The use of radioactive isotopes,such as Cs-137,to measure formation density is a common practice;however,it poses high risks such as environmental contamination from lost sources.To address these challenges,the use of...The use of radioactive isotopes,such as Cs-137,to measure formation density is a common practice;however,it poses high risks such as environmental contamination from lost sources.To address these challenges,the use of pulsed neutron sources for density measurements,also known as“source-less density”,has emerged as a promising alternative.By collecting gamma counts at different time gates according to the duty cycle of the pulsed sequence,the inelastic gamma component can be isolated to obtain more accurate density measurements.However,the collection of gamma rays during the neutron burst-on period often contains a proportion of capture gamma rays,which can reduce the accuracy of density measurements.This proportion can vary depending on the formation environment and neutron duty cycle.To address these challenges,an adaptive capture gamma correction method was developed for density measurements.This method distinguishes between“burst-on”and“burst-off”periods based on the gamma time spectra,and derives the capture ratio in the burst-on period by iteratively fitting the capture gamma time spectra,resulting in a more accurate net inelastic gamma.This method identifies the end of the pulse by automatically calculating the differential,and fits the capture gamma time spectra using Gaussian process regression,which considers the differences in formation attenuation caused by different environments.The method was verified through simulations with errors of below 0.025 g/cm3,demonstrating its adaptability and feasibility for use in formation density measurements.Overall,the proposed method has the potential to minimize the risks associated with radioactive isotopes and improve the accuracy of density measurements in various duty cycles and formation environments.展开更多
Due to its properties of mutagenic,teratogenic,and carcinogenic,the detection of furazolidone(FZD)in aquaculture is of great importance for food safety and human health.In this study,molecularly imprinted fi lms modif...Due to its properties of mutagenic,teratogenic,and carcinogenic,the detection of furazolidone(FZD)in aquaculture is of great importance for food safety and human health.In this study,molecularly imprinted fi lms modifi ed with carboxylated multi-walled carbon nanotube-phosphomolybdic acid composite were used to fabricate an electrochemical sensor for the determination of FZD.The nanocomposites were characterized using infrared spectroscopy,scanning electron microscopy,energy-dispersive X-ray spectroscopy,and X-ray diff raction.The electrochemical characteristics of the modifi ed electrodes were examined using electrochemical impedance spectroscopy,cyclic voltammetry,and diff erential pulse voltammetry.The sensor exhibited exceptional catalytic performance.The calibration curves were acquired in the concentration range of 6 nmol·L^(−1)to 0.6μmol·L^(−1),with a limit of detection of 3.38 nmol·L^(−1).Additionally,the sensor proved successful in recognizing FZD in shrimp samples with satisfactory recoveries and precision.The method provides a strategy to construct a molecularly imprinted electrochemical sensing platform using nanomaterials,which has great promise in the field of food safety.展开更多
基金supported by the National Natural Science Foundation of China(No.52171253)the Natural Science Foundation of Sichuan(No.2022NSFSC0949).
文摘The use of radioactive isotopes,such as Cs-137,to measure formation density is a common practice;however,it poses high risks such as environmental contamination from lost sources.To address these challenges,the use of pulsed neutron sources for density measurements,also known as“source-less density”,has emerged as a promising alternative.By collecting gamma counts at different time gates according to the duty cycle of the pulsed sequence,the inelastic gamma component can be isolated to obtain more accurate density measurements.However,the collection of gamma rays during the neutron burst-on period often contains a proportion of capture gamma rays,which can reduce the accuracy of density measurements.This proportion can vary depending on the formation environment and neutron duty cycle.To address these challenges,an adaptive capture gamma correction method was developed for density measurements.This method distinguishes between“burst-on”and“burst-off”periods based on the gamma time spectra,and derives the capture ratio in the burst-on period by iteratively fitting the capture gamma time spectra,resulting in a more accurate net inelastic gamma.This method identifies the end of the pulse by automatically calculating the differential,and fits the capture gamma time spectra using Gaussian process regression,which considers the differences in formation attenuation caused by different environments.The method was verified through simulations with errors of below 0.025 g/cm3,demonstrating its adaptability and feasibility for use in formation density measurements.Overall,the proposed method has the potential to minimize the risks associated with radioactive isotopes and improve the accuracy of density measurements in various duty cycles and formation environments.
基金Supported by the National Natural Science Foundation of China(Grant No.22271119).
文摘Due to its properties of mutagenic,teratogenic,and carcinogenic,the detection of furazolidone(FZD)in aquaculture is of great importance for food safety and human health.In this study,molecularly imprinted fi lms modifi ed with carboxylated multi-walled carbon nanotube-phosphomolybdic acid composite were used to fabricate an electrochemical sensor for the determination of FZD.The nanocomposites were characterized using infrared spectroscopy,scanning electron microscopy,energy-dispersive X-ray spectroscopy,and X-ray diff raction.The electrochemical characteristics of the modifi ed electrodes were examined using electrochemical impedance spectroscopy,cyclic voltammetry,and diff erential pulse voltammetry.The sensor exhibited exceptional catalytic performance.The calibration curves were acquired in the concentration range of 6 nmol·L^(−1)to 0.6μmol·L^(−1),with a limit of detection of 3.38 nmol·L^(−1).Additionally,the sensor proved successful in recognizing FZD in shrimp samples with satisfactory recoveries and precision.The method provides a strategy to construct a molecularly imprinted electrochemical sensing platform using nanomaterials,which has great promise in the field of food safety.
