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Silver-catalyzed three-component reaction of phenyldiazoacetate with arylamine and imine
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作者 Bai‐Ling Chen Zhen Wang +2 位作者 you‐can zhang Zhi‐Gang Zhao Zili Chen 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第10期1594-1598,共5页
A new method was developed to diastereoselectively synthesize polysubstituted 1,2‐diamine compounds from the reaction of diazoesters with arylamines and diaryl imines by using the dioxazoline ligand L2‐ligated silve... A new method was developed to diastereoselectively synthesize polysubstituted 1,2‐diamine compounds from the reaction of diazoesters with arylamines and diaryl imines by using the dioxazoline ligand L2‐ligated silver catalyst.The Lewis acidity of the silver catalyst affected the different types of substrate diastereoselectivities;It also led to the formation of amine‐exchange side products. 展开更多
关键词 Silver catalysis Carbene transfer reaction Three‐component reaction Ammonium ylide Diamine compouds
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