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Efficient removal of Al(Ⅲ)and P507 from high concentration MgCl_(2)solution based on in-situ reaction strategy
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作者 Qiang WANG Meng WANG +3 位作者 Zong-yu FENG yong-qi zhang Xiao-wei HUANG Xiang-xin XUE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期3042-3053,共12页
For a highly efficient recycling of a wastewater containing a high concentration of MgCl_2,Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high concent... For a highly efficient recycling of a wastewater containing a high concentration of MgCl_2,Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high concentration MgCl_(2)solution at different pH values and Al/P molar ratios was investigated.The results showed that P507 formed organic complexes of Al_x(OH)_y~(Z+)-P507 at pH of 2.0-4.0.At pH of 4.0-5.0,Al(Ⅲ)precipitated and transferred into Al(OH)_(3)with a flocculent amorphous morphology.Active sites on the Al(OH)_(3)surface enhanced the removal efficiency of P507.At pH of 6.0-6.5,Al(Ⅲ)and Mg(Ⅱ)formed layered crystalline Al(OH)_(3)and MgAl_2(OH)_(8with)small pore channels and fewer active sites,resulting in a reduced removal efficiency of P507.When the Al/P molar ratio exceeded 13 and the pH was between 4.0 and 5.0,the removal rates of both Al(Ⅲ)and P507 were higher than98%,while the concentration loss of Mg(Ⅱ)was only 0.2%-0.9%. 展开更多
关键词 in-situ removal AL(III) P507 MgCl2 solution pH Al/P molar ratio
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Effects of co-precipitation temperature on structure and properties of La and Y doped cerium zirconium mixed oxides 被引量:2
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作者 Lian-jie zhang Mei-sheng CUI +5 位作者 Hao WANG Yong-ke HOU Shi-lei CHEN Zhi-zhe ZHAI Zhi-qi LONG yong-qi zhang 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第2期618-628,共11页
Due to the oxygen storage and release properties,cerium zirconium mixed oxides are recognized as the key material in automotive three-way catalysts.To reveal the effects of co-precipitation temperature on structure,ph... Due to the oxygen storage and release properties,cerium zirconium mixed oxides are recognized as the key material in automotive three-way catalysts.To reveal the effects of co-precipitation temperature on structure,physical and chemical properties of multi-doped cerium zirconium mixed oxides,a series of La and Y doped cerium zirconium mixed oxides(CZLYs)were synthesized via a co-precipitation method,and the physical and chemical properties of CZLYs were systemically characterized by XRD,N_(2) adsorption−desorption,TEM,XPS,oxygen storage capacity(OSC)and hydrogen temperature programmed reduction(H_(2)-TPR).The results show that co-precipitation temperature is an important parameter to influence the crystal size,oxygen storage capacity and thermal stability of CZLYs.When the co-precipitation temperature was 60℃,the best redox properties and thermal stability of CZLYs were obtained.After thermal treatment at 1100℃for 10 h,the specific surface area and oxygen storage capacity of the corresponding aged sample were 15.42 m^(2)/g and 497.7μmol/g,respectively.In addition,a mechanism was proposed to reveal the effects of co-precipitation temperature on the structure and properties of CZLYs. 展开更多
关键词 La and Y doping cerium zirconium mixed oxides co-precipitation temperature crystal size thermal stability
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A novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite oxide with surface doping of Y and its application in Pd-only three-way catalyst 被引量:1
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作者 Zheng Zhao Wei-Xin Zhao +6 位作者 yong-qi zhang Mei-Sheng Cui Yong-Ke Hou Dong-Ming Chen Juan-Yu Yang Zong-Yu Feng Xiao-Wei Huang 《Rare Metals》 SCIE EI CAS CSCD 2024年第2期749-757,共9页
The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way catalyst.Moreover,the surface structure of CZ plays an important role in catalytic activity of Pd.However,how to regulate th... The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way catalyst.Moreover,the surface structure of CZ plays an important role in catalytic activity of Pd.However,how to regulate the surface structure of CZ and clarify the structure–activity relationship is still a challenge.In this paper,a strategy is proposed to develop high activity Pd@CZ nanocatalysts by tuning Y doping sites in CZ.The precipitate-deposition method is developed to prepare the novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite with surface doping of Y(CZ-Y-S).In addition,the Pd@CZ-Y-S(Pd supported on CZ-Y-S)exhibits superior catalytic activity for HC,CO,and NO oxide,wherein,for CO and C_(3)H_(6) oxidation,the low-temperature activity of Pd@CZ-Y-S is still 20%higher than that of Pd@CZ-Y-B(Y bulk doping)and commercial Pd@CZ after 1000℃/4 h aging.The effect mechanism is further studied by density functional theory(DFT)calculation.Compared with Pd@CZ-Y-B,Pd@CZ-Y-S shows the lower CO oxide reaction energy barriers due to the weaker adsorption strength of O2.The Y surface doping strategy could provide valuable insights for the development of highly efficient Pd@CZ catalyst with extensive applications. 展开更多
关键词 Rare earth Ceria-zirconia-supported Pd Surface doping Experiment and theory Catalytic application
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