Owing to the wide range and low cost of sodium resources,sodium-ion batteries(SIBs)have received extensive attention and research.Metal sulfides with high theoretical capacity are used as promising anode materials for...Owing to the wide range and low cost of sodium resources,sodium-ion batteries(SIBs)have received extensive attention and research.Metal sulfides with high theoretical capacity are used as promising anode materials for SIBs.This paper presents the electrochemical performance of the binder-free NiS_(2)nanosheet arrays grown on stainless steel(SS)substrate(NiS_(2)/SS)using an in situ growth and sulfidation strategy as anode for sodium ion batteries.Owing to the close connection between the NiS_(2)nanosheet arrays and the SS current collector,the NiS_(2)/SS anode demonstrates high rate capability with a reversible capacity of 492.5 mAh·g^(-1)at 5.0C rate.Such rate capability is superior to that of NiS_(2)nanoparticles(NiS_(2)/CMC:41.7 mAh·g^(-1)at 5.0C,NiS_(2)/PVDF:7.3 mAh·g^(-1)at 5.0C)and other Ni sulfides(100–450 mAh·g^(-1)at 5.0C)reported.Furthermore,the initial reversible specific capacity and Coulombic efficiency of NiS_(2)/SS are 786.5 mAh·g^(-1)and 81%,respec-tively,demonstrating a better sodium storage ability than those of most NiS_(2)anodes reported for SIBs.In addition,the amorphization and conversion mechanism during the sodiation/desodiation process of NiS_(2)are proposed after investigation by in situ X-ray diffraction(XRD)measurements of intermediate products at successive charge/discharge stages.展开更多
基金the National Natural Science Foundation of China(No.21673051)the Department of Science and Technology of Guangdong Province(No.2019A050510043)the Department of Science and Technology of Zhuhai City,China(No.ZH22017001200059PWC)。
文摘Owing to the wide range and low cost of sodium resources,sodium-ion batteries(SIBs)have received extensive attention and research.Metal sulfides with high theoretical capacity are used as promising anode materials for SIBs.This paper presents the electrochemical performance of the binder-free NiS_(2)nanosheet arrays grown on stainless steel(SS)substrate(NiS_(2)/SS)using an in situ growth and sulfidation strategy as anode for sodium ion batteries.Owing to the close connection between the NiS_(2)nanosheet arrays and the SS current collector,the NiS_(2)/SS anode demonstrates high rate capability with a reversible capacity of 492.5 mAh·g^(-1)at 5.0C rate.Such rate capability is superior to that of NiS_(2)nanoparticles(NiS_(2)/CMC:41.7 mAh·g^(-1)at 5.0C,NiS_(2)/PVDF:7.3 mAh·g^(-1)at 5.0C)and other Ni sulfides(100–450 mAh·g^(-1)at 5.0C)reported.Furthermore,the initial reversible specific capacity and Coulombic efficiency of NiS_(2)/SS are 786.5 mAh·g^(-1)and 81%,respec-tively,demonstrating a better sodium storage ability than those of most NiS_(2)anodes reported for SIBs.In addition,the amorphization and conversion mechanism during the sodiation/desodiation process of NiS_(2)are proposed after investigation by in situ X-ray diffraction(XRD)measurements of intermediate products at successive charge/discharge stages.
