Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized. They readily formed different kinds of organized supramolecular assemblies, including vesicles, tapes, and micellar fibers,...Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized. They readily formed different kinds of organized supramolecular assemblies, including vesicles, tapes, and micellar fibers, in aqueous solution. The aggregates morphology was characterized by transmission electron microscopy (TEM) after negative staining. The superstructures of these aggregates seemed to be determined by the geometry and the head group's properties of the corresponding amphiphiles..展开更多
Diosgenyl alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (1) and Diosgenyl alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranoside (2) were shown to be fascinating '...Diosgenyl alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (1) and Diosgenyl alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranoside (2) were shown to be fascinating ''facial amphiphiles'' by conformational analysis based on NOE-MD method.展开更多
文摘Three types of single-chain hydrocarbon fluorocarbon hybrid bolaamphiphiles were synthesized. They readily formed different kinds of organized supramolecular assemblies, including vesicles, tapes, and micellar fibers, in aqueous solution. The aggregates morphology was characterized by transmission electron microscopy (TEM) after negative staining. The superstructures of these aggregates seemed to be determined by the geometry and the head group's properties of the corresponding amphiphiles..
文摘Diosgenyl alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside (1) and Diosgenyl alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranoside (2) were shown to be fascinating ''facial amphiphiles'' by conformational analysis based on NOE-MD method.
