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组分性质对电极浆料流变行为及成型的影响
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作者 明皓 关银燕 +3 位作者 高瑛俊 刘诗月 高维春 梁吉艳 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第9期100-107,共8页
以聚合物溶液为分散剂、活性粒子为填充剂配制浆料,应用涂覆法制备电容去离子电极是常用方式。聚合物和粒子等组分对涂层微观结构有不同贡献,电极可呈现强度和性能差异。讨论涂覆成型过程中组分间相互作用有助于结构机制的识别。流变学... 以聚合物溶液为分散剂、活性粒子为填充剂配制浆料,应用涂覆法制备电容去离子电极是常用方式。聚合物和粒子等组分对涂层微观结构有不同贡献,电极可呈现强度和性能差异。讨论涂覆成型过程中组分间相互作用有助于结构机制的识别。流变学可通过宏观流动现象研究浆料内部微观相互作用。文中选用不同链长聚合物和不同粒径填充粒子制备浆料,通过流变分析讨论了剪切条件下组分性质对涂覆成型的影响。结果表明,长链聚合物分子缠结贡献了基体黏度和柔性网络,加工窗口内可容纳更多粒子;短链分子则通过桥接絮凝与粒子形成物理交联网络,相互作用力弱时结构不稳定。微米粒子对调控流变行为和成型更有利,而纳米尺度下发生类凝胶行为逾渗阈值较低,易导致脆性涂层。基于此,提出了涂层电极浆料组分和成型条件选择的流变学方法。 展开更多
关键词 电容去离子 涂层电极 涂覆 流变行为 缠结 桥接絮凝
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悬浮液流变行为对涂层电极成型的影响
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作者 明皓 关银燕 +4 位作者 刘诗月 高瑛俊 高维春 田雪咏 梁吉艳 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第4期110-114,共5页
为探究电容去离子电极涂覆成型过程中各组分间的相互作用和微观结构,采用流变学分析手段考察了聚合物黏结剂分子链构型对电极结构的影响,建立通过流动状态识别微观结构的机制,以引导电极成型。结果表明,聚合物链结构显著影响悬浮液流变... 为探究电容去离子电极涂覆成型过程中各组分间的相互作用和微观结构,采用流变学分析手段考察了聚合物黏结剂分子链构型对电极结构的影响,建立通过流动状态识别微观结构的机制,以引导电极成型。结果表明,聚合物链结构显著影响悬浮液流变性质和涂层状态。2种聚合物均可与粒子形成物理交联网络;对于直链聚乙烯醇(PVA),链末端较少,网络的形成依靠桥接絮凝,因此黏度调控窗口较宽,分子内及分子间氢键作用使涂层坚硬,弹性低;而支化的聚乙烯亚胺(PEI),具有丰富的末端基团,与粒子作用所形成物理网络交联密度高,因此悬浮液剪切变稀显著,低分子量时涂层脆易开裂。基于此,提出了涂层电极黏结剂和成型条件选择的流变学方法。 展开更多
关键词 涂层电极 涂覆 流变行为 链结构 黏结剂
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A surrogate model for uncertainty quantification and global sensitivity analysis of nonlinear large-scale dome structures
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作者 Huidong ZHANG Yafei SONG +3 位作者 Xinqun ZHU Yaqiang ZHANG Hui WANG yingjun gao 《Frontiers of Structural and Civil Engineering》 SCIE EI CSCD 2023年第12期1813-1829,共17页
Full-scale dome structures intrinsically have numerous sources of irreducible aleatoric uncertainties.A large-scale numerical simulation of the dome structure is required to quantify the effects of these sources on th... Full-scale dome structures intrinsically have numerous sources of irreducible aleatoric uncertainties.A large-scale numerical simulation of the dome structure is required to quantify the effects of these sources on the dynamic performance of the structure using the finite element method(FEM).To reduce the heavy computational burden,a surrogate model of a dome structure was constructed to solve this problem.The dynamic global sensitivity of elastic and elastoplastic structures was analyzed in the uncertainty quantification framework using fully quantitative variance-and distribution-based methods through the surrogate model.The model considered the predominant sources of uncertainty that have a significant influence on the performance of the dome structure.The effects of the variables on the structural performance indicators were quantified using the sensitivity index values of the different performance states.Finally,the effects of the sample size and correlation function on the accuracy of the surrogate model as well as the effects of the surrogate accuracy and failure probability on the sensitivity index values are discussed.The results show that surrogate modeling has high computational efficiency and acceptable accuracy in the uncertainty quantification of large-scale structures subjected to earthquakes in comparison to the conventional FEM. 展开更多
关键词 large-scale dome structure surrogate model global sensitivity analysis uncertainty quantification structural performance
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The Meso-inhomogeneous Deformation of Pure Copper under Tension-Compression Cyclic Strain Loading 被引量:1
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作者 Lili Jin Shenghuan Qin +2 位作者 Bin Zeng yingjun gao Keshi Zhang 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2020年第3期403-417,共15页
The investigation based on experiments and crystal plasticity simulation is carried out to undertake research on mesodeformation inhomogeneity of metals under cyclic loading at grain level.Symmetrical tension-compress... The investigation based on experiments and crystal plasticity simulation is carried out to undertake research on mesodeformation inhomogeneity of metals under cyclic loading at grain level.Symmetrical tension-compression cycle tests are performed on pure copper specimens to observe the inhomogeneous distribution of slip deformation and its evolution with cycle number.Cyclic hardening process and stable hysteretic behavior of pure copper under cyclic loading are simulated by applying a crystal plasticity constitutive model including nonlinear kinematic hardening associated with the polycrystalline representative volume element(RVE)constructed by Voronoi tessellation.Inhomogeneous deformation processes of materials under six different strain amplitudes are simulated by 1600 cycles,respectively.We discuss the variation law of the inhomogeneous meso-deformation distribution of material with the increase in cycle number,and research the rationality of characterizing the inhomogeneous deformation distribution and variation with the statistical standard deviation of the micro-longitudinal strain or the statistical average of the first principal strain based on the statistical analysis of the inhomogeneous deformation of the polycrystalline RVE model during the cycling process.It is found that these two parameters are related to and approximately inversely proportional to the length of measuring gauge. 展开更多
关键词 Strain cycle Deformation inhomogeneity Polycrystalline representative volume element Measuring gauge Crystal plasticity
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