Lidar based on the optical phased array(OPA)and frequency-modulated continuous wave(FMCW)technology stands out in automotive applications due to its all-solid-state design,high reliability,and remarkable resistance to...Lidar based on the optical phased array(OPA)and frequency-modulated continuous wave(FMCW)technology stands out in automotive applications due to its all-solid-state design,high reliability,and remarkable resistance to interference.However,while FMCW coherent detection enhances the interference resistance capabilities,it concurrently results in a significant increase in depth computation,becoming a primary constraint for improving point cloud density in such perception systems.To address this challenge,this study introduces a lidar solution leveraging the flexible scanning characteristics of OPA.The proposed system categorizes target types within the scene based on RGB images.Subsequently,it performs scans with varying angular resolutions depending on the importance of the targets.Experimental results demonstrate that,compared to traditional scanning methods,the target-adaptive method based on semantic segmentation reduces the number of points to about one-quarter while maintaining the resolution of the primary target area.Conversely,with a similar number of points,the proposed approach increases the point cloud density of the primary target area by about four times.展开更多
Light detection and ranging(LiDAR)serves as one of the key components in the fields of autonomous driving,surveying mapping,and environment detection.Conventionally,dense points clouds are pursued by LiDAR systems to ...Light detection and ranging(LiDAR)serves as one of the key components in the fields of autonomous driving,surveying mapping,and environment detection.Conventionally,dense points clouds are pursued by LiDAR systems to provide high-definition 3D images.However,the LiDAR is typically used to produce abundant yet redundant data for scanning the homogeneous background of scenes,resulting in power waste and excessive processing time.Hence,it is highly desirable for a LiDAR system to“gaze”at the target of interest by dense scanning and rough sparse scans on the uninteresting areas.Here,we propose a LiDAR structure based on an optical phased array(OPA)with reconfigurable apertures to achieve such a gaze scanning function.By virtue of the cascaded optical switch integrated on the OPA chip,a 64-,128-,192-,or 256-channel antenna can be selected discretionarily to construct an aperture with variable size.The corresponding divergence angles for the far-field beam are 0.32°,0.15°,0.10°,and 0.08°,respectively.The reconfigurable-aperture OPA enables the LiDAR system to perform rough scans via the large beam spots prior to fine scans of the target by using the tiny beam spots.In this way,the OPA-based LiDAR can perform the“gaze”function and achieve full-range scanning efficiently.The scanning time and power consumption can be reduced by 1/4 while precise details of the target are maintained.Finally,we embed the OPA into a frequency-modulated continuous-wave(FMCW)system to demonstrate the“gaze”function in beam scanning.Experiment results show that the number of precise scanning points can be reduced by 2/3 yet can obtain the reasonable outline of the target.The reconfigurable-aperture OPA(RA-OPA)can be a promising candidate for the applications of rapid recognition,like car navigation and robot vision.展开更多
The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region w...The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region was investigated using a method combining Google Earth with the field survey.The gaps between management practices and legislation requirements were analyzed.Finally,several countermeasures for water resource protection were proposed as follows:to promote delineation in a more scientific way,to safeguard the sanctity of the law,to make better plan on water saving,and to encourage public participation in supervision and management.展开更多
Germanium-on-silicon(Ge-on-Si) avalanche photodiodes(APDs) are widely used in near-infrared detection, laser ranging, free space communication, quantum communication, and other fields. However, the existence of lattic...Germanium-on-silicon(Ge-on-Si) avalanche photodiodes(APDs) are widely used in near-infrared detection, laser ranging, free space communication, quantum communication, and other fields. However, the existence of lattice defects at the Ge/Si interface causes a high dark current in the Ge-on-Si APD, degrading the device sensitivity and also increasing energy consumption in integrated circuits. In this work, we propose a novel surface illuminated Ge-on-Si APD architecture with three terminals. Besides two electrodes on Si substrates, a third electrode is designed for Ge to regulate the control current and bandwidth, achieving multiple outputs of a single device and reducing the dark current of the device. When the voltage on Ge is -27.5 V, the proposed device achieves a dark current of 100 n A, responsivity of 9.97 A/W at -40 d Bm input laser power at 1550 nm, and optimal bandwidth of 142 MHz. The low dark current and improved responsivity can meet the requirements of autonomous driving and other applications demanding weak light detection.展开更多
Bessel beam featured with self-healing is essential to the optical sensing applications in the obstacle scattering environment.Integrated on-chip generation of the Bessel beam outperforms the conventional structure by...Bessel beam featured with self-healing is essential to the optical sensing applications in the obstacle scattering environment.Integrated on-chip generation of the Bessel beam outperforms the conventional structure by small size,robustness,and alignment-free scheme.However,the maximum propagation distance(Z_(max))provided by the existing approaches cannot support long-range sensing,and thus,it restricts its potential applications.In this work,we propose an integrated silicon photonic chip with unique structures featured with concentrically distributed grating arrays to generate the Bessel-Gaussian beam with a long propagation distance.The spot with the Bessel function profile is measured at 10.24m without optical lenses,and the photonic chip’s operation wavelength can be continuously performed from 1500 to 1630 nm.To demonstrate the functionality of the generated Bessel-Gaussian beam,we also experimentally measure the rotation speeds of a spinning object via the rotational Doppler Effect and the distance through the phase laser ranging principle.The maximum error of the rotation speed in this experiment is measured to be 0.05%,indicating the minimum error in the current reports.By the compact size,low cost,and mass production potential of the integrated process,our approach is promising to readily enable the Bessel-Gaussian beam in widespread optical communication and micro-manipulation applications.展开更多
Optical phased array(OPA)technology is considered a promising solution for solid-state beam steering to supersede the traditional mechanical beam steering.As a key component of the LIDAR system for long-range detectio...Optical phased array(OPA)technology is considered a promising solution for solid-state beam steering to supersede the traditional mechanical beam steering.As a key component of the LIDAR system for long-range detection,OPAs featuring a wide steering angle and high resolution without beam aliasing are highly desired.However,a wide steering range requires a waveguide pitch less than half of the wavelength,which is easily subjected to cross talk.Besides,high resolution requires a large aperture,and it is normally achieved by a high count number of waveguides,which complicates the control system.To solve the mentioned issues,we design two high-performance 128-channel OPAs fabricated on a multilayered SiN-on-SOI platform.Attributed to the nonuniform antenna pitch,only 128 waveguides are used to achieve a 4 mm wide aperture.Besides,by virtue of innovative dual-level silicon nitride(Si_(3)N_(4))waveguide grating antennas,the fishbone antenna OPA achieves a 100°×19.4°field of view(FOV)with divergence of 0.021°×0.029°,and the chain antenna OPA realizes a 140°×19.23°FOV with divergence of 0.021°×0.1°.To our best knowledge,140°is the widest lateral steering range in two-dimensional OPA,and 0.029°is the smallest longitudinal divergence.Finally,we embed the OPA into a frequency-modulated continuous-wave system to achieve 100 m distance measurement.The reflected signal from 100 m distance is well detected with 26 dBm input transmitter power,which proves that OPA serves as a promising candidate for transceiving optical signal in a LIDAR system.展开更多
The oxygen reduction reaction (ORR) is the cornerstone reaction of the cathode in metal±air batteries;however,slow kinetics requires high-performance catalysts to promote the reaction.Polyphthalocyanine (PPc) has...The oxygen reduction reaction (ORR) is the cornerstone reaction of the cathode in metal±air batteries;however,slow kinetics requires high-performance catalysts to promote the reaction.Polyphthalocyanine (PPc) has a typical chemical cross-linking structure and uniformly dispersed metal active sites,but its poor activity and conductivity limit its applications as an ORR catalyst.Herein,a manageable and convenient strategy is proposed to synthesize ternary ORR catalysts through the low-temperature pyrolysis of Fe PPc.The optimal catalyst,Fe_(3)O_(4)/Fe_(3)N/Fe-N-C@PC-2.5,exhibits excellent ORR activity in alkaline solution with a half-wave potential of 0.90 V,which is significantly higher than that of commercial 20%Pt/C (0.84 V).Electrochemical tests and extended X-ray absorption fine structure spectroscopy reveal that the superior ORR activity of Fe_(3)O_(4)/Fe_(3)N/Fe-N-C@PC-2.5 could be ascribed to the balance of its ternary components(i.e.,Fe_(3)O_(4),Fe_(3)N,and Fe-N;species).A Zn±air battery incorporating Fe_(3)O_(4)/Fe_(3)N/Fe-N-C@PC-2.5 as an air cathodic catalyst delivers a high open-circuit voltage and peak power density.During galvanostatic discharge,the battery demonstrates a specific capacity of 815.7 mA h g^(-1).The facile strategy of using PPc to develop high-performance composite electrocatalysts may be expanded to develop new types of catalysts in the energy field.展开更多
To understand the transfer process of soluble reactive phosphorus (SRP) on the lake sediment-water interface in a mesotrophic shallow lake in South China, the SRP concentrations and the oxidation-reduction potential...To understand the transfer process of soluble reactive phosphorus (SRP) on the lake sediment-water interface in a mesotrophic shallow lake in South China, the SRP concentrations and the oxidation-reduction potential (ORP) across the sediment-water interfaces were continually monitored. Sediment samples were collected from Xinghu Lake in Guangdong Province. The ORP dynamics at different layers of overlying water was similar for six experimental systems, whereas those in porewater were significantly different. The ORP in overlying water was 200-300 mV higher than those in sediments. The oxygen penetration depth ranged from 2 to 10 mm in Xiannu Lake sediments. The variation amplitudes of ORP increased with sediment depth, but the mean ORP values were all about 218 mV. The SRP concentrations in porewater maintained at a low level of about 0.049 mg/L because of high atom ratio of total iron and total manganese to total phosphorus. The SRP concentrations and variation amplitudes in porewater increased with sediment depth. The SRP in overlying water mainly originated from S RP transference of the porewater of middle and bottom sediments (3-15 cm). The ORP variation and SRP transfer in porewater played important roles in changing SRP concentrations. A distinct SRP concentration gradient appeared in overlying water when intense exchange occurred at the sediment-water interface; therefore, it was necessary to monitor the SRP concentration profiles to accurately estimate the internal loading.展开更多
Electrocatalysts for the oxygen reduction reaction(ORR)are critically important in the development of fuel cells and metal-air batteries.Intensive research interests have been devoted to improving the electrocatalytic...Electrocatalysts for the oxygen reduction reaction(ORR)are critically important in the development of fuel cells and metal-air batteries.Intensive research interests have been devoted to improving the electrocatalytic performance by tuning the morphology and defect-active sites.Herein,we demonstrate that the oxidation state can also serve as an effective strategy for designingORR electrocatalysts.Valencemodels of silver with gradient chemical valence from zero valence to trivalence were successfully built.Their oxidation states were evaluated by cryo-X-ray photoelectron spectroscopy,X-ray absorptionfinestructure,and electron paramagnetic resonance spectroscopy.For the first time,our results demonstrated that the electrocatalytic activities of silver species can be improved by increasing their valence,conforming the orderofAg<Ag_(2)O<Ag_(2)O_(2)<Ag_(3)O_(4)<Ag_(2)O_(3).Computational studies reveal that higher valence Ag species possess a higher proportion of d band holes andmore electrons closer to the Fermi level.Therefore,the oxygen adsorption and activation energy on the Ag sites can be regulated to a near-optimal level and the ORR catalytic efficiency increases.This work clearly presents that oxidation state is another degree of freedom in designing efficient ORR electrocatalysts.展开更多
基金National Key Research and Development Program of China(2022YFB2804502,2022YFB2804504)National Natural Science Foundation of China(61934003,62090054)+2 种基金Major Scientific and Technological Program of Jilin Province(20210301014GX)Jilin Provincial Development and Reform Commission Project(2020C056)Program for Jilin University Science and Technology Innovative Research Team(JLUSTIRT,2021TD-39)。
文摘Lidar based on the optical phased array(OPA)and frequency-modulated continuous wave(FMCW)technology stands out in automotive applications due to its all-solid-state design,high reliability,and remarkable resistance to interference.However,while FMCW coherent detection enhances the interference resistance capabilities,it concurrently results in a significant increase in depth computation,becoming a primary constraint for improving point cloud density in such perception systems.To address this challenge,this study introduces a lidar solution leveraging the flexible scanning characteristics of OPA.The proposed system categorizes target types within the scene based on RGB images.Subsequently,it performs scans with varying angular resolutions depending on the importance of the targets.Experimental results demonstrate that,compared to traditional scanning methods,the target-adaptive method based on semantic segmentation reduces the number of points to about one-quarter while maintaining the resolution of the primary target area.Conversely,with a similar number of points,the proposed approach increases the point cloud density of the primary target area by about four times.
基金Program for Jilin University Science and Technology Innovative Research Team(2021TD-39)Jilin Provincial Development and Reform Commission Project(2020C056)+2 种基金Major Scientific and Technological Program of Jilin Province(20210301014GX)National Natural Science Foundation of China(62105173,62105174,61934003,62090054)National Key Research and Development Program of China(2022YFB2804504)。
文摘Light detection and ranging(LiDAR)serves as one of the key components in the fields of autonomous driving,surveying mapping,and environment detection.Conventionally,dense points clouds are pursued by LiDAR systems to provide high-definition 3D images.However,the LiDAR is typically used to produce abundant yet redundant data for scanning the homogeneous background of scenes,resulting in power waste and excessive processing time.Hence,it is highly desirable for a LiDAR system to“gaze”at the target of interest by dense scanning and rough sparse scans on the uninteresting areas.Here,we propose a LiDAR structure based on an optical phased array(OPA)with reconfigurable apertures to achieve such a gaze scanning function.By virtue of the cascaded optical switch integrated on the OPA chip,a 64-,128-,192-,or 256-channel antenna can be selected discretionarily to construct an aperture with variable size.The corresponding divergence angles for the far-field beam are 0.32°,0.15°,0.10°,and 0.08°,respectively.The reconfigurable-aperture OPA enables the LiDAR system to perform rough scans via the large beam spots prior to fine scans of the target by using the tiny beam spots.In this way,the OPA-based LiDAR can perform the“gaze”function and achieve full-range scanning efficiently.The scanning time and power consumption can be reduced by 1/4 while precise details of the target are maintained.Finally,we embed the OPA into a frequency-modulated continuous-wave(FMCW)system to demonstrate the“gaze”function in beam scanning.Experiment results show that the number of precise scanning points can be reduced by 2/3 yet can obtain the reasonable outline of the target.The reconfigurable-aperture OPA(RA-OPA)can be a promising candidate for the applications of rapid recognition,like car navigation and robot vision.
文摘The protection of drinking water sources is vital to urban development and public health.In this study,the current situation of the mandatory protection area for drinking water source in the Pearl River Delta region was investigated using a method combining Google Earth with the field survey.The gaps between management practices and legislation requirements were analyzed.Finally,several countermeasures for water resource protection were proposed as follows:to promote delineation in a more scientific way,to safeguard the sanctity of the law,to make better plan on water saving,and to encourage public participation in supervision and management.
基金Program for Jilin University Science and Technology Innovative Research Team(JLUSTIRT,2021TD-39)Jilin Scientific and Technological Development Program(20200501007GX)National Natural Science Foundation of China(61627820,61934003,62090054)。
文摘Germanium-on-silicon(Ge-on-Si) avalanche photodiodes(APDs) are widely used in near-infrared detection, laser ranging, free space communication, quantum communication, and other fields. However, the existence of lattice defects at the Ge/Si interface causes a high dark current in the Ge-on-Si APD, degrading the device sensitivity and also increasing energy consumption in integrated circuits. In this work, we propose a novel surface illuminated Ge-on-Si APD architecture with three terminals. Besides two electrodes on Si substrates, a third electrode is designed for Ge to regulate the control current and bandwidth, achieving multiple outputs of a single device and reducing the dark current of the device. When the voltage on Ge is -27.5 V, the proposed device achieves a dark current of 100 n A, responsivity of 9.97 A/W at -40 d Bm input laser power at 1550 nm, and optimal bandwidth of 142 MHz. The low dark current and improved responsivity can meet the requirements of autonomous driving and other applications demanding weak light detection.
基金supported by National Key R&D Program of China under Grants no.2022YFB2804504The National Natural Science Foundation of China under Grants nos.62090054,61934003,62105173 and 62105174+1 种基金Major scientific and technological program of Jilin Province under Grants nos.20200501007GX and 20210301014GXProgram for JLU Science and Technology Innovative Research Team(JLUSTIRT,2021TD-39).
文摘Bessel beam featured with self-healing is essential to the optical sensing applications in the obstacle scattering environment.Integrated on-chip generation of the Bessel beam outperforms the conventional structure by small size,robustness,and alignment-free scheme.However,the maximum propagation distance(Z_(max))provided by the existing approaches cannot support long-range sensing,and thus,it restricts its potential applications.In this work,we propose an integrated silicon photonic chip with unique structures featured with concentrically distributed grating arrays to generate the Bessel-Gaussian beam with a long propagation distance.The spot with the Bessel function profile is measured at 10.24m without optical lenses,and the photonic chip’s operation wavelength can be continuously performed from 1500 to 1630 nm.To demonstrate the functionality of the generated Bessel-Gaussian beam,we also experimentally measure the rotation speeds of a spinning object via the rotational Doppler Effect and the distance through the phase laser ranging principle.The maximum error of the rotation speed in this experiment is measured to be 0.05%,indicating the minimum error in the current reports.By the compact size,low cost,and mass production potential of the integrated process,our approach is promising to readily enable the Bessel-Gaussian beam in widespread optical communication and micro-manipulation applications.
基金National Key Research and Development Program of China(2016YFE0200700)National Natural Science Foundation of China(61627820,61934003,62090054,62105173,62105174)+2 种基金Jilin Scientific and Technological Development Program(20200501007GX)Program for Jilin University Science and Technology Innovative Research Team(JLUSTIRT,2021TD-39)Guangdong Basic and Applied Basic Research Foundation(2019A1515111206)。
文摘Optical phased array(OPA)technology is considered a promising solution for solid-state beam steering to supersede the traditional mechanical beam steering.As a key component of the LIDAR system for long-range detection,OPAs featuring a wide steering angle and high resolution without beam aliasing are highly desired.However,a wide steering range requires a waveguide pitch less than half of the wavelength,which is easily subjected to cross talk.Besides,high resolution requires a large aperture,and it is normally achieved by a high count number of waveguides,which complicates the control system.To solve the mentioned issues,we design two high-performance 128-channel OPAs fabricated on a multilayered SiN-on-SOI platform.Attributed to the nonuniform antenna pitch,only 128 waveguides are used to achieve a 4 mm wide aperture.Besides,by virtue of innovative dual-level silicon nitride(Si_(3)N_(4))waveguide grating antennas,the fishbone antenna OPA achieves a 100°×19.4°field of view(FOV)with divergence of 0.021°×0.029°,and the chain antenna OPA realizes a 140°×19.23°FOV with divergence of 0.021°×0.1°.To our best knowledge,140°is the widest lateral steering range in two-dimensional OPA,and 0.029°is the smallest longitudinal divergence.Finally,we embed the OPA into a frequency-modulated continuous-wave system to achieve 100 m distance measurement.The reflected signal from 100 m distance is well detected with 26 dBm input transmitter power,which proves that OPA serves as a promising candidate for transceiving optical signal in a LIDAR system.
基金financially supported by the Basic Research Project of the Science and Technology Innovation Commission of Shenzhen (JCYJ20200109141640095 and JCYJ20190809115413414)the National Natural Science Foundation of China (21671096 and 21905180)+2 种基金the Natural Science Foundation of Guangdong Province (2018A030310225)Guangdong Provincial Key Laboratory of Energy Materials for Electric Power (2018B030322001)support from the Center for Computational Science and Engineering and Core Research Facilities of SUSTech。
文摘The oxygen reduction reaction (ORR) is the cornerstone reaction of the cathode in metal±air batteries;however,slow kinetics requires high-performance catalysts to promote the reaction.Polyphthalocyanine (PPc) has a typical chemical cross-linking structure and uniformly dispersed metal active sites,but its poor activity and conductivity limit its applications as an ORR catalyst.Herein,a manageable and convenient strategy is proposed to synthesize ternary ORR catalysts through the low-temperature pyrolysis of Fe PPc.The optimal catalyst,Fe_(3)O_(4)/Fe_(3)N/Fe-N-C@PC-2.5,exhibits excellent ORR activity in alkaline solution with a half-wave potential of 0.90 V,which is significantly higher than that of commercial 20%Pt/C (0.84 V).Electrochemical tests and extended X-ray absorption fine structure spectroscopy reveal that the superior ORR activity of Fe_(3)O_(4)/Fe_(3)N/Fe-N-C@PC-2.5 could be ascribed to the balance of its ternary components(i.e.,Fe_(3)O_(4),Fe_(3)N,and Fe-N;species).A Zn±air battery incorporating Fe_(3)O_(4)/Fe_(3)N/Fe-N-C@PC-2.5 as an air cathodic catalyst delivers a high open-circuit voltage and peak power density.During galvanostatic discharge,the battery demonstrates a specific capacity of 815.7 mA h g^(-1).The facile strategy of using PPc to develop high-performance composite electrocatalysts may be expanded to develop new types of catalysts in the energy field.
基金supported by the Environment and Pollution Control Technology Innovation Program,which is one part of the 985 Project at Sun Yat-sen University
文摘To understand the transfer process of soluble reactive phosphorus (SRP) on the lake sediment-water interface in a mesotrophic shallow lake in South China, the SRP concentrations and the oxidation-reduction potential (ORP) across the sediment-water interfaces were continually monitored. Sediment samples were collected from Xinghu Lake in Guangdong Province. The ORP dynamics at different layers of overlying water was similar for six experimental systems, whereas those in porewater were significantly different. The ORP in overlying water was 200-300 mV higher than those in sediments. The oxygen penetration depth ranged from 2 to 10 mm in Xiannu Lake sediments. The variation amplitudes of ORP increased with sediment depth, but the mean ORP values were all about 218 mV. The SRP concentrations in porewater maintained at a low level of about 0.049 mg/L because of high atom ratio of total iron and total manganese to total phosphorus. The SRP concentrations and variation amplitudes in porewater increased with sediment depth. The SRP in overlying water mainly originated from S RP transference of the porewater of middle and bottom sediments (3-15 cm). The ORP variation and SRP transfer in porewater played important roles in changing SRP concentrations. A distinct SRP concentration gradient appeared in overlying water when intense exchange occurred at the sediment-water interface; therefore, it was necessary to monitor the SRP concentration profiles to accurately estimate the internal loading.
基金This work was financially supported by the Basic Research Project of the Science and Technology Innovation Commission of Shenzhen(no.JCYJ20200109141640095)the Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials(no.ZDSYS20200421111401738)+3 种基金the Leading Talents of Guangdong Province Program(no.2016LJ06C536)the National Natural Science Foundation of China(no.21875097)Z.J.and G.L.were supported by the Introduced Innovative R&D Team of Guangdong(no.2017ZT07C062)the fund of the Guangdong Provincial Key Laboratory of Computational Science and Material Design(no.2019B030301001).
文摘Electrocatalysts for the oxygen reduction reaction(ORR)are critically important in the development of fuel cells and metal-air batteries.Intensive research interests have been devoted to improving the electrocatalytic performance by tuning the morphology and defect-active sites.Herein,we demonstrate that the oxidation state can also serve as an effective strategy for designingORR electrocatalysts.Valencemodels of silver with gradient chemical valence from zero valence to trivalence were successfully built.Their oxidation states were evaluated by cryo-X-ray photoelectron spectroscopy,X-ray absorptionfinestructure,and electron paramagnetic resonance spectroscopy.For the first time,our results demonstrated that the electrocatalytic activities of silver species can be improved by increasing their valence,conforming the orderofAg<Ag_(2)O<Ag_(2)O_(2)<Ag_(3)O_(4)<Ag_(2)O_(3).Computational studies reveal that higher valence Ag species possess a higher proportion of d band holes andmore electrons closer to the Fermi level.Therefore,the oxygen adsorption and activation energy on the Ag sites can be regulated to a near-optimal level and the ORR catalytic efficiency increases.This work clearly presents that oxidation state is another degree of freedom in designing efficient ORR electrocatalysts.