All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable performance.However,their atomically precise structures remain undefined,...All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable performance.However,their atomically precise structures remain undefined,complicating their optimization and limiting the understanding of their enhanced performance.Here,the underlying structure-property correlation is explored by using a well-defined cobalt-phosphate polyoxometalate cluster [{(Co4)(OH)3(PO4)}4(SiW9 O34)4]^32-(1),which may serve as a molecular model of multimetal hydr(oxy)oxides.The catalytic activity is enhanced upon replacing Co by Fe in 1,resulting in a reduced overpotential(385 mV) for oxygen evolution(by 66 mV) compared to that of the parent 1 at 10 mA cm^-2 in an acidic medium;this overpotential is comparable to that for the IrO2 catalyst These abundant-metal-based polyoxometalates exhibit high stability,with no evidence of degradation even after 24 h of operation.展开更多
We report on the optical color variability of a sample of 24 blazars, consisting of nine flat spectrum radio quasars(FSRQs) and 15 BL Lacertae objects(BL Lacs), on timescales of years using simultaneous V-and R-band o...We report on the optical color variability of a sample of 24 blazars, consisting of nine flat spectrum radio quasars(FSRQs) and 15 BL Lacertae objects(BL Lacs), on timescales of years using simultaneous V-and R-band observations observed by the Kanata telescope at Higashi-Hiroshima Observatory.The correlations between color indices V-R and magnitudes reveal that 11 BL Lacs and one FSRQ exhibited significant(i.e., r > 0.2 and P < 0.01) bluer-when-brighter(BWB) trend and two FSRQs followed the redder-when-brighter(RWB) tend, indicating a possibility that the BWB chromatic trend is dominant for BL Lacs and the RWB trend is especially found in FSRQs, which has been presented occasionally in different samples of blazars.The superpositions of the red emission component from the Doppler-boosted relativistic jet and the blue component arising from the accretion disk might be a possible interpretation for the long-term color behaviors.展开更多
文摘All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable performance.However,their atomically precise structures remain undefined,complicating their optimization and limiting the understanding of their enhanced performance.Here,the underlying structure-property correlation is explored by using a well-defined cobalt-phosphate polyoxometalate cluster [{(Co4)(OH)3(PO4)}4(SiW9 O34)4]^32-(1),which may serve as a molecular model of multimetal hydr(oxy)oxides.The catalytic activity is enhanced upon replacing Co by Fe in 1,resulting in a reduced overpotential(385 mV) for oxygen evolution(by 66 mV) compared to that of the parent 1 at 10 mA cm^-2 in an acidic medium;this overpotential is comparable to that for the IrO2 catalyst These abundant-metal-based polyoxometalates exhibit high stability,with no evidence of degradation even after 24 h of operation.
基金supported by the Education Department of Yunnan Province, China (Grant Nos.2017ZZX079, 2016ZZX230 and 2018JS506)the Youth Program of the Applied Basic Research Projects of Yunnan Province, China (Grant No.2017FD147)
文摘We report on the optical color variability of a sample of 24 blazars, consisting of nine flat spectrum radio quasars(FSRQs) and 15 BL Lacertae objects(BL Lacs), on timescales of years using simultaneous V-and R-band observations observed by the Kanata telescope at Higashi-Hiroshima Observatory.The correlations between color indices V-R and magnitudes reveal that 11 BL Lacs and one FSRQ exhibited significant(i.e., r > 0.2 and P < 0.01) bluer-when-brighter(BWB) trend and two FSRQs followed the redder-when-brighter(RWB) tend, indicating a possibility that the BWB chromatic trend is dominant for BL Lacs and the RWB trend is especially found in FSRQs, which has been presented occasionally in different samples of blazars.The superpositions of the red emission component from the Doppler-boosted relativistic jet and the blue component arising from the accretion disk might be a possible interpretation for the long-term color behaviors.
