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Practical CuCl/DABCO/4-HO-TEMPO-catalyzed oxidative synthesis of nitriles from alcohols with air as oxidant
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作者 yongke hu Lei Chen Bindong Li 《Chinese Chemical Letters》 SCIE CAS CSCD 2018年第3期464-466,共3页
A mild and efficient methodology for the direct oxidative synthesis of nitriles from easily available alcohols and aqueous ammonia by employing CuCI/DABCO/4-HO-TEMPO as the catalysts is described. This protocol uses t... A mild and efficient methodology for the direct oxidative synthesis of nitriles from easily available alcohols and aqueous ammonia by employing CuCI/DABCO/4-HO-TEMPO as the catalysts is described. This protocol uses the air as a green oxidant and aqueous ammonia as the nitrogen source at room temperature, A variety of aryl, heterocyclic and allylic alcohols are smoothly converted into the corresponding nitriles in good to excellent yields. 展开更多
关键词 Nitriles Alcohols Copper 4-HO-TEMPO Aerobic oxidation
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