Microstructure evolution and mechanical property of Mg-3Al alloys with addition of Ca and Gd during rolling and annealing process

The formability of magnesium alloys at ambient temperature can be enhanced by alloying additions such as Ca and RE elements,which is ascribed to the weakened basal texture.To produce magnesium alloy sheets with excellent comprehensive performance,the evolution of texture characterization during fabrication process and subsequent effect of texture on mechanical properties are vital controlling factors.In this investigation,three experimental Mg-3Al series alloys were hot rolled and annealed to sheets with 1 mm thickness.The microstructure evolution during rolling and annealing process was investigated.Furthermore,the influence of texture on tensile properties along different tensile directions was also studied.The results show that weakened basal texture and refined grains were achieved with the co-addition of Ca and RE element.However,strengthening of mechanical properties wasn't obtained.During hot rolling process,microstructure was refined,second phase particles broken,and basal texture was increased.While basal texture was weakened during annealing process.Recrystallization behavior influenced by formation of second phase was dominated to attenuate basal texture.Tensile deformation behavior was controlled by basal slip and followed Schmid factor criterion.Moreover,the weakened basal texture and activation of non-basal slips during hot rolling process can contribute to diminish the anisotropy of tensile properties.

Characterizing changes in ecosystem service values in China's eastern Loess Plateau

Human activities such as the implementation of ecological protection projects and expansion of construction land can cause complex land use changes that affect ecosystem service values （ESV）. In this study, we investigated changes in ESV in response to land use changes in Ningwu County, in eastern Loess Plateau of China. Our aim is to provide guidance for sustainable land use planning in this region. We used remote sensing to evaluate land use changes, and applied a fast, proxy-based method for evaluating ESVat three points in time： 1990, 2000, and 2010. More than 89% of the total ESV in Ningwu County was attributable to woodland and grassland. The ESV in western mountain areas show the greatest increase from 1990 to 2010, but ESV decreased the most in the low-elevation northeastern area of flat terrain These tradeoffs led to a slight net decrease （1.0%） in Ningwu County＇s total ESV. Although the decline in ESV was relatively low compared to the rate of economic growth, total ESV was much lower than global and national average levels at the end of the study period.

Research advances in eco-hydrological process and function

Present studies on the coupling relationship and hydrology mechanism between basin ecosystem and hydrological process has become an international research frontier in hydrology. This paper investigates this coupling relationship, and also summarizes research and presents a method of combining isotopic technology with hydro-chemical methods, for the study of eco-hydrological process and function in different landscape zones. We then examine research trends for future direction and development of this field.

男性腺性膀胱炎的临床表现与治疗

目的:探讨男性腺性膀胱炎(CG)的临床表现与治疗效果。方法:回顾性分析我院1999年~2014年治疗的22例成年男性经病理证实为腺性膀胱炎的临床资料。本组22例患者年龄27~74岁,平均52.5岁。临床表现:尿频、尿急症状18例,尿痛13例,血尿7例,下腹部疼痛8例,有20例患者有临床症状经两周以上抗炎治疗或反复抗炎治疗疗效不佳。所有患者随访3~48个月。结果:22例患者均行经尿道膀胱病灶电切术并联合膀胱灌注治疗,有17例患者治愈或好转,4例临床症状无明显改善,有1例患者术后临床症状加重,经抗炎及膀胱灌注治疗6个月后好转,无恶变病例。结论:男性腺性膀胱炎呈逐渐多发趋势,应提高对男性腺性膀胱炎的重视及诊断水平,经尿道膀胱病灶电切术联合膀胱灌注治疗创伤小,疗效明确,适合临床推广。

Tuning exciton dynamics by the dielectric confinement effect in quasi-two-dimensional perovskites

The dielectric confinement effect plays an essential role in optoelectronic devices.Existing studies on the relationship between the dielectric confinement and the photoelectric properties are inadequate.Herein,three organic spacers with different dielectric constants are employed to tune the exciton dynamics of quasi-two-dimensional(quasi-2D)Ruddlesden–Popper perovskite films.Femtosecond transient absorption spectroscopy reveals that the small dielectric constant ligand enables a weak dynamic disorder and a large modulation depth of the coherent phonons,resulting in a more complete energy transfer and the inhibition of a trap-mediated nonradiative recombination.Additionally,the increase in the bulk-ligand dielectric constant reduces the corresponding exciton binding energy and then suppresses the Auger recombination,which is beneficial for high-luminance lightemitting diodes.This work emphasizes the importance of dielectric confinement for regulating the exciton dynamics of layered perovskites.

微生物胞外长距离电子传递网络研究进展

微生物的电子传递过程在生命进化和生物地球化学循环中发挥着关键作用。近年来,随着微生物电子传递研究的深入开展,微生物纳米导线、导电生物被膜及种间电子传递等多种新型的微生物胞外电子传递机制不断被发现,微生物电子传递的距离也从纳米级拓展至厘米级。这些微生物的长距离电子传递过程环环相扣、相互协同,从而构成长距离电子传递网络,并在物质循环和能量转化中共同发挥作用。微生物长距离电子传递网络的结构功能及其调控机制已成为多个学科共同关注的焦点。本文以电子传递的距离为主线,对不同尺度的微生物长距离电子传递过程及网络研究的新进展进行综述,包括纳米尺度的电子传递网络(周质空间和外膜表层)、微米至毫米尺度的电子传递网络(纳米导线、细胞间电子和导电生物被膜)、厘米尺度的电子传递网络(电缆细菌)等,并分析了该研究现存的主要问题和下一步的发展方向,以期为进一步推进微生物长距离电子传递网络理论和应用研究提供科学参考。

Photoluminescent chiral carbon dots derived from glutamine

The integration of luminescence and chirality in carbon dots(CDs) encourages candidates to explore novel functions and applications of CDs, however, the preparation of chiral CDs is very limited. Herein, we report a hydrothermal method to fabricate chiral CDs by utilizing amino acid enantiomers as the precursors. LGln-CDs or DGln-CDs with uniform size of 3–4 nm show excitation-dependent blue fluorescence in solutions. Circular dichroism measurement confirms the opposite optical rotation of chiral CDs in the region from 200 nm to 300 nm, and the signals can be regulated by concentrations of CDs solution. Timedependent density functional calculation reveals that polypeptides may exist on the surface of CDs due to the polycondensation of L/DGln at high temperature, and the optical activity of CDs originates from the stacking of neighboring carbonyl groups. The facile synthetic methodology proposed will provide potential opportunities for the preparation and application of chiral and chiroptical CDs-based materials.