Underwater quantum communication plays a crucial role in ensuring secure data transmission and extensible quantum networks in underwater environments.However,the implementation of such applications encounters challeng...Underwater quantum communication plays a crucial role in ensuring secure data transmission and extensible quantum networks in underwater environments.However,the implementation of such applications encounters challenges due to the light attenuation caused by the complicated natural seawater.This paper focuses on employing a model based on seawater chlorophyll-a concentration to characterize the absorption and scattering of light through quantum channels.We propose a multi-scattering random channel model,which demonstrates characteristics of the excess noise in different propagation directions of communication links.Furthermore,we consider the fidelity of a continuous-variable quantum teleportation through seawater channel.To enhance transmission performance,non-Gaussian operations have been conducted.Numerical simulations show that incorporating non-Gaussian operations enables the protocol to achieve higher fidelity transmission or lower fidelity fading rates over longer transmission distances.展开更多
A new species of the coral snake genus Sinomicrurus is described based on four specimens from southern Hainan Island (three specimens from Tianchi, Jianfengling National Nature Reserve, one specimen from Diaoluoshan ...A new species of the coral snake genus Sinomicrurus is described based on four specimens from southern Hainan Island (three specimens from Tianchi, Jianfengling National Nature Reserve, one specimen from Diaoluoshan National Nature Reserve), Hainan Province, China. Morphologically, the new species is rather similar to Sinomicrurus kelloggi. However, it is distinct from S. kelloggi by the pattern on the head, the head length, head length/width, the number of infralabial scales, number of bands on dorsal body, and number of blotches on the belly.展开更多
Revealing the molecular packing,intermolecular interactions,and aggregation behaviors in the nanocrystalline bulk heterojunction(BHJ)domains undertake the tasks for future materials design for efficient solar cells,es...Revealing the molecular packing,intermolecular interactions,and aggregation behaviors in the nanocrystalline bulk heterojunction(BHJ)domains undertake the tasks for future materials design for efficient solar cells,especially in understanding the structure–property relationship of isomeric non-fullerene acceptors(NFAs).Theoretical calculations reveal that 2ClIC-βδ,withβ-andδ-chlorine-substituted terminal groups,achieves a relatively higher dipole moment for enhanced intermolecular interactions.More importantly,when comparing the single-crystal X-ray diffraction patterns of three isomeric NFAs,BTIC-BO4Cl-βδ,BTIC-BO4Cl-βγ,and BTIC-BO4Cl,the synergistic effect of chlorine atoms at theβ-andδ-positions endows BTIC-BO4Cl-βδbetter molecular planarity with a dihedral angle of 1.14°.In turn,this creates the shortestπ∙∙∙πdistance(3.28Å)and smallest binding energies(−51.66 kcal mol^(−1))of the three NFAs,resulting in the tightest three-dimensional network packing structure with a framework of L_(x)=14.0Åand L_(y)=13.6Å.Such a structure has multiple intermolecular interactions for better charge transfer.However,the chlorine atomat theγ-position in the other two isomers contributes to non-intermolecular interactions with subordinate packing arrangements.Subsequently,the red-shifted UV-absorption and higher electron mobility observed in neat films of BTIC-BO4Cl-βδagree well with its more ordered crystallinity.This leads to a more suitable fiber-like phase separation in the corresponding active blend,ultimately improving the device performance with superior charge transport.As a result,the highest power conversion efficiency of 17.04%with a current density of 26.07 mA cm^(−2)was obtained with the BTIC-BO4Cl-βδ-based device.The carrier dynamics test and grazing incidence wide-angle X-ray scattering measurement indicate that the packing arrangement of molecules in the nanocrystalline BHJ domains is consistent with their crystallinity.This work investigates the structure–property differences in three acceptors and emphasizes the effect of isomeric chlorine substitution,which suggests that changes in the crystal packing arrangement,especially the size of the framework,have a considerable influence on charge carrier transport and ultimately are reflected on the device efficiency elevation.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.61871407)the Natural Science Foundation of Hunan Province,China(Grant No.2021JJ30878)the Key Research and Development Program of Hunan Province,China(Grant Nos.2020GK4063 and 2022GK2016)。
文摘Underwater quantum communication plays a crucial role in ensuring secure data transmission and extensible quantum networks in underwater environments.However,the implementation of such applications encounters challenges due to the light attenuation caused by the complicated natural seawater.This paper focuses on employing a model based on seawater chlorophyll-a concentration to characterize the absorption and scattering of light through quantum channels.We propose a multi-scattering random channel model,which demonstrates characteristics of the excess noise in different propagation directions of communication links.Furthermore,we consider the fidelity of a continuous-variable quantum teleportation through seawater channel.To enhance transmission performance,non-Gaussian operations have been conducted.Numerical simulations show that incorporating non-Gaussian operations enables the protocol to achieve higher fidelity transmission or lower fidelity fading rates over longer transmission distances.
基金funded by the National Natural Science Foundation of China (31471968)Key Discipline of Ecology and Research Platform of Bioresource Institution, Huangshan University
文摘A new species of the coral snake genus Sinomicrurus is described based on four specimens from southern Hainan Island (three specimens from Tianchi, Jianfengling National Nature Reserve, one specimen from Diaoluoshan National Nature Reserve), Hainan Province, China. Morphologically, the new species is rather similar to Sinomicrurus kelloggi. However, it is distinct from S. kelloggi by the pattern on the head, the head length, head length/width, the number of infralabial scales, number of bands on dorsal body, and number of blotches on the belly.
基金supported by the National Natural Science Foundation of China(grant nos.21733005,21975115)Guangdong Provincial Key Laboratory of Catalysis(grant no.2020B121201002)+2 种基金Guangdong Innovative and Entrepreneurial Research Team Program(grant no.2016ZT06G587)Shenzhen Fundamental Research Program(grant nos.JCYJ20210324120010028,JCYJ20200109140801751)Shenzhen Sci-Tech Fund(grant no.KYTDPT20181011104007).
文摘Revealing the molecular packing,intermolecular interactions,and aggregation behaviors in the nanocrystalline bulk heterojunction(BHJ)domains undertake the tasks for future materials design for efficient solar cells,especially in understanding the structure–property relationship of isomeric non-fullerene acceptors(NFAs).Theoretical calculations reveal that 2ClIC-βδ,withβ-andδ-chlorine-substituted terminal groups,achieves a relatively higher dipole moment for enhanced intermolecular interactions.More importantly,when comparing the single-crystal X-ray diffraction patterns of three isomeric NFAs,BTIC-BO4Cl-βδ,BTIC-BO4Cl-βγ,and BTIC-BO4Cl,the synergistic effect of chlorine atoms at theβ-andδ-positions endows BTIC-BO4Cl-βδbetter molecular planarity with a dihedral angle of 1.14°.In turn,this creates the shortestπ∙∙∙πdistance(3.28Å)and smallest binding energies(−51.66 kcal mol^(−1))of the three NFAs,resulting in the tightest three-dimensional network packing structure with a framework of L_(x)=14.0Åand L_(y)=13.6Å.Such a structure has multiple intermolecular interactions for better charge transfer.However,the chlorine atomat theγ-position in the other two isomers contributes to non-intermolecular interactions with subordinate packing arrangements.Subsequently,the red-shifted UV-absorption and higher electron mobility observed in neat films of BTIC-BO4Cl-βδagree well with its more ordered crystallinity.This leads to a more suitable fiber-like phase separation in the corresponding active blend,ultimately improving the device performance with superior charge transport.As a result,the highest power conversion efficiency of 17.04%with a current density of 26.07 mA cm^(−2)was obtained with the BTIC-BO4Cl-βδ-based device.The carrier dynamics test and grazing incidence wide-angle X-ray scattering measurement indicate that the packing arrangement of molecules in the nanocrystalline BHJ domains is consistent with their crystallinity.This work investigates the structure–property differences in three acceptors and emphasizes the effect of isomeric chlorine substitution,which suggests that changes in the crystal packing arrangement,especially the size of the framework,have a considerable influence on charge carrier transport and ultimately are reflected on the device efficiency elevation.