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Research progress on vanadium oxides for potassium-ion batteries 被引量:2
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作者 Yuhan Wu guangbo Chen +6 位作者 Xiaonan Wu Lin Li Jinyu Yue yinyan guan Juan Hou Fanian Shi Jiyan Liang 《Journal of Semiconductors》 EI CAS CSCD 2023年第4期46-59,共14页
Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium ox... Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium oxides exhibit great potentiality.Vanadium oxides can provide multiple electron transfers during electrochemical reactions because vanadium possesses a variety of oxidation states.Meanwhile,their relatively low cost and superior material,structural,and physicochemical properties endow them with strong competitiveness.Although some inspiring research results have been achieved,many issues and challenges remain to be further addressed.Herein,we systematically summarize the research progress of vanadium oxides for PIBs.Then,feasible improvement strategies for the material properties and electrochemical performance are introduced.Finally,the existing challenges and perspectives are discussed with a view to promoting the development of vanadium oxides and accelerating their practical applications. 展开更多
关键词 potassium-ion batteries vanadium oxides electrode materials electrochemical performance improvement strategies
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悬浮液流变行为对涂层电极成型的影响
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作者 明皓 关银燕 +4 位作者 刘诗月 高瑛俊 高维春 田雪咏 梁吉艳 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第4期110-114,共5页
为探究电容去离子电极涂覆成型过程中各组分间的相互作用和微观结构,采用流变学分析手段考察了聚合物黏结剂分子链构型对电极结构的影响,建立通过流动状态识别微观结构的机制,以引导电极成型。结果表明,聚合物链结构显著影响悬浮液流变... 为探究电容去离子电极涂覆成型过程中各组分间的相互作用和微观结构,采用流变学分析手段考察了聚合物黏结剂分子链构型对电极结构的影响,建立通过流动状态识别微观结构的机制,以引导电极成型。结果表明,聚合物链结构显著影响悬浮液流变性质和涂层状态。2种聚合物均可与粒子形成物理交联网络;对于直链聚乙烯醇(PVA),链末端较少,网络的形成依靠桥接絮凝,因此黏度调控窗口较宽,分子内及分子间氢键作用使涂层坚硬,弹性低;而支化的聚乙烯亚胺(PEI),具有丰富的末端基团,与粒子作用所形成物理网络交联密度高,因此悬浮液剪切变稀显著,低分子量时涂层脆易开裂。基于此,提出了涂层电极黏结剂和成型条件选择的流变学方法。 展开更多
关键词 涂层电极 涂覆 流变行为 链结构 黏结剂
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