Microflowers made of interconnected MnO2 nanosheets have been successfully synthesized in a microwave reactor through a hydrothermal reduction of KMnO4 with aqueous HCI at elevated temperatures in the presence of supe...Microflowers made of interconnected MnO2 nanosheets have been successfully synthesized in a microwave reactor through a hydrothermal reduction of KMnO4 with aqueous HCI at elevated temperatures in the presence of superparamagnetic Fe3O4SiO2 core-shell nanoparticles.Due to the chemical compatibility between SiO2 and MnO2,the heterogeneous reaction leads to the spontaneous encapsulation of the Fe3O4@SiO2 core-shell nanoparticles in the MnO2 microflowers.The resulting hybrid particles exhibit multiple properties including high surface area associated with the MnO2nanosheets and superparamagnetism originated from the Fe3O4@SiO2 core-shell nanoparticles.which are beneficial for applications requiring both high surface area and magnetic separation.展开更多
In this paper,we consider the statistical inferences in a partially linear model when the model error follows an autoregressive process.A two-step procedure is proposed for estimating the unknown parameters by taking ...In this paper,we consider the statistical inferences in a partially linear model when the model error follows an autoregressive process.A two-step procedure is proposed for estimating the unknown parameters by taking into account of the special structure in error.Since the asymptotic matrix of the estimator for the parametric part has a complex structure,an empirical likelihood function is also developed.We derive the asymptotic properties of the related statistics under mild conditions.Some simulations,as well as a real data example,are conducted to illustrate the finite sample performance.展开更多
基金supported by the U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences,under Contract No.DE-AC02-06CH11357
文摘Microflowers made of interconnected MnO2 nanosheets have been successfully synthesized in a microwave reactor through a hydrothermal reduction of KMnO4 with aqueous HCI at elevated temperatures in the presence of superparamagnetic Fe3O4SiO2 core-shell nanoparticles.Due to the chemical compatibility between SiO2 and MnO2,the heterogeneous reaction leads to the spontaneous encapsulation of the Fe3O4@SiO2 core-shell nanoparticles in the MnO2 microflowers.The resulting hybrid particles exhibit multiple properties including high surface area associated with the MnO2nanosheets and superparamagnetism originated from the Fe3O4@SiO2 core-shell nanoparticles.which are beneficial for applications requiring both high surface area and magnetic separation.
基金supported by the NSF of China(Nos.11971208,11601197)the NSSF of China(Grant No.21&ZD152)+2 种基金the China Postdoctoral Science Foundation(Nos.2016M600511,2017T100475)the NSF of Jiangxi Province(Nos.2018ACB21002,20171ACB21030)the Post graduate Innovation Project of Jiangxi Province(No.YC2021CB124)。
文摘In this paper,we consider the statistical inferences in a partially linear model when the model error follows an autoregressive process.A two-step procedure is proposed for estimating the unknown parameters by taking into account of the special structure in error.Since the asymptotic matrix of the estimator for the parametric part has a complex structure,an empirical likelihood function is also developed.We derive the asymptotic properties of the related statistics under mild conditions.Some simulations,as well as a real data example,are conducted to illustrate the finite sample performance.
