zn addition has an evident influence on the corrosion properties of Mg xZn 0.2Ca alloy, and Mg 1.0Zn 0.2Ca alloy exhibits the minimum corrosion rate. This paper provides a novel low-alloyed magnesium alloy as a potential biodegradable material.

Effects of Zn content on the microstructure and the mechanical and corrosion properties of as-cast low-alloyed Mg–Zn–Ca alloys

The effects of Zn content on the microstxucture and the mechanical and corrosion properties of as-cast low-alloyed Mg-xZn~.2Ca alloys （x = 0.6wt%, 2.0wt%, 2.5wt%, hereafter denoted as 0.6Zn, 2.0Zn, and 2.5Zn alloys, respectively） axe investigated. The results show that the Zn content not only influences grain refinement but also induces different phase precipitation behaviors. The as-cast microstxucture of the 0.6Zn alloy is composed of ct-Mg, Mg2Ca, and Ca2Mg6Zn3 phases, whereas 2.0Zn and 2.5Zn alloys only contain ct-Mg and Ca2Mg6Zn3 phases, as revealed by X-ray diffraction （XRD） and txonsmission electron microscopy （TEM） analyses. Moreover, with in- creasing Zn content, both the ultimate tensile strength （UTS） and the elongation to fracture first increase and then decrease. Among the three investigated alloys, the largest UTS （178 MPa） and the highest elongation to fracture （6.5%） are obtained for the 2.0Zn alloy. In addition, the corrosion rate increases with increasing Zn content. This paper provides on updated investigation of the alloy composi- tion-microstxucture-property relationships of different Zn-containing Mg-Zn-Ca alloys.

Microstructure,mechanical properties and corrosion behavior of quaternary Mg−1Zn−0.2Ca−xAg alloy wires applied as degradable anastomotic nails

The microstructure,mechanical properties and corrosion behavior of quaternary degradable Mg−1Zn−0.2Ca−xAg(x=1,2,4 wt.%)alloy wires,intended as anastomotic nails,were investigated.It was found that these Ag-containing alloy wires mainly consist of Mg matrix and Ag17Mg54 phase,characterized by SEM,EDS,XRD and TEM.Tensile and knotting tests results demonstrate the superior mechanical properties of these alloy wires.Especially,Mg−1Zn−0.2Ca−4Ag alloy exhibits the highest mechanical properties,i.e.an ultimate tensile strength of 334 MPa and an elongation of 8.6%.Moreover,with increasing Ag content,the corrosion rates of these alloy wires remarkably increase due to the formation of more micro-galvanic coupling between Mg matrix and Ag17Mg54 phase,shown by mass loss and scanning Kelvin probe force microscopy(SKPFM)results.The present alloy can be completely degraded within 28 d,satisfying the property requirements of anastomotic nails.

Influence of Ca addition on microstructure,mechanical properties and corrosion behavior of Mg-2Zn alloy

The microstructure,mechanical properties and corrosion behaviors of as-cast ternary Mg-2Zn-x Ca(x=0,0.2,0.4,0.8)alloys have been investigated in this study.Results indicate that the microstructure of Mg-Zn-Ca alloys can be significantly refined with increasing Ca concentration.Moreover,the alloys with different contents of Ca exhibit the different phases formation behaviors,i.e.α-Mg+Ca_2Mg_6Zn_3 phases for Mg-2Zn-0.2Ca and Mg-2Zn-0.4Ca alloys,andα-Mg+Ca_2Mg_6Zn_3+Mg_2Ca phases for Mg-2Zn-0.8Ca alloy,respectively.Among all the alloys,the maximum ultimate tensile strength and elongation(161 MPa and 9.1%)can be attained for the Mg-2Zn-0.2Ca alloy.Corrosion tests in Hanks’balanced salt solution indicated that Ca addition is detrimental to corrosion resistance of Mg-2Zn alloy.The relationship between as-cast microstructure and properties for different Ca-containing alloys is also discussed in detail.