Impact of annealing temperature on the ferroelectric properties of W/Hf_(0.5)Zr_(0.5)O_(2)/W capacitor

Crystallization annealing is a crucial process for the formation of the ferroelectric phase in HfO_(2)-based ferroelectric thin films.Here,we systematically investigate the impact of the annealing process,with temperature varied from 350℃to 550℃,on the electricity,ferroelectricity and reliability of a Hf_(0.5)Zr_(0.5)O_(2)(HZO;7.5 nm)film capacitor.It was found that HZO film annealed at a low temperature of 400℃can effectively suppress the formation of the monoclinic phase and reduce the leakage current.HZO film annealed at 400℃also exhibits better ferroelectric properties than those annealed at 350℃and 550℃.Specifically,the 400℃-annealed HZO film shows an outstanding 2Pr value of 54.6μC·cm^(-2)at±3.0 MV·cm^(-1),which is relatively high compared with previously reported values for HZO film under the same electric field and annealing temperature.When the applied electric field increases to±5.0 MV·cm^(-1),the 2Pr value can reach a maximum of 69.6μC·cm^(-2).In addition,the HZO films annealed at 400℃and 550℃can endure up to bout 2.3×10^(8)cycles under a cycling field of 2.0 MV·cm^(-1)before the occurrence of breakdown.In the 400℃-annealed HZO film,72.1%of the initial polarization is maintained while only 44.9%is maintained in the 550℃-annealed HZO film.Our work demonstrates that HZO film with a low crystallization temperature(400℃)has quite a high ferroelectric polarization,which is of significant importance in applications in ferroelectric memory and negative capacitance transistors.

Hydrophobic epoxy resin coating with ionic liquid conversion pretreatment on magnesium alloy for promoting corrosion resistance

A hydrophobic epoxy resin coating with an environmental-friendly deep eutectic solvent(DES)-based conversion pretreatment was proposed to enhance the corrosion resistance of magnesium alloys.The hydrophobic epoxy resin coatings on the AZ31B magnesium alloy with and without the DES-based conversion pretreatment were thoroughly compared.It is found that the DES-based conversion film on the AZ31B magnesium alloy is mainly composed of MgH2,MgO and MgCO3.Furthermore,the conversion film possesses porous structure,which provides more anchor points for the following epoxy resin coating.However,without the DES-conversion pretreatment,the epoxy resin is difficult to be attached on the substrate during the dip-coating process.The double layered hybrid coating system promotes the corrosion resistance of the magnesium alloys significantly,which can be ascribed to the unique architecture and component including the hydrophobicity of the surface layer,the dense and interlocked epoxy resin,and the corrosion resistant DES-based conversion pretreatment.

Multiple plasmon couplings in 3D hybrid Au-nanoparticles-decorated Ag nanocone arrays boosting highly sensitive surface enhanced Raman scattering

Plasmon coupling is an essential strategy to realize strong local electromagnetic(EM)field which is crucial for high-performance plasmonic devices.In this work,multiple plasmon couplings are demonstrated in three-dimensional(3D)hybrid plasmonic systems composed of polydimethylsiloxane-supported ordered silver nanocone(AgNC)arrays decorated with high-density gold nanoparticles(AuNPs)which are fabricated by a template-assisted physical vapor deposition process.Strong interparticle coupling,particle-film coupling,inter-cone coupling,and particle-cone coupling are revealed by numerical simulations in such composite nanostructures,which produce intense and high-density EM hot spots,boosting highly sensitive and reproducible surface enhanced Raman scattering(SERS)detection with an enhancement factor of-1.74×10^(8).Furthermore,a linear correlation between logarithmic Raman intensity and logarithmic concentration of probe molecules is observed in a large concentration range.These results offer new ideas to develop novel plasmonic devices,and provide alternative strategy to realize flexible and high-performance SERS sensors for trace molecule detection and quantitative analysis.