A star-shaped multifunctional styrene-isoprene copolymer was synthesized with n-BuLi as initiator, divinyl benzene as coupling agent, cyclobexane as solvent by living anionic polymerization. Using this polymer as graf...A star-shaped multifunctional styrene-isoprene copolymer was synthesized with n-BuLi as initiator, divinyl benzene as coupling agent, cyclobexane as solvent by living anionic polymerization. Using this polymer as grafting agent, a novel star-shaped branched polymer, containing several polyisobutylene, was prepared via cationic ~aolymerization. The star PS-b-PI and star-branched polyisobutylene were characterized by GPC, ＇HNMR and FT-IR, and the effects of different adding order and the amount of grafting agent were investigated.展开更多
The binary random in-chain silyl-hydride multi-functionalized poly（styrene/butadiene/isoprene and dimethyl[4-（1-phenylvinyl） phenyl]silane） （PS-DPESiH, PB-DPESiH, PI-DPESiH） copolymers were successfully synthesi...The binary random in-chain silyl-hydride multi-functionalized poly（styrene/butadiene/isoprene and dimethyl[4-（1-phenylvinyl） phenyl]silane） （PS-DPESiH, PB-DPESiH, PI-DPESiH） copolymers were successfully synthesized. These functionalized copo- lymers were prepared in hexane with n-BuLi as the initiator at 50℃ for 4 h. The silyl-hydride groups were introduced into polymer backbones quantitatively by living anionic polymerization. The copolymers were determined through 1H NMR, size exclusion chromatography （SEC） and differential scanning calorimetry （DSC） techniques, while the number of silyl-hych-ide groups was calculated and discussed.展开更多
文摘A star-shaped multifunctional styrene-isoprene copolymer was synthesized with n-BuLi as initiator, divinyl benzene as coupling agent, cyclobexane as solvent by living anionic polymerization. Using this polymer as grafting agent, a novel star-shaped branched polymer, containing several polyisobutylene, was prepared via cationic ~aolymerization. The star PS-b-PI and star-branched polyisobutylene were characterized by GPC, ＇HNMR and FT-IR, and the effects of different adding order and the amount of grafting agent were investigated.
基金sponsored by the National Natural Science Foundation of China(Nos.21034001,21174021)
文摘The binary random in-chain silyl-hydride multi-functionalized poly（styrene/butadiene/isoprene and dimethyl[4-（1-phenylvinyl） phenyl]silane） （PS-DPESiH, PB-DPESiH, PI-DPESiH） copolymers were successfully synthesized. These functionalized copo- lymers were prepared in hexane with n-BuLi as the initiator at 50℃ for 4 h. The silyl-hydride groups were introduced into polymer backbones quantitatively by living anionic polymerization. The copolymers were determined through 1H NMR, size exclusion chromatography （SEC） and differential scanning calorimetry （DSC） techniques, while the number of silyl-hych-ide groups was calculated and discussed.
