The depression behavior and mechanism of guar gum on talc-type scheelite flotation were systematically investigated by flotation experiments, adsorption tests, zeta-potential measurements, and infrared spectroscopic a...The depression behavior and mechanism of guar gum on talc-type scheelite flotation were systematically investigated by flotation experiments, adsorption tests, zeta-potential measurements, and infrared spectroscopic analyses. The flotation results for monominerals, mixed minerals, and actual mineral samples indicated that guar gum exhibited much higher selective depression for talc than for scheelite. Bench-scale closed-circuit tests showed that a tungsten concentrate with a WO_3 grade of 51.43% and a WO_3 recovery of 76.18% was obtained. Adsorption tests, zeta-potential measurements, and infrared spectral analyses confirmed that guar gum absorbed more strongly onto the talc surface than onto the scheelite surface because of chemisorption between guar gum and talc. This chemisorption is responsible for the guar gum's highly selective depression for talc and small depression for scheelite. The flotation results provide technical support for talc-type scheelite flotation.展开更多
Thin walls of a copper-base alloy with the nominal composition CuNi17Al3Fe1.5Cr were successfully prepared by laser direct deposition additive manufacturing. The microstructure, as revealed by optical and scanning ele...Thin walls of a copper-base alloy with the nominal composition CuNi17Al3Fe1.5Cr were successfully prepared by laser direct deposition additive manufacturing. The microstructure, as revealed by optical and scanning electron microscopy, indicated that the deposited material was fully dense and with a dendritic microstructure. The dendrites are parallel to the build-up direction, which is also the heat con-duction direction during deposition. X-ray diffraction analysis results show that the deposited material is composed of a single phase and a copper-based solid solution. Some precipitate particles of metal silicides were observed in the interdendritic region by scanning electron mi-croscopy. The ultimate tensile strength along the laser scanning direction reaches 735 MPa. The hardness is about Hv0.1 300.展开更多
The approximately equimolar ratio A1CrNiSiTi multi-principal element alloy (MPEA) coatings were fab- ricated by laser cladding on Ti-6Al-4V (Ti64) alloy. Scanning electron microscopy (SEM), equipped with an ener...The approximately equimolar ratio A1CrNiSiTi multi-principal element alloy (MPEA) coatings were fab- ricated by laser cladding on Ti-6Al-4V (Ti64) alloy. Scanning electron microscopy (SEM), equipped with an energy-dispersive spectroscopy (EDS), and X-ray diffrac- tion (XRD) were used to characterize the microstructure and composition. Investigations show that the coatings consist of (Ti, Cr)5Si3 and NiA1 phases, formed by in situ reaction. The phase composition is initially explicated according to obtainable binary and ternary phase diagrams, and the formation Gibbs energy of TisSi3, VsSi3 and CrsSi3. Dry sliding reciprocating friction and wear tests of the A1CrNiSiTi coating and Ti64 alloy substrate without coating were evaluated. A surface mapping profiler was used to evaluate the wear volume. The worn surface was characterized by SEM-EDS. The hardness and wear resistance of the A1CrNiSiTi coating are well compared with that of the basal material (Ti64). The main wear mechanism of the AICrNiSiTi coating is slightly adhesive transfer from GCrl5 counterpart, and a mixed layer com- posed of transferred materials and oxide is formed.展开更多
Laser powder deposition was applied to fabricate the Ti-6.5Al-3.5Mo-1.5Zr-0.3Si (wt%)/Ti-47Al- 2Cr-2Nb-0.2W-0.15B (at%) bi-material system. The asdeposited TC11 alloy shows a basket-wave-like morphology while the ...Laser powder deposition was applied to fabricate the Ti-6.5Al-3.5Mo-1.5Zr-0.3Si (wt%)/Ti-47Al- 2Cr-2Nb-0.2W-0.15B (at%) bi-material system. The asdeposited TC11 alloy shows a basket-wave-like morphology while the as-deposited y-TiAl alloy consists of fully α2/γ lamellar microstructures. Regarding the thermal mismatch between TC11 and γ-TiAl during processing, the interface microstmcture evolution was concerned. The transformation pathway was illustrated. It is found that the content changes of Al elements and β-stabilizers Mo, Cr, and Nb are responsible for the evolution of microstructures at the interface. The fracture surfaces are located at the y-TiAl side. The bi-material shows a brittle-fracture manner, with the ultimate tensile strength of 560 MPa.展开更多
基金financially supported by the National Natural Science Foundation of China (No.51404218)the National Key Technology R&D Program (No.2015BAB12B02)the Science and Technology Planning Project of Guangdong Province, China (No.2013B090800016)
文摘The depression behavior and mechanism of guar gum on talc-type scheelite flotation were systematically investigated by flotation experiments, adsorption tests, zeta-potential measurements, and infrared spectroscopic analyses. The flotation results for monominerals, mixed minerals, and actual mineral samples indicated that guar gum exhibited much higher selective depression for talc than for scheelite. Bench-scale closed-circuit tests showed that a tungsten concentrate with a WO_3 grade of 51.43% and a WO_3 recovery of 76.18% was obtained. Adsorption tests, zeta-potential measurements, and infrared spectral analyses confirmed that guar gum absorbed more strongly onto the talc surface than onto the scheelite surface because of chemisorption between guar gum and talc. This chemisorption is responsible for the guar gum's highly selective depression for talc and small depression for scheelite. The flotation results provide technical support for talc-type scheelite flotation.
基金supported by the Major State Basic Research and Development Program of China (No.2006CB605206-1)
文摘Thin walls of a copper-base alloy with the nominal composition CuNi17Al3Fe1.5Cr were successfully prepared by laser direct deposition additive manufacturing. The microstructure, as revealed by optical and scanning electron microscopy, indicated that the deposited material was fully dense and with a dendritic microstructure. The dendrites are parallel to the build-up direction, which is also the heat con-duction direction during deposition. X-ray diffraction analysis results show that the deposited material is composed of a single phase and a copper-based solid solution. Some precipitate particles of metal silicides were observed in the interdendritic region by scanning electron mi-croscopy. The ultimate tensile strength along the laser scanning direction reaches 735 MPa. The hardness is about Hv0.1 300.
基金supported by the Chongqing Research Program of Basic Research and Frontier Technology(No.CSTC2013jcyjA50016)the National Natural Science Foundation of China(Nos.51401039,51571037 and 51204110)the Scientific and Technological Research Program of Chongqing Municipal Education Commission(No.KJ1709204).
文摘The approximately equimolar ratio A1CrNiSiTi multi-principal element alloy (MPEA) coatings were fab- ricated by laser cladding on Ti-6Al-4V (Ti64) alloy. Scanning electron microscopy (SEM), equipped with an energy-dispersive spectroscopy (EDS), and X-ray diffrac- tion (XRD) were used to characterize the microstructure and composition. Investigations show that the coatings consist of (Ti, Cr)5Si3 and NiA1 phases, formed by in situ reaction. The phase composition is initially explicated according to obtainable binary and ternary phase diagrams, and the formation Gibbs energy of TisSi3, VsSi3 and CrsSi3. Dry sliding reciprocating friction and wear tests of the A1CrNiSiTi coating and Ti64 alloy substrate without coating were evaluated. A surface mapping profiler was used to evaluate the wear volume. The worn surface was characterized by SEM-EDS. The hardness and wear resistance of the A1CrNiSiTi coating are well compared with that of the basal material (Ti64). The main wear mechanism of the AICrNiSiTi coating is slightly adhesive transfer from GCrl5 counterpart, and a mixed layer com- posed of transferred materials and oxide is formed.
基金financially supported by the National Basic Research Development Program of China(No.2011CB606305)
文摘Laser powder deposition was applied to fabricate the Ti-6.5Al-3.5Mo-1.5Zr-0.3Si (wt%)/Ti-47Al- 2Cr-2Nb-0.2W-0.15B (at%) bi-material system. The asdeposited TC11 alloy shows a basket-wave-like morphology while the as-deposited y-TiAl alloy consists of fully α2/γ lamellar microstructures. Regarding the thermal mismatch between TC11 and γ-TiAl during processing, the interface microstmcture evolution was concerned. The transformation pathway was illustrated. It is found that the content changes of Al elements and β-stabilizers Mo, Cr, and Nb are responsible for the evolution of microstructures at the interface. The fracture surfaces are located at the y-TiAl side. The bi-material shows a brittle-fracture manner, with the ultimate tensile strength of 560 MPa.