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A theoretical study on gaseous pollutant flushing of natural ventilation driven by buoyancy forces in industrial buildings
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作者 Jiawei Zhuang Genyang Chen +4 位作者 Rumeng Yang Kun Han Dongdong Tian yongfa diao Henggen Shen 《Building Simulation》 SCIE EI CSCD 2024年第4期575-589,共15页
The acceleration of industrialization worsening indoor environments of industrial buildings has drawn more attention in recent years.Natural ventilation can improve indoor air quality(IAQ)and reduce carbon emissions.T... The acceleration of industrialization worsening indoor environments of industrial buildings has drawn more attention in recent years.Natural ventilation can improve indoor air quality(IAQ)and reduce carbon emissions.To evaluate gaseous pollutant levels in industrial buildings for the development of buoyancy-driven natural ventilation,two theoretical models of pollutant flushing(Model I and Model II)are developed based on the existing thermal stratification theory in combination with the mixing characteristics of lower pollutant.The results show that indoor pollutant flushing is mainly dependent on the pollution source intensity and effective ventilation area.The mixing characteristics of lower pollutant has an important effect on pollutant stratification and evolution during ventilation,but it does not change the prediction results at steady state.When the dimensionless pollution source intensity is larger than 1,the pollution source should be cleaned up or other ventilation methods should be used instead to improve IAQ.In addition,the comparisons between Model I and Model II on instantaneous pollutant concentration are significantly influenced by the pollution source intensity,and the actual pollutant concentration is more likely to be between the predicted values of Model I and Model II.To reduce pollutant concentration to a required level,the pollution source intensity should be in a certain range.The theoretical models as well as the necessary conditions for ventilation effectiveness obtained can be used for the ventilation optimization design of industrial buildings. 展开更多
关键词 industrial buildings buoyancy-driven natural ventilation gaseous pollutants evolution model pollution sources
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NO_(2)和SO_(3)氧化聚苯硫醚的密度泛函理论计算 被引量:1
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作者 李子航 刁永发 +2 位作者 张俪安 周发山 陆遥 《过程工程学报》 CAS CSCD 北大核心 2021年第9期1099-1107,共9页
通过密度泛函理论(Density Functional Theory,DFT)中的B3LYP-D3/6-31G(d,p)方法研究二氧化氮(NO_(2))、三氧化硫(SO_(3))氧化聚苯硫醚(Polyphenylene Sulfide,PPS)生成亚砜与砜结构的过渡态,并使用内禀反应坐标(Intrinsic Reaction Coo... 通过密度泛函理论(Density Functional Theory,DFT)中的B3LYP-D3/6-31G(d,p)方法研究二氧化氮(NO_(2))、三氧化硫(SO_(3))氧化聚苯硫醚(Polyphenylene Sulfide,PPS)生成亚砜与砜结构的过渡态,并使用内禀反应坐标(Intrinsic Reaction Coordinate,IRC)确认其连接的反应物和产物,考察了PPS被氧化的反应路径,指出反应中分子几何结构与原子电荷的改变,揭示了NO_(2),SO_(3)氧化PPS滤料的微观机理。在此基础上,进一步计算不同温度下PPS氧化过程中的自由能垒,通过反应速率常数与半衰期定量比较NO_(2),SO_(3)氧化PPS的能力。结果表明,在180~220℃范围内,SO_(3)氧化PPS生成亚砜的反应速率常数是NO_(2)的107倍;SO_(3)氧化亚砜结构生成砜结构的反应速率常数是NO_(2)的104倍,即SO_(3)对于PPS分子链上S原子的氧化能力远强于NO_(2);在实际环境中NO_(2)除了直接氧化PPS外,还可能存在能垒更低的反应路径。 展开更多
关键词 计算化学 聚苯硫醚 密度泛函理论 自由能垒 反应速率常数
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不同排列结构的纤维层对捕集PM2.5性能影响的数值模拟 被引量:1
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作者 楚明浩 刁永发 +1 位作者 张俪安 庄加玮 《过程工程学报》 CAS CSCD 北大核心 2021年第5期541-549,共9页
基于离散颗粒模型(Discrete Phase Model, DPM)研究了三种纤维排列结构捕集颗粒物规律。模拟了不同排列结构的纤维层在拦截和惯性碰撞两种捕集机制下捕集颗粒物的性能,考察了颗粒物粒径、入口风速和纤维层填充率对平行排列、单层垂直排... 基于离散颗粒模型(Discrete Phase Model, DPM)研究了三种纤维排列结构捕集颗粒物规律。模拟了不同排列结构的纤维层在拦截和惯性碰撞两种捕集机制下捕集颗粒物的性能,考察了颗粒物粒径、入口风速和纤维层填充率对平行排列、单层垂直排列和双层垂直排列纤维层捕集颗粒物性能的影响。结果表明,当颗粒物粒径为0.5~2.5μm,风速为0.6 m/s时,垂直纤维层捕集颗粒物对粒径为1.5μm及以上颗粒物的捕集性能增强,捕集性能在粒径为2.0μm时达到最大;入口风速为0.2~0.8 m/s,颗粒物粒径为2.5μm时,单层垂直纤维层结构颗粒物捕集效率随风速增加而增加,并高于平行排列结构和双层垂直排列结构,且其捕集性能随风速增加而降低;纤维层的填充率为6.0%~22.4%,颗粒物粒径为2.5μm时,纤维层对颗粒物的捕集效率随填充率增加而增加,捕集颗粒物性能随填充率增加而降低,单层垂直纤维层结构捕集效率始终高于另外两种结构;单层垂直纤维层结构对颗粒物的捕集速率最大。 展开更多
关键词 多纤维结构 数值模拟 捕集效率 质量因子
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磁性纤维直径对捕集Fe基细颗粒影响数值模拟
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作者 贾中坚 刁永发 +2 位作者 张俪安 楚明浩 沈恒根 《过程工程学报》 CAS CSCD 北大核心 2021年第8期926-934,共9页
为了实现对钢铁行业微细颗粒的超低排放,提出磁性纤维提高对Fe基细颗粒物的捕集。基于计算流体力学-离散相模型CFD-DPM对比研究了传统纤维、磁性纤维直径对Fe基细颗粒捕集效率以及过滤阻力的影响。结果表明:当风速为0.10m/s时,对于直径... 为了实现对钢铁行业微细颗粒的超低排放,提出磁性纤维提高对Fe基细颗粒物的捕集。基于计算流体力学-离散相模型CFD-DPM对比研究了传统纤维、磁性纤维直径对Fe基细颗粒捕集效率以及过滤阻力的影响。结果表明:当风速为0.10m/s时,对于直径为35~45μm范围的纤维,直径的增大能够明显增加过滤阻力。对于粒径小于2.5μm的颗粒,磁性纤维直径的增加对捕集效率提高的影响相对较小,当颗粒粒径大于2.5μm时,增大纤维直径能够显著提高捕集效率。风速处于0.01~0.05 m/s范围时,增大纤维直径对提高磁性纤维捕集效率作用明显;当风速为0.08~0.10 m/s时,纤维直径变化对捕集效率的影响较小。磁性纤维质量因子随纤维直径增大而下降。 展开更多
关键词 纤维直径 Fe基细颗粒 磁性纤维 质量因子 PM2.5
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Experimental study on PM2.5 removal by magnetic polyimide loaded with cobalt ferrate 被引量:3
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作者 Fashan Zhou yongfa diao +2 位作者 Ruge Wang Bingwen Yang Teng Zhang 《Energy and Built Environment》 2020年第4期404-409,共6页
A novel functional magnetic polyimide loaded with cobalt ferrite nanoparticles by coprecipitation method was proposed,and XRD,FTIR,SEM technologies were employed to study their physicochemical properties.The filtra-ti... A novel functional magnetic polyimide loaded with cobalt ferrite nanoparticles by coprecipitation method was proposed,and XRD,FTIR,SEM technologies were employed to study their physicochemical properties.The filtra-tion performance of non-magnetic and magnetic polyimide were examined by experimental system.The effects of dust resistance,filtration velocity and initial dust concentration on the filtration performance of magnetic polyimide were investigated under different dust loadings.The results revealed that presence of𝜌-лconjuga-tion between the cobalt ferrite and polyimide fiber resulted in easily load on the fiber surface for cobalt ferrite nanoparticles.The magnetic polyimide exhibited good filtration efficiency especially in the range of particle size less than 2μm.The filtration efficiency of magnetic polyimide filter materials increased by nearly 20%com-pared with the primary polyimide.Due to the loading of cobalt ferrite,the resistance of the magnetic polyimide increased,while the resistance growth rate decreased from 100%to 29%with increased filtration velocity from 0.5 m/min to 2.5 m/min. 展开更多
关键词 Magnetic polyimide Cobalt ferrite PM2.5 Filtration performance
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