The hierarchical porous nitrogen-doped carbon materials (HNCs) were prepared by using nitrogen containing gelatin as the carbon source and nano-silica obtained by a simple flame synthesis approach as the template. A...The hierarchical porous nitrogen-doped carbon materials (HNCs) were prepared by using nitrogen containing gelatin as the carbon source and nano-silica obtained by a simple flame synthesis approach as the template. All of the as-obtained HNCs show much higher Li storage capacity as compared with commercial graphite. Specifically, HNC-700 with biggest micropore volume and highest nitrogen content exhibited optimal reversible capacities of 1084 mAh·g^-1 at the current density of 37.2 mA·g^-1 (0.1 C) and 309 mAh·g^-1 even at 3.72 A·g^-1 (10 C). This result suggests that HNCs should be a promising candidate for anode materials in high-rate lithium ion batteries (LIBs).展开更多
基金We greatly appreciate the Natural Science Foundation of China (No. 21275104) for supporting this work.
文摘The hierarchical porous nitrogen-doped carbon materials (HNCs) were prepared by using nitrogen containing gelatin as the carbon source and nano-silica obtained by a simple flame synthesis approach as the template. All of the as-obtained HNCs show much higher Li storage capacity as compared with commercial graphite. Specifically, HNC-700 with biggest micropore volume and highest nitrogen content exhibited optimal reversible capacities of 1084 mAh·g^-1 at the current density of 37.2 mA·g^-1 (0.1 C) and 309 mAh·g^-1 even at 3.72 A·g^-1 (10 C). This result suggests that HNCs should be a promising candidate for anode materials in high-rate lithium ion batteries (LIBs).