Moisture-preventing MAPbI_(3) solar cells with high photovoltaic performance via multiple ligand engineering

Perovskite solar cells present one of the most prominent photovoltaic technologies,yet their stability,and engineering at the molecular level remain challenging.We have demonstrated multifunctional molecules to improve the operating stability of perovskite solar cells while depicting a high-power conversion efficiency.The multifunctional molecule 4-[(trifluoromethyl)sulphanyl]-aniline(4TA)with trifluoromethyl(-CF_(3))and aniline(-NH_(2))moieties is meticulously designed to modulate the perovskite.The-CF_(3) and-NH_(2) functional groups have strong interaction with perovskite to suppress surface defects to improve device stability,as well as obtain large crystal grains through delaying crystallization.Moreover,this-CF_(3) forms a hydrophobic barrier on the surface of the perovskite to prevent cell decomposition.Consequently,the performance of the perovskite solar cells is remarkably improved with the efficiency increased from 18.00% to 20.24%.The perovskite solar cells with multifunctional molecular maintaining 93% of their original efficiency for over 30 days(-55%humidity)in air without device encapsulation,exhibiting a high long-term stability.Moreover,the lead leakage issue of perovskite solar cells has also been suppressed by the built-in 4TA molecule,which is beneficial to environment-friendly application.Ultimately,we believe this multifunctional small molecule provides an available way to achieve high performance perovskite solar cells and the related design strategy is helpful to further develop more versatile materials for perovskite-based optoelectronic devices.

Full-scale chemical and field-effect passivation:21.52% efficiency of stable MAPbI_(3) solar cells via benzenamine modification

Organic-inorganic metal halide perovskite solar cells have achieved high efficiency of 25.5%.Finding an effective means to suppress the formation of traps and correlate stability losses are thought to be a promising route for further increasing the photovoltaic performance and commercialization potential of perovskite photovoltaic devices.Herein,we report a facile passivation model,which uses a multi-functional organic molecule to simultaneously realize the chemical passivation and field-effect passivation for the perovskite film by an upgraded anti-solvent coating method,which reduces the trap states density of the perovskite,improves interface charge transfer,and thus promotes device performance.In addition,the hydrophobic groups of the molecules can form a moisture-repelling barrier on the perovskite grains,which apparently promotes the humidity stability of the solar cells.Therefore,the optimal power conversion efficiency(PCE)of perovskite solar cells after synergistic passivation reaches 21.52%,and it can still retain 95%of the original PCE when stored in-40%humidity for 30 days.Our findings extend the scope for traps passivation to further promote both the photovoltaic performance and the stability of the perovskite solar cells.

Upgraded antisolvent engineering enables 2D@3D quasi core-shell perovskite for achieving stable and 21.6%efficiency solar cells

Perovskite solar cells(PSCs)have become a promising alternative to sustainable energy due to their high power conversion efficiency(PCE)and low-cost processing.However,the practical applications of PSCs are still limited by the trade-off between high performance and poor stability under operation.Here,a2D@3D perovskite with quasi core-shell architecture linking the superiorities of both two-dimensional(2D)and three-dimensional(3D)perovskite is prepared through a novel upgraded antisolvent approach.The basic properties as well as the phase distribution and the charge transport behavior of the 2D@3D perovskite were systematically elucidated.A high PCE of 21.60%for 2D@3D PSCs is achieved due to the enhanced surface and grain boundaries passivation,improved energy level alignment and efficient holes transport.The 2D@3D perovskite device without encapsulation shows significantly improved stability at the room temperature(90%of initial PCE for 45 d with a relative humidity of 50%±5%)and relative thermal conditions(83%of initial PCE for 200 h under 85℃).Compared with traditional 3D PSCs,it proved that such 2D@3D perovskite configuration is an effective architecture for enhancing efficiency and improving stability and therefore will facilitate the further industrialization of PSCs.