Crystal defect engineering is widely used as an effective approach to regulate the optical and optoelectronic properties of semiconductor nanostructures.However,photogenerated electron-hole pair recombination centers ...Crystal defect engineering is widely used as an effective approach to regulate the optical and optoelectronic properties of semiconductor nanostructures.However,photogenerated electron-hole pair recombination centers caused by structural defects usually lead to the reduction of optoelectronic performance.In this work,a high-performance photodetector based on(GaN)_(1-x)(ZnO)_(x)solid solution nanowire with bicrystal structure is fabricated and it shows excellent photoresponse to ultraviolet and visible light.The highest responsivity of the photodetector is as high as 60,86 and 43 A/W under the irradiation of365 nm,532 nm and 650 nm,respectively.The corresponding response time is as fast as 170,320 and 160 ms.Such wide spectral responses can be attributed to various intermediate energy levels induced by the introduction of various structural defects and dopants in the solid solution nanowire.Moreover,the peculiar bicrystal boundary along the axial direction of the nanowire provides two parallel and fast transmission channels for photo-generated carriers,reducing the recombination of photo-generated carriers.Our findings provide a valued example using crystal defect engineering to broaden the photoresponse range and improve the photodetector performance and thus can be extended to other material systems for various optoelectronic applications.展开更多
The morphology evolution and magnetic properties of Co films–native oxide Si(100)were investigated at 873,973,and 1073 K in a high magnetic field of 11.5 T.Formation of Kirkendall voids in the Co films was found to c...The morphology evolution and magnetic properties of Co films–native oxide Si(100)were investigated at 873,973,and 1073 K in a high magnetic field of 11.5 T.Formation of Kirkendall voids in the Co films was found to cause morphology evolution due to the difference in diffusion flux of Co and Si atoms through the native oxide layer.The high magnetic fields had considerable effect on the morphology evolution by accelerating nanoscale Kirkendall effect.The diffusion mechanism in the presence of high magnetic fields was given to explain the increase of diffusion coefficient.The morphology evolution of Co films on native oxide Si(100)under high magnetic fields during annealing resulted in the magnetic properties variation.展开更多
Recent years have witnessed an unprecedented explosion of scientific knowledge and advances in human microbiome research due to the emerging high-throughput molecular technologies. The term human microbiome refers to ...Recent years have witnessed an unprecedented explosion of scientific knowledge and advances in human microbiome research due to the emerging high-throughput molecular technologies. The term human microbiome refers to the population of microorganisms, including bacteria, viruses, fungi and protozoan, and their genetic material that live on and inside the human organisms (skin, mucous membranes, intestinal tract, etc.) (Honey, 2008). A search of the literature at PubMed for the term "microbiome" in the title and abstract illustrates the fast progression of microbiome science. From 2006 to 2010 there were just 304 papers that used the word microbiome in their title and/or abstract, whereas the number has increased to 11,128 from 2011 to 2017.展开更多
The quantum limit, where only the lowest Landau level is occupied by electrons, can be achieved under a high magnetic field when the Landau level splitting is comparable with the Fermi energy. The rather small Fermi p...The quantum limit, where only the lowest Landau level is occupied by electrons, can be achieved under a high magnetic field when the Landau level splitting is comparable with the Fermi energy. The rather small Fermi pockets and Fermi energy in CaFeAsF reported recently make this compound a good candidate for investigating the electrical transport near the quantum limit.Here, we report high-field experiments up to 65 T on a single-crystalline CaFeAsF, which shows a metal-insulator quantum phase transition tuned by the out-of-plane magnetic field. The obtained critical exponent zν through the finite-size scaling analysis is very close to 4/3. This transition is closely associated with the evolution of electronic states approaching the quantum limit.The resistivity behaviors as a function of field and temperature were evaluated based on Adams-Holstein theory(A-H theory).Moreover, the in-plane component of the field, which does not affect the transport behavior in the classical region, suppressed the magnetoresistance near the quantum limit.展开更多
All iron-based superconductors, regardless of their detailed crystal structure, share the same conductive Fe2X2 (X = As, P, Se, and S) layers as the crucial structural unit [1-8]. In the Fe2X2 layers, edge-shared Fe...All iron-based superconductors, regardless of their detailed crystal structure, share the same conductive Fe2X2 (X = As, P, Se, and S) layers as the crucial structural unit [1-8]. In the Fe2X2 layers, edge-shared FeX4 tetrahedra form a square lattice in quasi-two-dimensional (quasi-2D) planes. One may wonder what kind of properties will be manifested in the quasi-one-dimensional (quasi-1 D) counterparts exhibiting an identical coordination as the above-mentioned quasi-2D cases. Theoretical proposals on magnetic states and possible superconductivity have been reported in the recent five years [9-11]. Recently, a quasi-lD compound, BaFe:S3, with FeX4 tetrahedra extending along one direction, was studied and found to be superconductive at pressure around 11 GPa [ 12,13].展开更多
Crystal structure of Ti_(5)Al_(2)C_(3)was determined by means of X-ray powder diffraction(XRPD),transmission electron microscopy(TEM)and ab initio calculations.In contrast to the already known P63/mmc space group that...Crystal structure of Ti_(5)Al_(2)C_(3)was determined by means of X-ray powder diffraction(XRPD),transmission electron microscopy(TEM)and ab initio calculations.In contrast to the already known P63/mmc space group that the MAX phases crystallize,it was demonstrated that the R3_m space group could better satisfy the experimental data.The lattice parameters are a=0.30564 nm,c=4.81846 nm in a hexagonal unit cell.展开更多
The gut microbiome has attracted increasing attention over the past 15 years.Along with the fast-growing body of research literature and media reports,the public's opinions on the gut microbiome have begun to appe...The gut microbiome has attracted increasing attention over the past 15 years.Along with the fast-growing body of research literature and media reports,the public's opinions on the gut microbiome have begun to appear polarized.Some believe that the gut microbiome is at the core of human health and is related to every single disease.To the opposite,some people question the scientific basis of gut microbiome studies and criticize that many of them are farfetched;there is even a joke spreading in the biomedical research field—"keeping gut microbiome in mind,no mechanism is hard to find".展开更多
Highly efficient Co_(3)O_(4)/TiO_(2) monolithic catalysts with enhanced stability were in-situ grown on Ti mesh for CO oxidation,which could completely oxidize CO at 120℃.The comprehensive catalytic performance is co...Highly efficient Co_(3)O_(4)/TiO_(2) monolithic catalysts with enhanced stability were in-situ grown on Ti mesh for CO oxidation,which could completely oxidize CO at 120℃.The comprehensive catalytic performance is competitive to some noble metal catalysts and conventional Co_(3)O_(4) powder catalysts,which holds great potential toward industrial applications.Meanwhile,the in-situ synthesis strategy of Co_(3)O_(4)/TiO_(2) monolithic catalysts on flexible mesh substrate in this work can be extended to the development of a variety of oxide-based monolithic catalysts towards diverse catalysis applications.展开更多
基金partially supported by the National Natural Science Foundation of China(Nos.51702326 and 51872296)the Liaoning Province Natural Science Foundation(No.2019-MS333)+3 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2019197)the Shenyang National Laboratory for Materials Science(No.L2019F36)the Shenyang Planning Project of Science and Technology(No.18-013-0-52)Tomsk Polytechnic University Competitiveness Enhancement Program grant with project number TPU CEP NOC N.M.Kizhnera188/2020。
文摘Crystal defect engineering is widely used as an effective approach to regulate the optical and optoelectronic properties of semiconductor nanostructures.However,photogenerated electron-hole pair recombination centers caused by structural defects usually lead to the reduction of optoelectronic performance.In this work,a high-performance photodetector based on(GaN)_(1-x)(ZnO)_(x)solid solution nanowire with bicrystal structure is fabricated and it shows excellent photoresponse to ultraviolet and visible light.The highest responsivity of the photodetector is as high as 60,86 and 43 A/W under the irradiation of365 nm,532 nm and 650 nm,respectively.The corresponding response time is as fast as 170,320 and 160 ms.Such wide spectral responses can be attributed to various intermediate energy levels induced by the introduction of various structural defects and dopants in the solid solution nanowire.Moreover,the peculiar bicrystal boundary along the axial direction of the nanowire provides two parallel and fast transmission channels for photo-generated carriers,reducing the recombination of photo-generated carriers.Our findings provide a valued example using crystal defect engineering to broaden the photoresponse range and improve the photodetector performance and thus can be extended to other material systems for various optoelectronic applications.
基金the National Natural Science Foundation of China(Nos.51425401,51690162)Liaoning Innovative Research Team in University(No.LT2017011)the Fundamental Research Funds for the Central Universities(Nos.N160907001,N180915002 and N180912004)。
文摘The morphology evolution and magnetic properties of Co films–native oxide Si(100)were investigated at 873,973,and 1073 K in a high magnetic field of 11.5 T.Formation of Kirkendall voids in the Co films was found to cause morphology evolution due to the difference in diffusion flux of Co and Si atoms through the native oxide layer.The high magnetic fields had considerable effect on the morphology evolution by accelerating nanoscale Kirkendall effect.The diffusion mechanism in the presence of high magnetic fields was given to explain the increase of diffusion coefficient.The morphology evolution of Co films on native oxide Si(100)under high magnetic fields during annealing resulted in the magnetic properties variation.
基金This study was supported by project "Ethical, legal, and social implications of human microbiome research" funded by China National Social Science Foundation (16CZX064). We are very grateful for the insights from anonymous reviewers.
文摘Recent years have witnessed an unprecedented explosion of scientific knowledge and advances in human microbiome research due to the emerging high-throughput molecular technologies. The term human microbiome refers to the population of microorganisms, including bacteria, viruses, fungi and protozoan, and their genetic material that live on and inside the human organisms (skin, mucous membranes, intestinal tract, etc.) (Honey, 2008). A search of the literature at PubMed for the term "microbiome" in the title and abstract illustrates the fast progression of microbiome science. From 2006 to 2010 there were just 304 papers that used the word microbiome in their title and/or abstract, whereas the number has increased to 11,128 from 2011 to 2017.
基金supported by the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant Nos. 2015187, and 2016215)National Natural Science Foundation of China (Grant Nos. 11574338, 11204338, and 11404359)and the ”Strategic Priority Research Program (B)” of the Chinese Academy of Sciences (Grant No. XDB04040300)
文摘The quantum limit, where only the lowest Landau level is occupied by electrons, can be achieved under a high magnetic field when the Landau level splitting is comparable with the Fermi energy. The rather small Fermi pockets and Fermi energy in CaFeAsF reported recently make this compound a good candidate for investigating the electrical transport near the quantum limit.Here, we report high-field experiments up to 65 T on a single-crystalline CaFeAsF, which shows a metal-insulator quantum phase transition tuned by the out-of-plane magnetic field. The obtained critical exponent zν through the finite-size scaling analysis is very close to 4/3. This transition is closely associated with the evolution of electronic states approaching the quantum limit.The resistivity behaviors as a function of field and temperature were evaluated based on Adams-Holstein theory(A-H theory).Moreover, the in-plane component of the field, which does not affect the transport behavior in the classical region, suppressed the magnetoresistance near the quantum limit.
基金supported by the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.2015187)the National Natural Science Foundation of China(Grant Nos.11204338,11574338,and51572165)+2 种基金the“Strategic Priority Research Program(B)”of the Chinese Academy of Sciences(Grant No.XDB04040300)the National Key R&D Program(Grant No.2016YFF0101701)the Science and Technology Commission of Shanghai Municipality(Grant Nos.16521108400,16DZ0504300,and 14521102800)
文摘All iron-based superconductors, regardless of their detailed crystal structure, share the same conductive Fe2X2 (X = As, P, Se, and S) layers as the crucial structural unit [1-8]. In the Fe2X2 layers, edge-shared FeX4 tetrahedra form a square lattice in quasi-two-dimensional (quasi-2D) planes. One may wonder what kind of properties will be manifested in the quasi-one-dimensional (quasi-1 D) counterparts exhibiting an identical coordination as the above-mentioned quasi-2D cases. Theoretical proposals on magnetic states and possible superconductivity have been reported in the recent five years [9-11]. Recently, a quasi-lD compound, BaFe:S3, with FeX4 tetrahedra extending along one direction, was studied and found to be superconductive at pressure around 11 GPa [ 12,13].
基金This work was funded by the NSFC under Grant No.50832008,Grant No.91226202 and the IMR innovative research foundation.
文摘Crystal structure of Ti_(5)Al_(2)C_(3)was determined by means of X-ray powder diffraction(XRPD),transmission electron microscopy(TEM)and ab initio calculations.In contrast to the already known P63/mmc space group that the MAX phases crystallize,it was demonstrated that the R3_m space group could better satisfy the experimental data.The lattice parameters are a=0.30564 nm,c=4.81846 nm in a hexagonal unit cell.
基金This work was supported by National Key Research and Development Program of China(2018YFC2000500)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB29020000)+1 种基金the National Natural Science Foundation of China(31771481,91857101)the National Social Science Foundation of China(16CZX064).We thank Prof.Liping Zhao from Shanghai Jiao Tong University for insightful advice and the many researchers,clinicians and industry specialists who participated in the discussion and provided valuable suggestions.
文摘The gut microbiome has attracted increasing attention over the past 15 years.Along with the fast-growing body of research literature and media reports,the public's opinions on the gut microbiome have begun to appear polarized.Some believe that the gut microbiome is at the core of human health and is related to every single disease.To the opposite,some people question the scientific basis of gut microbiome studies and criticize that many of them are farfetched;there is even a joke spreading in the biomedical research field—"keeping gut microbiome in mind,no mechanism is hard to find".
基金partially supported by the National Natural Science Foundation of China(No.51872296)the Joint Fund between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals(No.18LHPY012)。
文摘Highly efficient Co_(3)O_(4)/TiO_(2) monolithic catalysts with enhanced stability were in-situ grown on Ti mesh for CO oxidation,which could completely oxidize CO at 120℃.The comprehensive catalytic performance is competitive to some noble metal catalysts and conventional Co_(3)O_(4) powder catalysts,which holds great potential toward industrial applications.Meanwhile,the in-situ synthesis strategy of Co_(3)O_(4)/TiO_(2) monolithic catalysts on flexible mesh substrate in this work can be extended to the development of a variety of oxide-based monolithic catalysts towards diverse catalysis applications.