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基于纳米铜涂层的超浸润织物的制备及应用——推荐一个化学科普实验 被引量:3
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作者 肖怡婷 赵瑾瑜 +2 位作者 孟莹 帅琴 欧阳磊 《大学化学》 CAS 2023年第9期114-121,共8页
纳米材料功能化的新型织物因具有抗污、防水等特性,得到了广泛应用,但背后的原理却少有了解。本实验通过铜还原反应,在织物表面生成纳米铜涂层,得到超疏水织物;通过氧化处理,使织物展现出水下超疏油、油下超疏水性。通过展示铜超浸润织... 纳米材料功能化的新型织物因具有抗污、防水等特性,得到了广泛应用,但背后的原理却少有了解。本实验通过铜还原反应,在织物表面生成纳米铜涂层,得到超疏水织物;通过氧化处理,使织物展现出水下超疏油、油下超疏水性。通过展示铜超浸润织物的特性,并结合多种互动方案探究背后的原理,具有重要的科普意义和价值。 展开更多
关键词 纳米织物涂层 纳米铜 超浸润 油下超疏水 水下超疏油
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ALKALINE PRETREATMENT AND AIR MIXING FOR IMPROVEMENT OF METHANE PRODUCTION FROM ANAEROBIC CO-DIGESTION OF POULTRY LITTER WITH WHEAT STRAW
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作者 Yuanhang ZHAN Jun ZHU +1 位作者 yiting xiao Leland C.SCHRADER 《Frontiers of Agricultural Science and Engineering》 CSCD 2023年第3期424-436,共13页
Alkaline pretreatment(AL)and air mixing(air)both have the potential to improve anaerobic co-digestion(Co-AD)of poultry litter with wheat straw for methane production.In this study,the effects of the combination of AL(... Alkaline pretreatment(AL)and air mixing(air)both have the potential to improve anaerobic co-digestion(Co-AD)of poultry litter with wheat straw for methane production.In this study,the effects of the combination of AL(pH 12 for 12 h)and air mixing(12 mL·d^(−1))on the Co-AD process were investigated.The substrate hydrolysis was enhanced by AL,with soluble chemical oxygen demand increased by 4.59 times and volatile fatty acids increased by 5.04 times.The cumulative methane yield in the group of Co-AD by AL integrated with air(Co-(AL+air)),being 287 mL·(g VS_(added))^(−1),was improved by 46.7%compared to the control.The cone model was found the best in simulating the methane yield kinetics with R^(2)≥0.9979 and root mean square prediction error(rMSPE)≤3.50.Co-(AL+air)had a larger hydrolysis constant k(0.14 d^(−1))and a shorter lag phaseλ(0.99 d)than the control(k=0.12 d^(−1),λ=2.06 d).The digestate improved the removal of total solids and total volatile solids by 2.0 and 2.3 times,respectively.AL facilitated substrate degradation,while air can enrich the microbial activity,together enhancing the methane generation.The results show that AL+air can be applied as an effective method to improve methane production from the Co-AD process. 展开更多
关键词 sodium hydroxide air injection cumulative methane yield kinetic modeling analysis DIGESTATE
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DEGRADATION OF ORGANIC POLLUTANTS IN FLOCCULATED LIQUID DIGESTATE USING PHOTOCATALYTIC TITANATE NANOFIBERS: MECHANISM AND RESPONSE SURFACE OPTIMIZATION
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作者 yiting xiao Yang TIAN +1 位作者 Yuanhang ZHAN Jun ZHU 《Frontiers of Agricultural Science and Engineering》 CSCD 2023年第3期492-502,共11页
Titanate nanofibers(TNFs)were synthesized using a hydrothermal method and were employed for the first time in this study to photocatalytically degrade organic pollutants found in flocculated liquid digestate of poultr... Titanate nanofibers(TNFs)were synthesized using a hydrothermal method and were employed for the first time in this study to photocatalytically degrade organic pollutants found in flocculated liquid digestate of poultry litter.The photocatalytic performance of TNFs,with a bandgap of 3.16 eV,was tested based on degradation of organic pollutants and removal of color.Five combinations of pollutant concentration and pH were examined(0.2 to 1.3 g·L^(−1) at pH 4 to 10).Central composite design(CCD)and response surface methodology(RSM)were applied in order to optimize the removal rates of volatile fatty acids(VFA)and chemical oxygen demand(COD),and the decolorization rate.There were no significant differences between the regression models generated by the CCD/RSM and the experimental data.It was found that the optimal values for pH,dosage,VFA removal rate,COD removal rate and decolorization rate were 6.752,0.767 g·L^(−1),72.9%,59.1%and 66.8%,respectively.These findings indicates that photocatalytic TNFs have potential for the posttreatment of anaerobic digestion effluent,as well as other types of wastewater. 展开更多
关键词 titanate nanofibers PHOTOCATALYSIS poultry litter liquid digestate
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