Single-atom catalysts(SACs)have been extensively studied in photocatalysis,electrochemistry,and thermocatalysis.However,their utilization in photothermal catalysis is still in the infancy and is worth investigating,as...Single-atom catalysts(SACs)have been extensively studied in photocatalysis,electrochemistry,and thermocatalysis.However,their utilization in photothermal catalysis is still in the infancy and is worth investigating,as these catalysts are expected to bring further advancement to the field.展开更多
Asymmetry has been demonstrated an effective approach in recent years to tune the structural and energetic orders of nonfullerene electron acceptors(NFAs)to prepare efficient organic solar cells(OSCs).In this article,...Asymmetry has been demonstrated an effective approach in recent years to tune the structural and energetic orders of nonfullerene electron acceptors(NFAs)to prepare efficient organic solar cells(OSCs).In this article,five asymmetric NFAs,namely C9BTP-BO-Th Cl-2F,C9BTP-BO-Cl-2F,C9BTP-BO-2Cl-2F,C7BTP-BO-2Cl-2F and C5BTP-BO-2Cl-2F possessing varied asymmetric end-groups and alkyl chains are synthesized to tune the charge transport networks formed within these NFAs.We found that the enhanced planarity in the asymmetric NFA can facilitate closerπ-πstacking distance in either the A-to-A or A-toD type NFA dimers,whilst the larger dipole moment can promote the formation of three-dimensional(3D)charge transport networks among NFAs.Taking those advantages,C7BTP-BO-2Cl-2F exhibit a compact 3D honeycomb network with a high packing coefficient of 72.1%and molecular packing density of 0.48 g/cm^(3),contributing to a superior power conversion efficiency of 18.0%when employing PM6 as the donor,with an open-circuit voltage of 0.85 V,short-circuit current of26.7 m A cm^(-2)and fill factor of 79.3%.Our work provides guidelines in engineering the end group and side chains of asymmetric NFAs to achieve compact charge transport networks for high efficiency OSCs.展开更多
Accurate transient stability assessment(TSA) and effective preventive control are important for the stable operation of power systems. With the superiorities in precision and efficiency, data-driven methods are widely...Accurate transient stability assessment(TSA) and effective preventive control are important for the stable operation of power systems. With the superiorities in precision and efficiency, data-driven methods are widely used in TSA nowadays. Data-driven TSA model can be adopted in the stability constraints of preventive control optimization, but existing methods are mostly iteration-based ones, which may result in low efficiency, sometimes even non-convergence. In this paper,an analytical representation method of data-driven transient stability constraint is proposed based on a non-parametric regression model built for TSA. Key feature extraction and dominant sample selection are proposed to reduce the scale of the TSA model, and bi-level linearization is applied to further modify it.Optimal preventive control model is then formulated as a mixed-integer linear program(MILP) problem with the linearized analytical data-driven transient stability constraint, which can be solved without iterations. An overall procedure of datadriven TSA and preventive control is finally developed. Case studies show that the proposed method has high accuracy in TSA and can achieve effective preventive control of power system with high efficiency.展开更多
基金supported by the National Key Research and Development Program of China(2022YFB3803600)the National Natural Science Foundation of China(52276212)+3 种基金the Suzhou Science and Technology Program(SYG202101)the Natural Science Foundation of Jiangsu Province(BK20231211)the Key Research and Development Program in Shaanxi Province of China(2023YBGY-300)the China Fundamental Research Funds for the Central Universities。
文摘Single-atom catalysts(SACs)have been extensively studied in photocatalysis,electrochemistry,and thermocatalysis.However,their utilization in photothermal catalysis is still in the infancy and is worth investigating,as these catalysts are expected to bring further advancement to the field.
基金supported by the National Natural Science Foundation of China(52073221,52273196)。
文摘Asymmetry has been demonstrated an effective approach in recent years to tune the structural and energetic orders of nonfullerene electron acceptors(NFAs)to prepare efficient organic solar cells(OSCs).In this article,five asymmetric NFAs,namely C9BTP-BO-Th Cl-2F,C9BTP-BO-Cl-2F,C9BTP-BO-2Cl-2F,C7BTP-BO-2Cl-2F and C5BTP-BO-2Cl-2F possessing varied asymmetric end-groups and alkyl chains are synthesized to tune the charge transport networks formed within these NFAs.We found that the enhanced planarity in the asymmetric NFA can facilitate closerπ-πstacking distance in either the A-to-A or A-toD type NFA dimers,whilst the larger dipole moment can promote the formation of three-dimensional(3D)charge transport networks among NFAs.Taking those advantages,C7BTP-BO-2Cl-2F exhibit a compact 3D honeycomb network with a high packing coefficient of 72.1%and molecular packing density of 0.48 g/cm^(3),contributing to a superior power conversion efficiency of 18.0%when employing PM6 as the donor,with an open-circuit voltage of 0.85 V,short-circuit current of26.7 m A cm^(-2)and fill factor of 79.3%.Our work provides guidelines in engineering the end group and side chains of asymmetric NFAs to achieve compact charge transport networks for high efficiency OSCs.
基金supported by National Key R&D Program of China (No.2018YFB0904500)State Grid Corporation of China (No. SGLNDK00KJJS1800236)。
文摘Accurate transient stability assessment(TSA) and effective preventive control are important for the stable operation of power systems. With the superiorities in precision and efficiency, data-driven methods are widely used in TSA nowadays. Data-driven TSA model can be adopted in the stability constraints of preventive control optimization, but existing methods are mostly iteration-based ones, which may result in low efficiency, sometimes even non-convergence. In this paper,an analytical representation method of data-driven transient stability constraint is proposed based on a non-parametric regression model built for TSA. Key feature extraction and dominant sample selection are proposed to reduce the scale of the TSA model, and bi-level linearization is applied to further modify it.Optimal preventive control model is then formulated as a mixed-integer linear program(MILP) problem with the linearized analytical data-driven transient stability constraint, which can be solved without iterations. An overall procedure of datadriven TSA and preventive control is finally developed. Case studies show that the proposed method has high accuracy in TSA and can achieve effective preventive control of power system with high efficiency.
