A facile method for the selective synthesis of pillar[6]arenes has been developed.Due to a strong electron do-nor-acceptor interaction between the electron-deficient naphthalene diimide and a precursor for the pillara...A facile method for the selective synthesis of pillar[6]arenes has been developed.Due to a strong electron do-nor-acceptor interaction between the electron-deficient naphthalene diimide and a precursor for the pillararene,1,4-diisobutoxy-2,5-bis(methoxymethyl)benzene,naphthalene diimide has been demonstrated to act as a template for selective synthesis of pillar[6]arene in a modest yield(30%).展开更多
基金supported by the National Natu-ral Science Foundation of China(No.21202020 and J1103303)the Doctoral Fund of Ministry of Education of China(20123514120002)the Science&Tech-nical Development Foundation of Fuzhou University(Nos.2012-XQ-10 and 2013-XQ-14).
文摘A facile method for the selective synthesis of pillar[6]arenes has been developed.Due to a strong electron do-nor-acceptor interaction between the electron-deficient naphthalene diimide and a precursor for the pillararene,1,4-diisobutoxy-2,5-bis(methoxymethyl)benzene,naphthalene diimide has been demonstrated to act as a template for selective synthesis of pillar[6]arene in a modest yield(30%).
