Numerical Study on Effect of Non-uniform CMAS Penetration on TGO Growth and Interface Stress Behavior of APS TBCs

The penetration of CaO-MgO-Al_(2)O_(3)-SiO_(2)(CMAS)is one of the most significant factors that induce the failure of air-plasma-sprayed thermal barrier coatings(APS TBCs).The direct penetration of CMAS changes the thermal/mechanical properties of the top coat(TC)layer,which affects the thermal mismatch stress behavior and the growth of thermally grown oxide(TGO)at the TC/bond coat(BC)interface,thereby resulting in a more complicated interface stress state.In the present study,a two-dimensional global model of APS TBCs with half of the TC layer penetrated by CMAS is established to investigate the effect of non-uniform CMAS penetration on the interface stress behavior.Subsequently,a local model extracted from the global model is established to investigate the effects of interface morphologies and CMAS penetration depth.The results show that non-uniform CMAS penetration causes non-uniform TGO growth in APS TBCs,which consequently causes the stress behavior to vary along the interface.Furthermore,the CMAS pen-etration depth imposes a significant effect on the TC/TGO interface stress behavior,whereas the interface roughness exerts a prominent effect on the stress level at the BC/TGO interface under CMAS penetration.This study reveals the mechanism associated with the effect of non-uniform CMAS penetration on the interface stress behavior in APS TBCSs.

温敏漆应用于高超声速燃烧辐射环境的方法

热防护系统设计需要高空间分辨率的热流密度场测 量 方法来获取热流密度峰值及其对应的空间位 置 然而, 燃烧产生的背景 辐射严重阻碍了现有热流密度场测 量 方法的应用. 为了解决该难题, 提出了一种适用于强辐射燃烧环境的热流密度场测 量 方法, 基本 思想是利用温敏漆测 量 燃烧室外壁面温度的变化历程结合三维瞬态热传导反问题的求解确定内壁面热流密度场分布. 文中详细介绍 了测量系统构成、 数据处理方法及温敏漆涂层厚度对测 量 结果的影响, 最后给出了数值和实验结果验证了该方法的可行性.

基于压敏涂料的大型螺旋桨叶片压力场测量

压敏涂料(PSP)是一种全局压力测量技术.与压力传感器相比,PSP具有空间分辨率高、非接触式测量等显著优点.然而,由于其他压力测量技术的限制,在快速旋转的叶片上验证PSP测量通常比较困难.本文在中国空气动力研究与发展中心对直径为1 m的螺旋桨进行了综合研究,包括PSP测量、气动力天平测量和数值模拟.首先通过将计算的气动拉力与天平测量结果进行比较来验证文章给出的数值模拟(CFD)算法.然后,将PSP测量得到的螺旋桨叶片上的压力分布与不同工况下的CFD结果进行比较.PSP测量、天平测量和CFD的结果显示出良好的一致性,PSP测量误差估计小于叶尖动压的5%.最后讨论了不同转速和来流速度下压力分布的变化.

Ambient flash sintering of reduced graphene oxide/zirconia composites:Role of reduced graphene oxide

Fabrication of graphene/ceramic composites commonly requires a high-temperature sintering step with long times as well as a vacuum or inert atmosphere,which not only results in property degradation but also significant equipment complexity and manufacturing costs.In this work,the ambient flash sintering behavior of reduced graphene oxide/3 mol% yttria-stabilized ZrO_(2)(rGO/3 YSZ) composites utilizing rGO as both a composite component and a conductive additive is reported.When the sintering condition is carefully optimized,a dense and conductive composite can be achieved at room temperature and in the air within 20 s.The role of the rGO in the FS of the rGO/3 YSZ composites is elucidated,especially with the assistance of a separate investigation on the thermal runaway behavior of the rGO.The work suggests a promising fabrication route for rGO/ceramic composites where the vacuum and furnace are not needed,which is of interest in terms of simplifying the fabrication equipment for energy and cost savings.

Thermal stability improvement of sprayable fast-responding pressure-sensitive paint for measurement above 100℃

The thermal stability of sprayable fast-responding Pressure-Sensitive Paint(fast PSP)was investigated to explore the possibility for application in turbomachinery and hypersonic research with temperature above 100℃.The first part of the study focused on a widely-used Polymer Ceramic PSP(PC-PSP).The effects of thermal degradation on its key sensing properties,including luminescent intensity,pressure sensitivity and response time,were examined for a temperature range from 60 to 100℃.Severe degradation in intensity and pressure sensitivity was found as temperature reached 70℃or higher,which would cause failure of PSP application in these conditions.Subsequently,a fast-responding Mesoporous-Particle PSP(MP-PSP)was developed which did not show degradation effects until 140℃.The greatly improved thermal stability of MP-PSP was attributed to:selection of polymer with higher glass transition temperature(polystyrene)to delay the saturation effect of oxygen quenching as temperature increased;porous and hollow structure of particles for luminophore deposition that minimizes polymer–luminophore interaction.This new paint formulation has significantly raised the upper temperature limit of fast PSP and offers more opportunities for applications in harsh environment.

Noise reduction for temperature-sensitive paint measurement contaminated by strong background radiation in a high enthalpy hypersonic tunnel

The strong background radiation in high enthalpy hypersonic shock tunnels has posed severe challenges for measurement using luminescent coatings.We proposed a solution for reducing background radiation from time-resolved temperature-sensitive paint(TSP)measurement in a hypersonic flow with Ma=6.5 and T_(0)=3525 K.The TSP was applied on an inlet ramp model,and the images were taken by a high-speed camera at 2 kHz under a modulated excitation.The strong background radiation led to a low signal-to-noise ratio and significant errors for the first half of the 130-ms test duration.Accordingly,three noise reduction methods were developed and evaluated based on temporal reconstruction,spatial reconstruction and robust principal component analysis(RPCA),respectively.The RPCA method showed the best performance that successfully recovered high-quality TSP data for a majority of test duration(t≥40 ms).

Jet sweeping angle control by fluidic oscillators with master-slave designs

The fluidic oscillator is an instrument that can continuously generate a spatially sweeping jet entirely based on its internal geometry without any moving parts.However,the traditional fluidic oscillator has an inherent limitation,that is,the spreading angle cannot be controlled independently,rather by the jet volume flow rate and internal geometry.Accordingly,two types of fluidic oscillators based on the master-slave design are developed in current study to decouple this correlation.In both designs,the master layer inherits the similar oscillation mechanisms of a sweeping jet,and the slave layer resembles a steady jet channel.The difference between the two designs is that Design A has a short diverging exit in the slave layer,but Design B adds a long interaction chamber in the exit channel to intensify flow instability.The external flow fields and governing oscillation properties of these two designs are experimentally explored with time-resolved Particle Image Velocimetry(PIV),while the internal flow dynamics and driving oscillation mechanisms are numerically investigated.By fixing the total volume flow rate,the jet spreading angle of Design A can be increased smoothly from 0°to above 100°by increasing the proportion of master layer’s flow rate from 0 to 100%.For Design B,the control authority of the master layer is significantly enhanced by adding the interaction chamber in the slave layer.In addition,the added chamber causes notable jet oscillation even when the master layer has none input.

Interfacial properties of nano TiO_(2) and cellulose paper coating

This paper examined different kinds of organic functional groups that were introduced onto the surface of nano TiO_(2) by surface modification with different types of zircoaluminate coupling agents.The modified nanoTiO_(2) products with different interfacial properties were obtained,and the impact of the interfacial properties of nanoTiO_(2) on the rheological behavior of paper coating and the properties of coated paper was systematically investigated.The steady shear rheological results showed that the paper coatings containing nano TiO_(2) exhibited a pseudoplastic fluid behavior,characterized as obvious shear thinning.Compared to the hydrophilic unmodified nano TiO_(2),modified nano TiO_(2) could contribute more to the viscosity of paper coatings.The study on the dynamic viscoelasticity revealed that,through the enhancing action among each component in paper coatings,the modified nano TiO_(2) with quaternary amine groups or carboxyl led to a higher dynamic elastic storage modulus and viscous loss modulus of paper coatings.In addition,SEM and AFM analyses indicated that adding modified nano TiO_(2) products in paper coating could improve the coating structure,thus ameliorating the optical properties and printability of coated paper.The results obtained could provide a good reference for the application of nano pigments in paper coating.