The multiple filamentation of terawatt femtosecond (fs) laser pulses is experimentally studied in a natural environment. A more than 30-m long plasma filament with a millimeter diameter is formed by the collimated f...The multiple filamentation of terawatt femtosecond (fs) laser pulses is experimentally studied in a natural environment. A more than 30-m long plasma filament with a millimeter diameter is formed by the collimated fs laser pulse freely propagating in an open atmosphere. This study provides the first quantitative experimental data about the electron density of a long range light filament in the atmosphere. The electron density of such a filament is quantitatively detected by using an electric method, showing that it is at the 1011-cm -3 level.展开更多
Smart fire alarm sensor(FAS)materials with mechanically robust,excellent flame retardancy as well as ultra-sensitive temperature-responsive capability are highly attractive platforms for fire safety application.Howeve...Smart fire alarm sensor(FAS)materials with mechanically robust,excellent flame retardancy as well as ultra-sensitive temperature-responsive capability are highly attractive platforms for fire safety application.However,most reported FAS materials can hardly provide sensitive,continuous and reliable alarm signal output due to their undesirable temperature-responsive,flame-resistant and mechanical performances.To overcome these hurdles,herein,we utilize the multi-amino molecule,named HCPA,that can serve as triple-roles including cross-linker,fire retardant and reducing agent for decorating graphene oxide(GO)sheets and obtaining the GO/HCPA hybrid networks.Benefiting from the formation of multi-interactions in hybrid network,the optimized GO/HCPA network exhibits significant increment in mechanical strength,e.g.,tensile strength and toughness increase of~2.3and~5.7 times,respectively,compared to the control one.More importantly,based on P and N doping and promoting thermal reduction effect on GO network,the excellent flame retardancy(withstanding~1200℃flame attack),ultra-fast fire alarm response time(~0.6 s)and ultra-long alarming period(>600 s)are obtained,representing the best comprehensive performance of GO-based FAS counterparts.Furthermore,based on GO/HCPA network,the fireproof coating is constructed and applied in polymer foam and exhibited exceptional fire shielding performance.This work provides a new idea for designing and fabricating desirable FAS materials and fireproof coatings.展开更多
The singular points of a 6-SPS Stewart platform are distributed on the multi-dimensional singularity hypersurface in the task-space, which divides the workspace of the manipulator into several singularity-free regions...The singular points of a 6-SPS Stewart platform are distributed on the multi-dimensional singularity hypersurface in the task-space, which divides the workspace of the manipulator into several singularity-free regions. Because of the motion un- certainty at singular points, while the manipulator traverses this kind of hypersurface from one singularity-free region to another, its motion cannot be predetermined. In this paper, a detailed approach for the manipulator to traverse the singularity hypersurface with its non-persistent configuration is presented. First, the singular point transfer disturbance and the pose disturbance, which make the perturbed singular point transfer horizontally and vertically, respectively, are constructed. Through applying these disturbances into the input parameters within the maximum loss control domain, the perturbed persistent configuration is transformed into its corresponding non-persistent one. Under the action of the disturbances, the manipulator can traverse the singularity hypersurface from one singularity-flee region to another with a desired configuration.展开更多
Development of multifunctional and high-performance silicone aerogel is highly required for various promising applications.However,unstable cross-linking structure and poor thermal stability of silicone network as wel...Development of multifunctional and high-performance silicone aerogel is highly required for various promising applications.However,unstable cross-linking structure and poor thermal stability of silicone network as well as complicated processing restrict the practical use significantly.Herein,we report a facile and versatile ambient drying strategy to fabricate lightweight,wide-temperature flexible,super-hydrophobic and flame retardant silicone composite aerogels modified with low-content functionalized graphene oxide(FGO).After optimizing silane molecules,incorporation ofγ-aminopropyltriethoxysilane functionalization is found to promote the dispersion stability of GO during the hydrolysis-polymerization process and thus produce the formation of unique strip-like co-cross-linked network.Consequently,the aerogels containing∼2.0 wt%FGO not only possess good cyclic compressive stability under strain of 70%for 100 cycles and outstanding mechanical reliability in wide temperature range(from liquid nitrogen to 350℃),but also display excellent flame resistance and super-hydrophobicity.Further,the optimized silicone/FGO aerogels display exceptional thermal insulating performance superior to pure aerogel and hydrocarbon polymer foams,and they also show efficient oil absorption and separation capacity for var-ious solvents and oil from water.Clearly,this work provides a new route for the rational design and development of advanced silicone composite aerogels for multifunctional applications.展开更多
It is found that there is an upper-limit critical power for self-guided propagation of intense lasers in plasma in addition to the well-known lower-limit critical power set by the relativistic effect.Above this upper-...It is found that there is an upper-limit critical power for self-guided propagation of intense lasers in plasma in addition to the well-known lower-limit critical power set by the relativistic effect.Above this upper-limit critical power,the laser pulse experiences defocusing due to expulsion of local plasma electrons by the transverse ponderomotive force.Associated with the upper-limit power,a lower-limit critical plasma density is also found for a given laser spot size,below which self-focusing does not occur for any laser power.Both the upper-limit power and the lower-limit density are derived theoretically and verified by two-dimensional particle-in-cell simulations.The present study provides new guidance for experimental designs,where self-guided propagation of lasers is essential.展开更多
The authors would like to apologize for an error found in the acknowledgement section on page 79.The acknowledgement should read:This work is supported in part by National Basic Research Program of China(Grant No.2013...The authors would like to apologize for an error found in the acknowledgement section on page 79.The acknowledgement should read:This work is supported in part by National Basic Research Program of China(Grant No.2013CBA01501)and展开更多
Temperature-re s ponsive resistance transition behaviors of the melamine sponges wrapped with different graphene oxide derivatives(i.e.nanoribbon,wide-ribbon and sheet)were investigated.Melamine sponge composites coat...Temperature-re s ponsive resistance transition behaviors of the melamine sponges wrapped with different graphene oxide derivatives(i.e.nanoribbon,wide-ribbon and sheet)were investigated.Melamine sponge composites coated by three types of GO derivatives were prepared by a simple dip-coating approach.All these composites show good mechanical flexibility and reliability(almost unchanged compressive stress at 70%strain after 100 cycles),high hydrophobicity(water contact angle>120°),excellent flame resistance(self-extinguishing)and structural stability even after burning,which was used to construct the resistance-based fire alarm/warning sensor.Notably,the different resistance response behaviors of such sensors are strongly dependent on the GO size and network formed on the MF skeleton surface.Typically,at a fixed high temperature of~350℃,the three fire alarm sensors show different response time(to trigger the alarm light)of 6.3,8.4 and 11.1 s for nanoribbon,wide-ribbon and sheet at the same concentration,respectively.The structural observation and chemical analysis demonstrated that the discrepancy of temperature-responsive resistance transition behaviors of various GO derivatives was strongly determined by their different thermal reduction degrees during the high-tempe rature or flame treating process.This work offers a design and development for construction of smart fire alarm device for potential fire prevention and safety applications.展开更多
With the development of ultraintense terawatt(TW) and petawatt(PW) laser systems, powerful terahertz(THz) radiation from laser–plasma interactions has been reported. Plasma-based THz systems, which are usually operat...With the development of ultraintense terawatt(TW) and petawatt(PW) laser systems, powerful terahertz(THz) radiation from laser–plasma interactions has been reported. Plasma-based THz systems, which are usually operated at extremely low repetition rates, call for single-shot diagnostics. In this paper, various state-of-the-art single-shot detection methods are introduced or designed for measurements and applications involved in high-power plasma-based THz sciences.展开更多
Uveitis is a sophisticated syndrome showing a high relevance with reactive oxygen species(ROS).Herein,an ROS-responsive PEGylated polypeptide based macromolecular prodrug of herbaceous antioxidant ethyl caffeate(EC)is...Uveitis is a sophisticated syndrome showing a high relevance with reactive oxygen species(ROS).Herein,an ROS-responsive PEGylated polypeptide based macromolecular prodrug of herbaceous antioxidant ethyl caffeate(EC)is designed via phenylboronic esters with improved solubility for the alleviation of uveitis.The antioxidative 4-hydroxybenzyl alcohol(HBA)and EC can be released from the macromolecular EC prodrug under the stimulation of ROS,which can effectively protect cells against oxidative stress-induced injury in an ROS-depletion way.The antioxidative and protective effects of the macromolecular EC prodrug in vivo are further verified in a uveitis mouse model.Overall,this work not only provides a handy method to synthesize a phenylboronic ester-bearing EC prodrug which is highly sensitive to pathological ROS,but also depicts a promising future to apply macromolecular antioxidative prodrugs in the treatment of uveitis as well as other ROS-related diseases.展开更多
In this paper, the recent studies of laboratory astrophysics with strong magnetic fields in China have been reviewed.On the Shenguang-II laser facility of the National Laboratory on High-Power Lasers and Physics, a la...In this paper, the recent studies of laboratory astrophysics with strong magnetic fields in China have been reviewed.On the Shenguang-II laser facility of the National Laboratory on High-Power Lasers and Physics, a laser-driven strong magnetic field up to 200 T has been achieved. The experiment was performed to model the interaction of solar wind with dayside magnetosphere. Also the low beta plasma magnetic reconnection(MR) has been studied. Theoretically, the model has been developed to deal with the atomic structures and processes in strong magnetic field. Also the study of shock wave generation in the magnetized counter-streaming plasmas is introduced.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11574387,11404335,11474002,and 11535001)the National Basic Research Program of China(Grant Nos.2013CBA01501 and 2013CB922401)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grants Nos.XDB16010200 and XDB07030300)the Science Challenge Project,China(Grant No.TZ2016005)
文摘The multiple filamentation of terawatt femtosecond (fs) laser pulses is experimentally studied in a natural environment. A more than 30-m long plasma filament with a millimeter diameter is formed by the collimated fs laser pulse freely propagating in an open atmosphere. This study provides the first quantitative experimental data about the electron density of a long range light filament in the atmosphere. The electron density of such a filament is quantitatively detected by using an electric method, showing that it is at the 1011-cm -3 level.
基金The research work was financially supported by the Australian Research Council(Nos.DE190101176,FT190100188,DP190102992,IC170100032)the National Natural Science Foundation of China(51973047)+2 种基金the Project for the Science and Technology Program of Hangzhou(20201203B136,20201203B134)the International Collaboration Programs of Guangdong Province(2020A0505100010)Open access funding provided by Shanghai Jiao Tong University
文摘Smart fire alarm sensor(FAS)materials with mechanically robust,excellent flame retardancy as well as ultra-sensitive temperature-responsive capability are highly attractive platforms for fire safety application.However,most reported FAS materials can hardly provide sensitive,continuous and reliable alarm signal output due to their undesirable temperature-responsive,flame-resistant and mechanical performances.To overcome these hurdles,herein,we utilize the multi-amino molecule,named HCPA,that can serve as triple-roles including cross-linker,fire retardant and reducing agent for decorating graphene oxide(GO)sheets and obtaining the GO/HCPA hybrid networks.Benefiting from the formation of multi-interactions in hybrid network,the optimized GO/HCPA network exhibits significant increment in mechanical strength,e.g.,tensile strength and toughness increase of~2.3and~5.7 times,respectively,compared to the control one.More importantly,based on P and N doping and promoting thermal reduction effect on GO network,the excellent flame retardancy(withstanding~1200℃flame attack),ultra-fast fire alarm response time(~0.6 s)and ultra-long alarming period(>600 s)are obtained,representing the best comprehensive performance of GO-based FAS counterparts.Furthermore,based on GO/HCPA network,the fireproof coating is constructed and applied in polymer foam and exhibited exceptional fire shielding performance.This work provides a new idea for designing and fabricating desirable FAS materials and fireproof coatings.
基金Project (Nos. 50375111 and 50675188) supported by the National Natural Science Foundation of China
文摘The singular points of a 6-SPS Stewart platform are distributed on the multi-dimensional singularity hypersurface in the task-space, which divides the workspace of the manipulator into several singularity-free regions. Because of the motion un- certainty at singular points, while the manipulator traverses this kind of hypersurface from one singularity-free region to another, its motion cannot be predetermined. In this paper, a detailed approach for the manipulator to traverse the singularity hypersurface with its non-persistent configuration is presented. First, the singular point transfer disturbance and the pose disturbance, which make the perturbed singular point transfer horizontally and vertically, respectively, are constructed. Through applying these disturbances into the input parameters within the maximum loss control domain, the perturbed persistent configuration is transformed into its corresponding non-persistent one. Under the action of the disturbances, the manipulator can traverse the singularity hypersurface from one singularity-flee region to another with a desired configuration.
基金financially supported by the National Natural Science Foundation of China (Nos. 51973047 and 12002112)the Science Foundation and Technology Project of Zhejiang Province (No. Z22E035302)+1 种基金the Science Foundation and Technology Project of Shandong Province (No. ZR2020LFG004)the Project for Science and Technology Program of Hangzhou (Nos. 20191203B16 and 20201203B136)
文摘Development of multifunctional and high-performance silicone aerogel is highly required for various promising applications.However,unstable cross-linking structure and poor thermal stability of silicone network as well as complicated processing restrict the practical use significantly.Herein,we report a facile and versatile ambient drying strategy to fabricate lightweight,wide-temperature flexible,super-hydrophobic and flame retardant silicone composite aerogels modified with low-content functionalized graphene oxide(FGO).After optimizing silane molecules,incorporation ofγ-aminopropyltriethoxysilane functionalization is found to promote the dispersion stability of GO during the hydrolysis-polymerization process and thus produce the formation of unique strip-like co-cross-linked network.Consequently,the aerogels containing∼2.0 wt%FGO not only possess good cyclic compressive stability under strain of 70%for 100 cycles and outstanding mechanical reliability in wide temperature range(from liquid nitrogen to 350℃),but also display excellent flame resistance and super-hydrophobicity.Further,the optimized silicone/FGO aerogels display exceptional thermal insulating performance superior to pure aerogel and hydrocarbon polymer foams,and they also show efficient oil absorption and separation capacity for var-ious solvents and oil from water.Clearly,this work provides a new route for the rational design and development of advanced silicone composite aerogels for multifunctional applications.
基金supported in part by NSFC (Grant Nos. 11105217, 11121504, and 10925421)National Basic Research Program of China (Grant No. 2009GB105002)
文摘It is found that there is an upper-limit critical power for self-guided propagation of intense lasers in plasma in addition to the well-known lower-limit critical power set by the relativistic effect.Above this upper-limit critical power,the laser pulse experiences defocusing due to expulsion of local plasma electrons by the transverse ponderomotive force.Associated with the upper-limit power,a lower-limit critical plasma density is also found for a given laser spot size,below which self-focusing does not occur for any laser power.Both the upper-limit power and the lower-limit density are derived theoretically and verified by two-dimensional particle-in-cell simulations.The present study provides new guidance for experimental designs,where self-guided propagation of lasers is essential.
文摘The authors would like to apologize for an error found in the acknowledgement section on page 79.The acknowledgement should read:This work is supported in part by National Basic Research Program of China(Grant No.2013CBA01501)and
基金the funding support from the Natural Science Foundation of China(Nos.51973047 and 12002112)the Natural Science Foundation of Zhejiang Province(Nos.LY18E030005 and LY15E030015)+1 种基金the Science and Technology Project of Zhejiang Province(No.LGG20B040002)the Science and Technology Program of Hangzhou(Nos.20191203B16 and 20180533B01)。
文摘Temperature-re s ponsive resistance transition behaviors of the melamine sponges wrapped with different graphene oxide derivatives(i.e.nanoribbon,wide-ribbon and sheet)were investigated.Melamine sponge composites coated by three types of GO derivatives were prepared by a simple dip-coating approach.All these composites show good mechanical flexibility and reliability(almost unchanged compressive stress at 70%strain after 100 cycles),high hydrophobicity(water contact angle>120°),excellent flame resistance(self-extinguishing)and structural stability even after burning,which was used to construct the resistance-based fire alarm/warning sensor.Notably,the different resistance response behaviors of such sensors are strongly dependent on the GO size and network formed on the MF skeleton surface.Typically,at a fixed high temperature of~350℃,the three fire alarm sensors show different response time(to trigger the alarm light)of 6.3,8.4 and 11.1 s for nanoribbon,wide-ribbon and sheet at the same concentration,respectively.The structural observation and chemical analysis demonstrated that the discrepancy of temperature-responsive resistance transition behaviors of various GO derivatives was strongly determined by their different thermal reduction degrees during the high-tempe rature or flame treating process.This work offers a design and development for construction of smart fire alarm device for potential fire prevention and safety applications.
基金supported by the National Basic Research Program of China(grant no.2013CBA01501)the National Nature Science Foundation of China(grant nos.11135012and 11375262)the Key Research Program of the Chinese Academy of Science(grant no.KGZD-EW-T05)
文摘With the development of ultraintense terawatt(TW) and petawatt(PW) laser systems, powerful terahertz(THz) radiation from laser–plasma interactions has been reported. Plasma-based THz systems, which are usually operated at extremely low repetition rates, call for single-shot diagnostics. In this paper, various state-of-the-art single-shot detection methods are introduced or designed for measurements and applications involved in high-power plasma-based THz sciences.
基金financially supported by National Key Research and Development Project (No. 2020YFE0204400)
文摘Uveitis is a sophisticated syndrome showing a high relevance with reactive oxygen species(ROS).Herein,an ROS-responsive PEGylated polypeptide based macromolecular prodrug of herbaceous antioxidant ethyl caffeate(EC)is designed via phenylboronic esters with improved solubility for the alleviation of uveitis.The antioxidative 4-hydroxybenzyl alcohol(HBA)and EC can be released from the macromolecular EC prodrug under the stimulation of ROS,which can effectively protect cells against oxidative stress-induced injury in an ROS-depletion way.The antioxidative and protective effects of the macromolecular EC prodrug in vivo are further verified in a uveitis mouse model.Overall,this work not only provides a handy method to synthesize a phenylboronic ester-bearing EC prodrug which is highly sensitive to pathological ROS,but also depicts a promising future to apply macromolecular antioxidative prodrugs in the treatment of uveitis as well as other ROS-related diseases.
基金supported by National Basic Research Program of China (973 Program) under grant No.2013CBA01503the National Natural Science Foundation of China under grant No.11573040, 11503041 and 11135012supported by the Science Challenge Program
文摘In this paper, the recent studies of laboratory astrophysics with strong magnetic fields in China have been reviewed.On the Shenguang-II laser facility of the National Laboratory on High-Power Lasers and Physics, a laser-driven strong magnetic field up to 200 T has been achieved. The experiment was performed to model the interaction of solar wind with dayside magnetosphere. Also the low beta plasma magnetic reconnection(MR) has been studied. Theoretically, the model has been developed to deal with the atomic structures and processes in strong magnetic field. Also the study of shock wave generation in the magnetized counter-streaming plasmas is introduced.