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甘氨酸催化下串联合成香豆素-3-羧酸
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作者 董军 陈友威 +3 位作者 常伟 桑泽矾 曾子航 徐国栋 《大学化学》 CAS 2023年第12期205-211,共7页
“香豆素-3-羧酸的制备”是基础有机化学实验中一个经典的任务型教学实验。在实验过程中,我们发现香豆素-3-羧酸的合成步骤繁琐,时间较长,试剂环保性不足。为了提升该实验的有效时长,加强实验过程的绿色环保性,提升实验的拓展性与探究性... “香豆素-3-羧酸的制备”是基础有机化学实验中一个经典的任务型教学实验。在实验过程中,我们发现香豆素-3-羧酸的合成步骤繁琐,时间较长,试剂环保性不足。为了提升该实验的有效时长,加强实验过程的绿色环保性,提升实验的拓展性与探究性,我们对该制备反应进行了改进。改进后的实验用水作为溶剂,在回流条件下,以甘氨酸作为催化剂,从丙二酸环(亚)异丙酯与水杨醛出发,实现香豆素-3-羧酸的串联合成。此外,在化合物制备基础上,引入熔点测定、红外以及核磁表征环节,整个实验时长约为4小时,适合有机化学实验本科教学。本次改进实验,以绿色合成为基础,辅以表征环节,有效增加了拓展性。并在此过程中探索线上线下混合式教学模式,增加探究性,进而有效提升学生的科学素养。 展开更多
关键词 香豆素-3-羧酸 甘氨酸 水杨醛 丙二酸环(亚)异丙酯 绿色合成
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废弃植物油酯交换制备生物柴油
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作者 陈友威 余言射 +2 位作者 方嘉怡 徐国栋 方东 《大学化学》 CAS 2023年第1期192-198,共7页
培养学生的绿色环保意识和可持续发展意识是应用化学专业本科人才培养方案的基本要求之一。目前实验教学中培养学生绿色环保和可持续发展意识的实验项目较少,针对这一问题,在综合化学实验中增加本新创实验项目。实验以废弃菜籽油和甲醇... 培养学生的绿色环保意识和可持续发展意识是应用化学专业本科人才培养方案的基本要求之一。目前实验教学中培养学生绿色环保和可持续发展意识的实验项目较少,针对这一问题,在综合化学实验中增加本新创实验项目。实验以废弃菜籽油和甲醇为原料,氢氧化钠和氯化胆碱为催化剂,生成的副产物甘油与氯化胆碱原位形成低共熔体系,与产品形成液-液两相,促使反应正向进行,简化后处理,提高产品纯度和产率。GC-MS(Gas chromatographymassspectrometer)结果表明,产品纯度大于99%,产率接近85%。分离出的低共熔体系可循环使用。燃烧热测试表明其热值与矿物柴油相当。实验使用的原料安全低毒,涉及基础有机化学实验、物理化学燃烧热测定、分析化学等多门基础实验课程的基本操作和表征,适合作为应用化学专业三年级综合化学实验教学实验项目的补充。通过本实验,有利于让学生更加系统地理解和掌握化学实验技术,培养其主动探索精神,锻炼其综合实践能力,同时,将绿水青山、环保低碳、变废为宝等课程思政理念融于综合化学实验教学。 展开更多
关键词 废弃菜籽油 资源化 酯交换 生物柴油 综合化学实验
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2D hierarchical lattices' imperfection sensitivity to missing bars defect 被引量:1
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作者 Bo Wang Yunfeng Shi +2 位作者 Rui Li youwei chen Yihua Mo 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2015年第4期141-145,共5页
Commercially available lattices contain various kinds of morphological imperfections which result in great degradation in lattices' mechanical properties, therefore, to obtain imperfection insensitive lattice structu... Commercially available lattices contain various kinds of morphological imperfections which result in great degradation in lattices' mechanical properties, therefore, to obtain imperfection insensitive lattice structure is obviously a practical research subject. Hierarchical structure materials were found to be a class of promising anti-defect materials, This paper builds hierarchical lattice by adding soft adhesion to lattice's cell edges and numerical results show that its imperfection sensitivity to missing bars is minor compared with the classic lattice. Soft adhesion with appropriate properties reinforce cell edge's bending stiffness and thus reduce the bending deformation in lattice caused by missing bars defect, which is confirmed by statistical analysis of normalized node displacements of imperfect lattices under hydrostatic compression and shear loads. 展开更多
关键词 Hierarchical structures LATTICES Imperfection sensitivity Elastic properties Missing bars
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Zircon U-Pb Ages and Sr-Nd-Hf Isotopic Characteristics of the Huichizi Granitic Complex in the North Qinling Orogenic Belt and Their Geological Significance 被引量:5
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作者 youwei chen Ruizhong Hu +3 位作者 Xianwu Bi Shaohua Dong Yue Xu Ting Zhou 《Journal of Earth Science》 SCIE CAS CSCD 2018年第3期492-507,共16页
The Huichizi granite complex is the largest Paleozoic 1-type intrusion located in the North Qinling orogenic belt (NQB). In this study, we present systematic geochemical element data, zircon U-Pb ages, Ln-Hf isotopi... The Huichizi granite complex is the largest Paleozoic 1-type intrusion located in the North Qinling orogenic belt (NQB). In this study, we present systematic geochemical element data, zircon U-Pb ages, Ln-Hf isotopic data, and Sr-Nd isotopic data for the Huichizi granites. In terms of mineral and chemical compositions, these granites are biotite monzonitic and alkali-feldspar granites, both of which are characterized by high SiO2 and total alkali contents and low MgO, TiO2, and TFeO contents. These granites are weakly peraluminous (A/CNK values are 1-1.06 for biotite mon- zonitic granites and 1.04-1.09 for alkali-feldspar granites) and possess the geochemical characteristics of adakitic rocks, e.g., high Sr contents (319 ppm-633 ppm), Sr/Y ratios (18.5-174), and (La/Yb)N ratios (17.6-57) and low MgO (0.04 wt.%-0.83 wt.%), Y (3.0 ppm-17.2 ppm), and heavy rare-earth element (HREE) contents. This indicates that these rocks were most likely derived from the partial melting of a thickened lower crust. In situ zircon U-Pb dating of these granites yields Early Caledonian ages (437 Ma for biotite monzonitic granites and 424 Ma for alkali-feldspar granites), indicating that the Huichizi granitic complex is the product of multi-periodic magmatism. The positive but varying zircon tHe(t) values (+0.6 to +8.5) suggest that this thickened lower crust was mainly juvenile, i.e., accreted from depleted mantle during the Neo-Mesoproterozoic Period, but involved the ancient recycled crust. Biotite monzonitic granites formed during crust thickening at the extrusion stage, whereas the alkali granites formed during crust thickening at the extension stage (post extrusion). The Huichizi granite complex witnessed the process of extrusion to extension because of the collision between the NCB and the Qinling microcontinent in the Caledonian. 展开更多
关键词 U-Pb age Sr-Nd-Hf isotope Huichizi granitic complex adakitic granite North Qinling orogen.
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Effect of La-Y co-substitution on magnetic properties and microstructure of NdFeB alloy ribbons 被引量:1
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作者 Chuanjia Zhao Qingzheng Jiang +4 位作者 Sajjad Ur Rehman Xiang Li youwei chen Jie Song Zhenchen Zhong 《Journal of Rare Earths》 SCIE EI CAS CSCD 2022年第12期1894-1898,I0003,共6页
Committed to obtaining cost-effective NdFeB based permanent magnets,Nd_(27-x)La_(3)Y_(x)Fe_(bal)Al_(0.1)Cu_(0.1)B_(1)(x=0-3)alloys were fabricated to detect the magnetic properties and microstructure.When x=1.8,coerci... Committed to obtaining cost-effective NdFeB based permanent magnets,Nd_(27-x)La_(3)Y_(x)Fe_(bal)Al_(0.1)Cu_(0.1)B_(1)(x=0-3)alloys were fabricated to detect the magnetic properties and microstructure.When x=1.8,coercivity of 1004 kA/m and the magnetic remanence of 0.75 T are obtained,which are close to those of the original Nd_(30)Fe_(bal)A_(l0.1)Cu_(0.1)B_(1)alloy ribbons.The temperature coefficient of coercivity(β)and the temperature coefficient of remanence(α)of the LaY-substituted alloys are better than those of the original alloys.The research results manifest that La is mainly distributed in the grain boundary phases and plays the role of refining the main grains,optimizing the grain boundary phases and improving the wettability between the main phases and the grain boundary phases,while Y tends to enrich in the main phases and enhances the short-range exchange coupling. 展开更多
关键词 Magnetic properties MICROSTRUCTURE Alloy ribbons Main phase Exchange coupling Rare earths
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