This paper reports observations of significant synergistic effects between dielectric barrier discharge (DBD) plasmas and Cu-ZSM-5 catalysts for C2H4 selective reduction of NOx at 250 °C in the presence of excess...This paper reports observations of significant synergistic effects between dielectric barrier discharge (DBD) plasmas and Cu-ZSM-5 catalysts for C2H4 selective reduction of NOx at 250 °C in the presence of excess oxygen by using a one-stage plasma-over-catalyst (POC) reactor. With the reactant gas mixture of 530 ppm NO, 650 ppm C2H4, 5.8% O2 in N2 and GHSV = 12000 h-1, the pure catalytic, pure plasma-induced (discharges over fused silica pellets) and plasma- catalytic (in the POC reactor) NOx conversion are 39%, 1.5% and 79%, respectively. The in-situ optical emission spectra of the reactive systems imply some short-lived active species formed from plasma-induced and plasma-catalytic processes may be responsible to the observed synergistic effects in this one-stage POC system.展开更多
Interaction between two spheres with an interstitial fluid is essential in Discrete Element modeling for simulating the behaviors of 'wet' particulate materials. In this paper the interaction between two spher...Interaction between two spheres with an interstitial fluid is essential in Discrete Element modeling for simulating the behaviors of 'wet' particulate materials. In this paper the interaction between two spheres with an interstitial Power-law fluid was approximately resolved as normal and tangential interactive models respe ctively, for which the governing equations were simplified on the basis of Reynolds approximation. These equations were then solved analytically together with the boundary conditions to obtain the pressure distributions for each individual model, and event u-ally solutions of the viscous squeeze force and the tangential viscous resistance were obtained, which provide a set of solutions for implementing into DEM code or other purposes.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.20077005)the National High Technology Research and Development Program("863 Programm”)of China(Grant No.2002AA649140)the Provincial Grants of Science and Technology of Liaoning,China(No.20022112).
文摘This paper reports observations of significant synergistic effects between dielectric barrier discharge (DBD) plasmas and Cu-ZSM-5 catalysts for C2H4 selective reduction of NOx at 250 °C in the presence of excess oxygen by using a one-stage plasma-over-catalyst (POC) reactor. With the reactant gas mixture of 530 ppm NO, 650 ppm C2H4, 5.8% O2 in N2 and GHSV = 12000 h-1, the pure catalytic, pure plasma-induced (discharges over fused silica pellets) and plasma- catalytic (in the POC reactor) NOx conversion are 39%, 1.5% and 79%, respectively. The in-situ optical emission spectra of the reactive systems imply some short-lived active species formed from plasma-induced and plasma-catalytic processes may be responsible to the observed synergistic effects in this one-stage POC system.
文摘Interaction between two spheres with an interstitial fluid is essential in Discrete Element modeling for simulating the behaviors of 'wet' particulate materials. In this paper the interaction between two spheres with an interstitial Power-law fluid was approximately resolved as normal and tangential interactive models respe ctively, for which the governing equations were simplified on the basis of Reynolds approximation. These equations were then solved analytically together with the boundary conditions to obtain the pressure distributions for each individual model, and event u-ally solutions of the viscous squeeze force and the tangential viscous resistance were obtained, which provide a set of solutions for implementing into DEM code or other purposes.
