Volatile organic compounds (VOCs) are an atmospheric pollutant with a boiling point of 50˚C - 260˚C at room temperature and pressure. They are precursors of sulfur dioxide and ozone, which can seriously pollute the at...Volatile organic compounds (VOCs) are an atmospheric pollutant with a boiling point of 50˚C - 260˚C at room temperature and pressure. They are precursors of sulfur dioxide and ozone, which can seriously pollute the atmosphere and endanger human health. After the “14th Five-Year Plan”, VOCs, instead of SO2, became one of the five indicators of China’s atmospheric governance. As a result, the government’s efforts to control VOCs have increased significantly. VOCs governance mustn’t be delayed. This paper provides a comprehensive summary and analysis of VOCs governance, covering the classification of VOCs, analysis of VOC governance technology (with a focus on end-of-pipe governance technology), national policy regulations, current governance shortcomings, and a forward-looking perspective on the future direction of VOCs governance, emphasizing healthy and sustainable development.展开更多
Background Vascular hyporeactivity and leakage are key pathophysiologic features that produce multi-organ damage upon sepsis.We hypothesized that pericytes,a group of pluripotent cells that maintain vascular integrity...Background Vascular hyporeactivity and leakage are key pathophysiologic features that produce multi-organ damage upon sepsis.We hypothesized that pericytes,a group of pluripotent cells that maintain vascular integrity and tension,are protective against sepsis via regulating vascular reactivity and permeability.Methods We conducted a series of in vivo experiments using wild-type(WT),platelet-derived growth factor receptor-β(PDGFR-β)-Cre+mT/mG transgenic mice and Tie2-Cre+Cx43^(flox/flox)mice to examine the relative contribution of pericytes in sepsis,either induced by cecal ligation and puncture(CLP)or lipopolysaccharide(LPS)challenge.In a separate set of experiments with Sprague-Dawley(SD)rats,pericytes were depleted using CP-673451,a selective PDGFR-βinhibitor,at a dosage of 40 mg/(kg·d)for 7 consecutive days.Cultured pericytes,vascular endothelial cells(VECs)and vascular smooth muscle cells(VSMCs)were used for mechanistic investigations.The effects of pericytes and pericyte-derived microvesicles(PCMVs)and candidate miRNAs on vascular reactivity and barrier function were also examined.Results CLP and LPS induced severe injury/loss of pericytes,vascular hyporeactivity and leakage(P<0.05).Transplantation with exogenous pericytes protected vascular reactivity and barrier function via microvessel colonization(P<0.05).Cx43 knockout in either pericytes or VECs reduced pericyte colonization in microvessels(P<0.05).Additionally,PCMVs transferred miR-145 and miR-132 to VSMCs and VECs,respectively,exerting a protective effect on vascular reactivity and barrier function after sepsis(P<0.05).miR-145 primarily improved the contractile response of VSMCs by activating the sphingosine kinase 2(Sphk2)/sphingosine-1-phosphate receptor(S1PR)1/phosphorylation of myosin light chain 20 pathway,whereas miR-132 effectively improved the barrier function of VECs by activating the Sphk2/S1PR2/zonula occludens-1 and vascular endothelial-cadherin pathways.Conclusions Pericytes are protective against sepsis through regulating vascular reactivity and barrier function.Possible mechanisms include both direct colonization of microvasculature and secretion of PCMVs.展开更多
胃肝样腺癌(hepatoid adenocarcinoma of the stomach,HAS)是一种表现在肝脏外的罕见的特殊胃恶性肿瘤,与一般的胃癌不同,HAS的恶性程度高、侵袭性高,容易出现肝转移、淋巴转移、预后差,但是HAS的诊断、临床病理特征和预后仍有较大的争...胃肝样腺癌(hepatoid adenocarcinoma of the stomach,HAS)是一种表现在肝脏外的罕见的特殊胃恶性肿瘤,与一般的胃癌不同,HAS的恶性程度高、侵袭性高,容易出现肝转移、淋巴转移、预后差,但是HAS的诊断、临床病理特征和预后仍有较大的争论.为了帮助临床医生更了解这种胃癌,本文从甲胎蛋白的起源开始对HAS的诊断、临床病理特征及其预后等进行系统综述,从而为这种特殊胃癌的临床诊治提供建设性的意见及帮助.展开更多
Trees progress through various growth stages,each marked by specific responses and adaptation strate-gies to environmental conditions.Despite the importance of age-related growth responses on overall forest health and...Trees progress through various growth stages,each marked by specific responses and adaptation strate-gies to environmental conditions.Despite the importance of age-related growth responses on overall forest health and management policies,limited knowledge exists regarding age-related effects on dendroclimatic relationships in key subtropical tree species.In this study,we employed a den-drochronological method to examine the impact of rapid warming on growth dynamics and climatic sensitivity of young(40–60 years)and old(100–180 years)Pinus mas-soniana forests across six sites in central-southern China.The normalized log basal area increment of trees in both age groups increased significantly following rapid warming in 1984.Trees in young forests further showed a distinct growth decline during a prolonged severe drought(2004–2013),whereas those in old forests maintained growth increases.Tree growth was more strongly influenced by temperature than by moisture,particularly in old forests.Spring tem-peratures strongly and positively impacted the growth of old trees but had a weaker effect on young ones.Old forests had a significantly lower resistance to extreme drought but faster recovery compared to young forests.The“divergence problem”was more pronounced in younger forests due to their heightened sensitivity to warming-induced drought and heat stress.With ongoing warming,young forests also may initially experience a growth decline due to their heightened sensitivity to winter drought.Our findings underscore the importance of considering age-dependent changes in forest/tree growth response to warming in subtropical forest man-agement,particularly in the context of achieving“Carbon Peak&Carbon Neutrality”goals in China.展开更多
Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices stability.However,the strategies of suppressing photoinduced ph...Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices stability.However,the strategies of suppressing photoinduced phase segregation and related mechanisms have not been fully disclosed.Here,we report a new passivation agent 4-aminotetrahydrothiopyran hydrochloride(4-ATpHCl)with multifunctional groups for the interface treatment of a 1.77-eV wide-bandgap perovskite film.4-ATpH^(+)impeded halogen ion migration by anchoring on the perovskite surface,leading to the inhibition of phase segregation and thus the passivation of defects,which is ascribed to the interaction of 4-ATpH^(+)with perovskite and the formation of low-dimensional perovskites.Finally,the champion device achieved an efficiency of 19.32%with an open-circuit voltage(V_(OC))of 1.314 V and a fill factor of 83.32%.Moreover,4-ATpHCl modified device exhibited significant improved stability as compared with control one.The target device maintained 80%of its initial efficiency after 519 h of maximum power output(MPP)tracking under 1 sun illumination,however,the control device showed a rapid decrease in efficiency after 267 h.Finally,an efficiency of 27.38%of the champion 4-terminal all-perovskite tandem solar cell was achieved by mechanically stacking this wide-bandgap top subcell with a 1.25-eV low-bandgap perovskite bottom subcell.展开更多
Understanding the spatial variation,temporal changes,and their underlying driving forces of carbon sequestration in various forests is of great importance for understanding the carbon cycle and carbon management optio...Understanding the spatial variation,temporal changes,and their underlying driving forces of carbon sequestration in various forests is of great importance for understanding the carbon cycle and carbon management options.How carbon density and sequestration in various Cunninghamia lanceolata forests,extensively cultivated for timber production in subtropical China,vary with biodiversity,forest structure,environment,and cultural factors remain poorly explored,presenting a critical knowledge gap for realizing carbon sequestration supply potential through management.Based on a large-scale database of 449 permanent forest inventory plots,we quantified the spatial-temporal heterogeneity of aboveground carbon densities and carbon accumulation rates in Cunninghamia lanceolate forests in Hunan Province,China,and attributed the contributions of stand structure,environmental,and management factors to the heterogeneity using quantile age-sequence analysis,partial least squares path modeling(PLS-PM),and hot-spot analysis.The results showed lower values of carbon density and sequestration on average,in comparison with other forests in the same climate zone(i.e.,subtropics),with pronounced spatial and temporal variability.Specifically,quantile regression analysis using carbon accumulation rates along an age sequence showed large differences in carbon sequestration rates among underperformed and outperformed forests(0.50 and 1.80 Mg·ha^(-1)·yr^(-1)).PLS-PM demonstrated that maximum DBH and stand density were the main crucial drivers of aboveground carbon density from young to mature forests.Furthermore,species diversity and geotopographic factors were the significant factors causing the large discrepancy in aboveground carbon density change between low-and high-carbon-bearing forests.Hotspot analysis revealed the importance of culture attributes in shaping the geospatial patterns of carbon sequestration.Our work highlighted that retaining largesized DBH trees and increasing shade-tolerant tree species were important to enhance carbon sequestration in C.lanceolate forests.展开更多
The 1T-TiSe_(2) is a two-dimensional charge-density-wave(CDW)material that attracts great interest.A small band gap locates at the Fermi level separating the Ti d-bands and Se p-bands,which makes 1T-TiSe_(2) a promisi...The 1T-TiSe_(2) is a two-dimensional charge-density-wave(CDW)material that attracts great interest.A small band gap locates at the Fermi level separating the Ti d-bands and Se p-bands,which makes 1T-TiSe_(2) a promising candidate for realizing excitonic condensation.Here,we studied the band gap in 1T-TiSe_(2) using angle-resolved photoemission spectroscopy(ARPES).Instead of only focusing on the in-plane band dispersions,we obtained the detailed band dispersions of both conduction and valance bands along the out-of-plane direction.We found that the conduction and valance bands split into multiple sub-bands in the CDW state due to band folding.As a result,the band gap between the Ti d-bands and Se p-bands reduces to~25 meV and becomes a direct gap in the CDW state.More intriguingly,such band gap can be further reduced by the rubidium deposition.The band structure becomes semimetallic in the rubidium-doped sample.Meanwhile,exotic gapless behaviors were observed at the p-d band crossing.Our result characterized the band gap of 1T-TiSe_(2) in three-dimensional Brillouin zone with unpreceded precision.It also suggests a closing of band gap or a potential band inversion in 1T-TiSe_(2) driven by rubidium deposition.展开更多
BACKGROUND Febrile convulsions are a common pediatric emergency that imposes significant psychological stress on children and their families.Targeted emergency care and psychological nursing are widely applied in clin...BACKGROUND Febrile convulsions are a common pediatric emergency that imposes significant psychological stress on children and their families.Targeted emergency care and psychological nursing are widely applied in clinical practice,but their value and impact on the management of pediatric febrile convulsions are unclear.AIM To determine the impact of targeted emergency nursing combined with psychological nursing on satisfaction in children with febrile convulsions.METHODS Data from 111 children with febrile convulsions who received treatment at Nantong Maternal and Child Health Care Hospital between June 2021 and October 2022 were analyzed.The control group consisted of 44 children who received conventional nursing care and the research group consisted of 67 children who received targeted emergency and psychological nursing.The time to fever resolution,time to resolution of convulsions,length of hospital stays,Pittsburgh Sleep Quality Index,patient compliance,nursing satisfaction of the parents,occurrence of complications during the nursing process,and parental anxiety and depression were compared between the control and research groups.Parental anxiety and depression were assessed using the Hamilton Rating Scale for Depression(HAMD)and the Hamilton Rating Scale for Anxiety(HAMA).RESULTS The fever resolution,convulsion disappearance,and hospitalization times were longer in the control group compared with the research group(P<0.0001).The time to falling asleep,sleep time,sleep quality,sleep disturbance,sleep efficiency,and daytime status scores were significantly better in the research group compared with the control group(P<0.0001).The HAMD and HAMA scores for parents of children in the research group were lower than the scores in the control group after nursing(P<0.05).Compliance with treatment of children in the research group was higher than in the control group(P<0.05).Parental satisfaction with nursing in the research group was higher than in the control group(P<0.05).The total complication rate of children in the control group was higher than in the research group(P<0.05).CONCLUSION Combining psychological nursing with targeted emergency nursing improved the satisfaction of children’s families and compliance with treatment and promoted early recovery of clinical symptoms and improvement of sleep quality.展开更多
Geothermal energy has gained wide attention as a renewable alternative for mitigating greenhouse gas emissions.The advancements in enhanced geothermal system technology have enabled the exploitation of previously inac...Geothermal energy has gained wide attention as a renewable alternative for mitigating greenhouse gas emissions.The advancements in enhanced geothermal system technology have enabled the exploitation of previously inaccessible geothermal resources.However,the extraction of geothermal energy from deep reservoirs poses many challenges due to high‐temperature and high‐geostress conditions.These factors can significantly impact the surrounding rock and its fracture formation.A comprehensive understanding of the thermal–hydraulic–mechanical(THM)coupling effect is crucial to the safe and efficient exploitation of geothermal resources.This study presented a THM coupling numerical model for the geothermal reservoir of the Yangbajing geothermal system.This proposed model investigated the geothermal exploitation performance and the stress distribution within the reservoir under various combinations of geothermal wells and mass flow rates.The geothermal system performance was evaluated by the criteria of outlet temperature and geothermal productivity.The results indicate that the longer distance between wells can increase the outlet temperature of production wells and improve extraction efficiency in the short term.In contrast,the shorter distance between wells can reduce the heat exchange area and thus mitigate the impact on the reservoir stress.A larger mass flow rate is conducive to the production capacity enhancement of the geothermal system and,in turn causes a wider range of stress disturbance.These findings provide valuable insights into the optimization of geothermal energy extraction while considering reservoir safety and long‐term sustainability.This study deepens the understanding of the THM coupling effects in geothermal systems and provides an efficient and environmentally friendly strategy for a geothermal energy system.展开更多
This study aimed to investigate whether saline silt and sandy loam coastal soils could be reclaimed by micro-sprinkler irrigation.The experiments were run using moderately salt-tolerant tall fescue grass.Micro-sprinkl...This study aimed to investigate whether saline silt and sandy loam coastal soils could be reclaimed by micro-sprinkler irrigation.The experiments were run using moderately salt-tolerant tall fescue grass.Micro-sprinkler irrigation in three stages was used to regulate soil matric potential at a 20-cm soil depth.Continued regulation of soil water and salt through micro-sprinkler irrigation consistently resulted in an increasingly large low-salinity region.The application of the three stages of soil wateresalt regulation resulted in an absence of salt accumulation throughout the soil profile and the conversion of highly saline soils into moderately saline soils.There were increases in the plant height,leaf width,leaf length,and tiller numbers of tall fescue throughout the leaching process.The results showed that micro-sprinkler irrigation in three soil water and salt regulation stages can be used to successfully cultivate tall festuca in highly saline coastal soil.This approach achieved better effects in sandy loam soil than in silt soil.Tall fescue showed greater survival rates in sandy loam soil due to the rapid reclamation process,whereas plant growth was higher in silt soil because of effective water conservation.In sandy loam,soil moisture should be maintained during soil reclamation,and in silt soil,soil root-zone environments optimal for the emergence of plants should be quickly established.Micro-sprinkler irrigation can be successfully applied to the cultivation of tall fescue in coastal heavy saline soils under a three-stage soil wateresalt regulation regime.展开更多
Realizing phase transitions via non-thermal sample manipulations is important not only for applications,but also for uncovering the underlying physics.Here,we report on the discovery of two distinct metal–insulator t...Realizing phase transitions via non-thermal sample manipulations is important not only for applications,but also for uncovering the underlying physics.Here,we report on the discovery of two distinct metal–insulator transitions in 1T-TaS_(2) via angle-resolved photoemission spectroscopy and in-situ rubidium deposition.At 205 K,the rubidium deposition drives a normal metal–insulator transition via filling electrons into the conduction band.While at 225 K,however,the rubidium deposition drives a bandwidth-controlled Mott transition as characterized by a rapid collapsing of Mott gap and a loss of spectral weight of the lower Hubbard band.Our result,from a doping-controlled perspective,succeeds in distinguishing the metallic,band-insulating,and Mott-insulating phases of 1T-TaS_(2),manifesting a delicate balance among the electronitineracy,interlayer-coupling and Coulomb repulsion.We also establish an effective method to tune the balance between these interactions,which is useful in seeking exotic electronic phases and designing functional phase-changing devices.展开更多
Industrial robot which can acquire high accuracy has been widely used in automatic assembly.Usually,the geometric parameter of industrial robot should be inspected during manufacturing and application.High precision m...Industrial robot which can acquire high accuracy has been widely used in automatic assembly.Usually,the geometric parameter of industrial robot should be inspected during manufacturing and application.High precision measurement equipment was utilized to acquire the position and orientation of robot’s end⁃effector,when calibrating the geometric parameter of robot.A kind of measurement system based on a draw⁃wire encoder was presented,since the current measurement equipment has some disadvantages,such as the cost and the requirements of working environment are high.According to this kind of measurement system,a sort of geometric calibration method of robot was presented including position and orientation parameters.The uncertain arc length of the cable length between robot end⁃effector and the measurement can be exactly acquired according to the position and orientation parameters.The pose⁃solving model of robot end⁃effector was associated with the kinematic model of robot,and robot’s geometric parameter can be computed by using the least⁃squares methods.Validate instance was conducted,the result showed that the optimal number of the calibration pose was 47 with little improvement in accuracy,even if increasing the number of calibration pose.Robot calibration experiment was performed and the results showed that the absolute accuracy of robot decreased from 4.32 mm to 0.87 mm after calibration,which improved the robot’s absolute accuracy effectively.展开更多
The cowcatcher is one of the unique devices at the front end of the train, which can remove obstacles on the track by crashing before the vehicle body to ensure the safety of the train. When a collision accident happe...The cowcatcher is one of the unique devices at the front end of the train, which can remove obstacles on the track by crashing before the vehicle body to ensure the safety of the train. When a collision accident happens, the cowcatcher serves as the first energy-absorbing structure to dissipate and guide the collision energy. The design of the existing cowcatcher of multiple units generally focuses on the good ability to remove obstacles, while the secondary function, the crashworthiness of orderly deformation under collision, still needs further research. In this study, a finite element model of structural static load and collision analysis was established under standard EN 15227, with the cowcatcher for 160 km/h train as the prototype. Then the solution and simulation process was accomplished under the environment of ANSYS and LS-DYNA. The analysis results showed that the structural static strength of the current cowcatcher met the requirements of the standard EN 15227, and the longitudinal stiffness was evenly distributed. When removing the obstacles with low mass, the impact force was small and the structure would not produce obvious deformation;when removing the obstacles with large mass, the impact force was large and the shear fracture might occur at the connection of the cowcatcher.展开更多
文摘Volatile organic compounds (VOCs) are an atmospheric pollutant with a boiling point of 50˚C - 260˚C at room temperature and pressure. They are precursors of sulfur dioxide and ozone, which can seriously pollute the atmosphere and endanger human health. After the “14th Five-Year Plan”, VOCs, instead of SO2, became one of the five indicators of China’s atmospheric governance. As a result, the government’s efforts to control VOCs have increased significantly. VOCs governance mustn’t be delayed. This paper provides a comprehensive summary and analysis of VOCs governance, covering the classification of VOCs, analysis of VOC governance technology (with a focus on end-of-pipe governance technology), national policy regulations, current governance shortcomings, and a forward-looking perspective on the future direction of VOCs governance, emphasizing healthy and sustainable development.
基金supported by the Key Projects and Innovation Group of National Natural Science Foundation of China(81830065),the Innovation Groups of NSFC(81721001),and the Young Scientists Fund(82102279).
文摘Background Vascular hyporeactivity and leakage are key pathophysiologic features that produce multi-organ damage upon sepsis.We hypothesized that pericytes,a group of pluripotent cells that maintain vascular integrity and tension,are protective against sepsis via regulating vascular reactivity and permeability.Methods We conducted a series of in vivo experiments using wild-type(WT),platelet-derived growth factor receptor-β(PDGFR-β)-Cre+mT/mG transgenic mice and Tie2-Cre+Cx43^(flox/flox)mice to examine the relative contribution of pericytes in sepsis,either induced by cecal ligation and puncture(CLP)or lipopolysaccharide(LPS)challenge.In a separate set of experiments with Sprague-Dawley(SD)rats,pericytes were depleted using CP-673451,a selective PDGFR-βinhibitor,at a dosage of 40 mg/(kg·d)for 7 consecutive days.Cultured pericytes,vascular endothelial cells(VECs)and vascular smooth muscle cells(VSMCs)were used for mechanistic investigations.The effects of pericytes and pericyte-derived microvesicles(PCMVs)and candidate miRNAs on vascular reactivity and barrier function were also examined.Results CLP and LPS induced severe injury/loss of pericytes,vascular hyporeactivity and leakage(P<0.05).Transplantation with exogenous pericytes protected vascular reactivity and barrier function via microvessel colonization(P<0.05).Cx43 knockout in either pericytes or VECs reduced pericyte colonization in microvessels(P<0.05).Additionally,PCMVs transferred miR-145 and miR-132 to VSMCs and VECs,respectively,exerting a protective effect on vascular reactivity and barrier function after sepsis(P<0.05).miR-145 primarily improved the contractile response of VSMCs by activating the sphingosine kinase 2(Sphk2)/sphingosine-1-phosphate receptor(S1PR)1/phosphorylation of myosin light chain 20 pathway,whereas miR-132 effectively improved the barrier function of VECs by activating the Sphk2/S1PR2/zonula occludens-1 and vascular endothelial-cadherin pathways.Conclusions Pericytes are protective against sepsis through regulating vascular reactivity and barrier function.Possible mechanisms include both direct colonization of microvasculature and secretion of PCMVs.
文摘胃肝样腺癌(hepatoid adenocarcinoma of the stomach,HAS)是一种表现在肝脏外的罕见的特殊胃恶性肿瘤,与一般的胃癌不同,HAS的恶性程度高、侵袭性高,容易出现肝转移、淋巴转移、预后差,但是HAS的诊断、临床病理特征和预后仍有较大的争论.为了帮助临床医生更了解这种胃癌,本文从甲胎蛋白的起源开始对HAS的诊断、临床病理特征及其预后等进行系统综述,从而为这种特殊胃癌的临床诊治提供建设性的意见及帮助.
基金funded by the National Natural Science Foundation of China(42107476,31901241)the China Postdoctoral Science Foundation(2020M682600)+1 种基金the China Postdoctoral International Exchange Fellowship Program(PC2021099)the Natural Science Foundation of Hunan Province(2021JJ41075).
文摘Trees progress through various growth stages,each marked by specific responses and adaptation strate-gies to environmental conditions.Despite the importance of age-related growth responses on overall forest health and management policies,limited knowledge exists regarding age-related effects on dendroclimatic relationships in key subtropical tree species.In this study,we employed a den-drochronological method to examine the impact of rapid warming on growth dynamics and climatic sensitivity of young(40–60 years)and old(100–180 years)Pinus mas-soniana forests across six sites in central-southern China.The normalized log basal area increment of trees in both age groups increased significantly following rapid warming in 1984.Trees in young forests further showed a distinct growth decline during a prolonged severe drought(2004–2013),whereas those in old forests maintained growth increases.Tree growth was more strongly influenced by temperature than by moisture,particularly in old forests.Spring tem-peratures strongly and positively impacted the growth of old trees but had a weaker effect on young ones.Old forests had a significantly lower resistance to extreme drought but faster recovery compared to young forests.The“divergence problem”was more pronounced in younger forests due to their heightened sensitivity to warming-induced drought and heat stress.With ongoing warming,young forests also may initially experience a growth decline due to their heightened sensitivity to winter drought.Our findings underscore the importance of considering age-dependent changes in forest/tree growth response to warming in subtropical forest man-agement,particularly in the context of achieving“Carbon Peak&Carbon Neutrality”goals in China.
基金financially supported by the National Key R&D Program of China (2022YFB4200304)the National Natural Science Foundation of China (52303347)+3 种基金the Fundamental Research Funds for the Central Universities (YJ2021157)the Engineering Featured Team Fund of Sichuan University (2020SCUNG102)open foundation of Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, Guangxi University (2022GXYSOF05)the support from the National Natural Science Foundation of China (E30853YM19)
文摘Wide-bandgap(>1.7 eV)perovskites suffer from severe light-induced phase segregation due to high bromine content,causing irreversible damage to devices stability.However,the strategies of suppressing photoinduced phase segregation and related mechanisms have not been fully disclosed.Here,we report a new passivation agent 4-aminotetrahydrothiopyran hydrochloride(4-ATpHCl)with multifunctional groups for the interface treatment of a 1.77-eV wide-bandgap perovskite film.4-ATpH^(+)impeded halogen ion migration by anchoring on the perovskite surface,leading to the inhibition of phase segregation and thus the passivation of defects,which is ascribed to the interaction of 4-ATpH^(+)with perovskite and the formation of low-dimensional perovskites.Finally,the champion device achieved an efficiency of 19.32%with an open-circuit voltage(V_(OC))of 1.314 V and a fill factor of 83.32%.Moreover,4-ATpHCl modified device exhibited significant improved stability as compared with control one.The target device maintained 80%of its initial efficiency after 519 h of maximum power output(MPP)tracking under 1 sun illumination,however,the control device showed a rapid decrease in efficiency after 267 h.Finally,an efficiency of 27.38%of the champion 4-terminal all-perovskite tandem solar cell was achieved by mechanically stacking this wide-bandgap top subcell with a 1.25-eV low-bandgap perovskite bottom subcell.
基金the National Natural Science Foundation of China(Nos.U20A2089 and 41971152)the Research Foundation of the Department of Natural Resources of Hunan Province(No.20230138ST)to SLthe open research fund of Technology Innovation Center for Ecological Conservation and Restoration in Dongting Lake Basin,Ministry of Natural Resources(No.2023005)to YZ。
文摘Understanding the spatial variation,temporal changes,and their underlying driving forces of carbon sequestration in various forests is of great importance for understanding the carbon cycle and carbon management options.How carbon density and sequestration in various Cunninghamia lanceolata forests,extensively cultivated for timber production in subtropical China,vary with biodiversity,forest structure,environment,and cultural factors remain poorly explored,presenting a critical knowledge gap for realizing carbon sequestration supply potential through management.Based on a large-scale database of 449 permanent forest inventory plots,we quantified the spatial-temporal heterogeneity of aboveground carbon densities and carbon accumulation rates in Cunninghamia lanceolate forests in Hunan Province,China,and attributed the contributions of stand structure,environmental,and management factors to the heterogeneity using quantile age-sequence analysis,partial least squares path modeling(PLS-PM),and hot-spot analysis.The results showed lower values of carbon density and sequestration on average,in comparison with other forests in the same climate zone(i.e.,subtropics),with pronounced spatial and temporal variability.Specifically,quantile regression analysis using carbon accumulation rates along an age sequence showed large differences in carbon sequestration rates among underperformed and outperformed forests(0.50 and 1.80 Mg·ha^(-1)·yr^(-1)).PLS-PM demonstrated that maximum DBH and stand density were the main crucial drivers of aboveground carbon density from young to mature forests.Furthermore,species diversity and geotopographic factors were the significant factors causing the large discrepancy in aboveground carbon density change between low-and high-carbon-bearing forests.Hotspot analysis revealed the importance of culture attributes in shaping the geospatial patterns of carbon sequestration.Our work highlighted that retaining largesized DBH trees and increasing shade-tolerant tree species were important to enhance carbon sequestration in C.lanceolate forests.
基金Project supported by the National Key Research and Development Program of China (Grant Nos.2022YFA1403502 and 2018YFA0305602)the National Natural Science Foundation of China (Grant No.11888101)SSRF is supported by ME2 project under contract No.11227901 from the National Natural Science Foundation of China。
文摘The 1T-TiSe_(2) is a two-dimensional charge-density-wave(CDW)material that attracts great interest.A small band gap locates at the Fermi level separating the Ti d-bands and Se p-bands,which makes 1T-TiSe_(2) a promising candidate for realizing excitonic condensation.Here,we studied the band gap in 1T-TiSe_(2) using angle-resolved photoemission spectroscopy(ARPES).Instead of only focusing on the in-plane band dispersions,we obtained the detailed band dispersions of both conduction and valance bands along the out-of-plane direction.We found that the conduction and valance bands split into multiple sub-bands in the CDW state due to band folding.As a result,the band gap between the Ti d-bands and Se p-bands reduces to~25 meV and becomes a direct gap in the CDW state.More intriguingly,such band gap can be further reduced by the rubidium deposition.The band structure becomes semimetallic in the rubidium-doped sample.Meanwhile,exotic gapless behaviors were observed at the p-d band crossing.Our result characterized the band gap of 1T-TiSe_(2) in three-dimensional Brillouin zone with unpreceded precision.It also suggests a closing of band gap or a potential band inversion in 1T-TiSe_(2) driven by rubidium deposition.
文摘BACKGROUND Febrile convulsions are a common pediatric emergency that imposes significant psychological stress on children and their families.Targeted emergency care and psychological nursing are widely applied in clinical practice,but their value and impact on the management of pediatric febrile convulsions are unclear.AIM To determine the impact of targeted emergency nursing combined with psychological nursing on satisfaction in children with febrile convulsions.METHODS Data from 111 children with febrile convulsions who received treatment at Nantong Maternal and Child Health Care Hospital between June 2021 and October 2022 were analyzed.The control group consisted of 44 children who received conventional nursing care and the research group consisted of 67 children who received targeted emergency and psychological nursing.The time to fever resolution,time to resolution of convulsions,length of hospital stays,Pittsburgh Sleep Quality Index,patient compliance,nursing satisfaction of the parents,occurrence of complications during the nursing process,and parental anxiety and depression were compared between the control and research groups.Parental anxiety and depression were assessed using the Hamilton Rating Scale for Depression(HAMD)and the Hamilton Rating Scale for Anxiety(HAMA).RESULTS The fever resolution,convulsion disappearance,and hospitalization times were longer in the control group compared with the research group(P<0.0001).The time to falling asleep,sleep time,sleep quality,sleep disturbance,sleep efficiency,and daytime status scores were significantly better in the research group compared with the control group(P<0.0001).The HAMD and HAMA scores for parents of children in the research group were lower than the scores in the control group after nursing(P<0.05).Compliance with treatment of children in the research group was higher than in the control group(P<0.05).Parental satisfaction with nursing in the research group was higher than in the control group(P<0.05).The total complication rate of children in the control group was higher than in the research group(P<0.05).CONCLUSION Combining psychological nursing with targeted emergency nursing improved the satisfaction of children’s families and compliance with treatment and promoted early recovery of clinical symptoms and improvement of sleep quality.
基金supported by the financial support from the National Natural Science Foundation of China(52204084)Project funded by the China Postdoctoral Science Foundation(2021M700388).
文摘Geothermal energy has gained wide attention as a renewable alternative for mitigating greenhouse gas emissions.The advancements in enhanced geothermal system technology have enabled the exploitation of previously inaccessible geothermal resources.However,the extraction of geothermal energy from deep reservoirs poses many challenges due to high‐temperature and high‐geostress conditions.These factors can significantly impact the surrounding rock and its fracture formation.A comprehensive understanding of the thermal–hydraulic–mechanical(THM)coupling effect is crucial to the safe and efficient exploitation of geothermal resources.This study presented a THM coupling numerical model for the geothermal reservoir of the Yangbajing geothermal system.This proposed model investigated the geothermal exploitation performance and the stress distribution within the reservoir under various combinations of geothermal wells and mass flow rates.The geothermal system performance was evaluated by the criteria of outlet temperature and geothermal productivity.The results indicate that the longer distance between wells can increase the outlet temperature of production wells and improve extraction efficiency in the short term.In contrast,the shorter distance between wells can reduce the heat exchange area and thus mitigate the impact on the reservoir stress.A larger mass flow rate is conducive to the production capacity enhancement of the geothermal system and,in turn causes a wider range of stress disturbance.These findings provide valuable insights into the optimization of geothermal energy extraction while considering reservoir safety and long‐term sustainability.This study deepens the understanding of the THM coupling effects in geothermal systems and provides an efficient and environmentally friendly strategy for a geothermal energy system.
基金supported by the China Scholarship Council(Grant No.201906715015)the Priority Academic Development Program of Jiangsu Higher Education Institutions.
文摘This study aimed to investigate whether saline silt and sandy loam coastal soils could be reclaimed by micro-sprinkler irrigation.The experiments were run using moderately salt-tolerant tall fescue grass.Micro-sprinkler irrigation in three stages was used to regulate soil matric potential at a 20-cm soil depth.Continued regulation of soil water and salt through micro-sprinkler irrigation consistently resulted in an increasingly large low-salinity region.The application of the three stages of soil wateresalt regulation resulted in an absence of salt accumulation throughout the soil profile and the conversion of highly saline soils into moderately saline soils.There were increases in the plant height,leaf width,leaf length,and tiller numbers of tall fescue throughout the leaching process.The results showed that micro-sprinkler irrigation in three soil water and salt regulation stages can be used to successfully cultivate tall festuca in highly saline coastal soil.This approach achieved better effects in sandy loam soil than in silt soil.Tall fescue showed greater survival rates in sandy loam soil due to the rapid reclamation process,whereas plant growth was higher in silt soil because of effective water conservation.In sandy loam,soil moisture should be maintained during soil reclamation,and in silt soil,soil root-zone environments optimal for the emergence of plants should be quickly established.Micro-sprinkler irrigation can be successfully applied to the cultivation of tall fescue in coastal heavy saline soils under a three-stage soil wateresalt regulation regime.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11888101,91421107,and 11574004)the National Key Research and Development Program of China(Grant Nos.2018YFA0305602 and 2016YFA0301003)。
文摘Realizing phase transitions via non-thermal sample manipulations is important not only for applications,but also for uncovering the underlying physics.Here,we report on the discovery of two distinct metal–insulator transitions in 1T-TaS_(2) via angle-resolved photoemission spectroscopy and in-situ rubidium deposition.At 205 K,the rubidium deposition drives a normal metal–insulator transition via filling electrons into the conduction band.While at 225 K,however,the rubidium deposition drives a bandwidth-controlled Mott transition as characterized by a rapid collapsing of Mott gap and a loss of spectral weight of the lower Hubbard band.Our result,from a doping-controlled perspective,succeeds in distinguishing the metallic,band-insulating,and Mott-insulating phases of 1T-TaS_(2),manifesting a delicate balance among the electronitineracy,interlayer-coupling and Coulomb repulsion.We also establish an effective method to tune the balance between these interactions,which is useful in seeking exotic electronic phases and designing functional phase-changing devices.
基金Sponsored by the National Natural Science Foundation of China(Grant No.52075258).
文摘Industrial robot which can acquire high accuracy has been widely used in automatic assembly.Usually,the geometric parameter of industrial robot should be inspected during manufacturing and application.High precision measurement equipment was utilized to acquire the position and orientation of robot’s end⁃effector,when calibrating the geometric parameter of robot.A kind of measurement system based on a draw⁃wire encoder was presented,since the current measurement equipment has some disadvantages,such as the cost and the requirements of working environment are high.According to this kind of measurement system,a sort of geometric calibration method of robot was presented including position and orientation parameters.The uncertain arc length of the cable length between robot end⁃effector and the measurement can be exactly acquired according to the position and orientation parameters.The pose⁃solving model of robot end⁃effector was associated with the kinematic model of robot,and robot’s geometric parameter can be computed by using the least⁃squares methods.Validate instance was conducted,the result showed that the optimal number of the calibration pose was 47 with little improvement in accuracy,even if increasing the number of calibration pose.Robot calibration experiment was performed and the results showed that the absolute accuracy of robot decreased from 4.32 mm to 0.87 mm after calibration,which improved the robot’s absolute accuracy effectively.
基金supports by the National Natural Science Foundation of China(Grant No.52172353 and 52202431).
文摘The cowcatcher is one of the unique devices at the front end of the train, which can remove obstacles on the track by crashing before the vehicle body to ensure the safety of the train. When a collision accident happens, the cowcatcher serves as the first energy-absorbing structure to dissipate and guide the collision energy. The design of the existing cowcatcher of multiple units generally focuses on the good ability to remove obstacles, while the secondary function, the crashworthiness of orderly deformation under collision, still needs further research. In this study, a finite element model of structural static load and collision analysis was established under standard EN 15227, with the cowcatcher for 160 km/h train as the prototype. Then the solution and simulation process was accomplished under the environment of ANSYS and LS-DYNA. The analysis results showed that the structural static strength of the current cowcatcher met the requirements of the standard EN 15227, and the longitudinal stiffness was evenly distributed. When removing the obstacles with low mass, the impact force was small and the structure would not produce obvious deformation;when removing the obstacles with large mass, the impact force was large and the shear fracture might occur at the connection of the cowcatcher.
