By means of pre-compressive creep treatment, the cubic γ′ phase in a nickel base single crystal superalloy is transformed into the P-type rafted structure. And the influence of the pre-compressive creep on the inter...By means of pre-compressive creep treatment, the cubic γ′ phase in a nickel base single crystal superalloy is transformed into the P-type rafted structure. And the influence of the pre-compressive creep on the internal friction stress and creep lifetimes of the superalloy are investigated by means of the measurement of the creep curves and microstructure observation. Results show that, compared to the P-type structure alloy, the full heat treated state alloy displays a bigger internal friction stress value of dislocation motion during steady state creep and a longer creep lifetimes. The creep activation energies of the full heat treated and P-type structures alloys are measured to be 462 kJ/mol and 412 kJ/mol, respectively. Thereinto, the P-type rafted γ′ phase in the alloy is transformed into the N-type structure during tensile creep. And the N-type γ′ phase transformed from the P-type structure displays a shorter size in length, this is a main reason of the P-type structure alloy possessing a shorter creep lifetimes due to creep dislocation moving easily over the rafted γ′ phase.展开更多
The corrosion behaviors and mechanism of Ni-14%Cr alloys in molten salt with Na2SO4 at 1000℃ was investigated by means of XRD analysis and SEM observation. Results show that the alloys were subjected to the accelerat...The corrosion behaviors and mechanism of Ni-14%Cr alloys in molten salt with Na2SO4 at 1000℃ was investigated by means of XRD analysis and SEM observation. Results show that the alloys were subjected to the accelerated corrosion in molten salt and the corrosion kinetic of the alloy obeys the parabolic law. On the other hand, the corrosion-resistance of the alloy could be improved significantly by increasing of chromium content. Corrosion products may be divided into three layers, i. e. NiCr2O4, CoCr2O4, CoNi2S4, AlWO3 and Al2O3 granule are included in the outside of the scales, the continuous Al2O3 layer is localed in intermediate layer, and the sulfides is in the internal layer. The Cr2S3 phase in Ni-14Cr prevents the S and O from the matrix of the alloy. The morphology examinations tend to support the sulphidization-basic dissolution model previously proposed for hot corrosion mechanism.展开更多
基金Supported by the National Natural Science Foundation of China (No 50571070)
文摘By means of pre-compressive creep treatment, the cubic γ′ phase in a nickel base single crystal superalloy is transformed into the P-type rafted structure. And the influence of the pre-compressive creep on the internal friction stress and creep lifetimes of the superalloy are investigated by means of the measurement of the creep curves and microstructure observation. Results show that, compared to the P-type structure alloy, the full heat treated state alloy displays a bigger internal friction stress value of dislocation motion during steady state creep and a longer creep lifetimes. The creep activation energies of the full heat treated and P-type structures alloys are measured to be 462 kJ/mol and 412 kJ/mol, respectively. Thereinto, the P-type rafted γ′ phase in the alloy is transformed into the N-type structure during tensile creep. And the N-type γ′ phase transformed from the P-type structure displays a shorter size in length, this is a main reason of the P-type structure alloy possessing a shorter creep lifetimes due to creep dislocation moving easily over the rafted γ′ phase.
文摘The corrosion behaviors and mechanism of Ni-14%Cr alloys in molten salt with Na2SO4 at 1000℃ was investigated by means of XRD analysis and SEM observation. Results show that the alloys were subjected to the accelerated corrosion in molten salt and the corrosion kinetic of the alloy obeys the parabolic law. On the other hand, the corrosion-resistance of the alloy could be improved significantly by increasing of chromium content. Corrosion products may be divided into three layers, i. e. NiCr2O4, CoCr2O4, CoNi2S4, AlWO3 and Al2O3 granule are included in the outside of the scales, the continuous Al2O3 layer is localed in intermediate layer, and the sulfides is in the internal layer. The Cr2S3 phase in Ni-14Cr prevents the S and O from the matrix of the alloy. The morphology examinations tend to support the sulphidization-basic dissolution model previously proposed for hot corrosion mechanism.
