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磁控溅射镀铝AZ31镁合金等离子体电解氧化揭示的放电通道结构及其腐蚀行为
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作者 胡攀峰 魏兵剑 +1 位作者 程昱琳 程英亮 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第1期139-156,共18页
在硅酸盐-六偏磷酸盐电解液中对覆盖薄磁控溅射铝层的AZ31镁合金进行等离子体电解氧化(PEO),以研究PEO机理并提高合金的耐腐蚀性。使用SEM和EDS检测涂层形貌并追踪涂层中Mg和Al元素的分布。新的涂层主要在靠近涂层/金属基体界面的放电... 在硅酸盐-六偏磷酸盐电解液中对覆盖薄磁控溅射铝层的AZ31镁合金进行等离子体电解氧化(PEO),以研究PEO机理并提高合金的耐腐蚀性。使用SEM和EDS检测涂层形貌并追踪涂层中Mg和Al元素的分布。新的涂层主要在靠近涂层/金属基体界面的放电通道下部形成。在放电通道上部先前形成的氧化物大部分以固态形式保留在原先的位置,只有少部分熔融氧化物通过涂层的微孔流出,到达表层。阴离子可以通过涂层充满电解液的孔传输,自由地进入涂层的最深部位。在3.5%NaCl (质量分数)中进行开路电位、极化曲线和EIS测试。结果表明,致密的磁控溅射Al层可以显着提高AZ31镁合金的耐腐蚀性,其耐腐蚀性甚至优于PEO处理后的样品。 展开更多
关键词 AZ31镁合金 磁控溅射Al层 等离子体电解氧化 放电通道 耐腐蚀性能
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Weak Merging Scenario of CLASH Cluster A209
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作者 Wen-cheng Feng Heng Yu +7 位作者 Hai-Hui Zhao Xiao-Lan Hou Shu-Mei Jia cheng-Kui Li yu-lin cheng Paolo Tozzi Ming Sun Yong Chen 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2024年第4期174-182,共9页
We study the structural and dynamical properties of A209 based on Chandra and XMM-Newton observations.We obtain detailed temperature,pressure,and entropy maps with the contour binning method,and find a hot region in t... We study the structural and dynamical properties of A209 based on Chandra and XMM-Newton observations.We obtain detailed temperature,pressure,and entropy maps with the contour binning method,and find a hot region in the NW direction.The X-ray brightness residual map and corresponding temperature profiles reveal a possible shock front in the NW direction and a cold front feature in the SE direction.Combined with the galaxy luminosity density map we propose a weak merger scenario.A young sub-cluster passing from the SE to NW direction could explain the optical subpeak,the intracluster medium temperature map,the X-ray surface brightness excess,and the X-ray peak offset together. 展开更多
关键词 X rays:galaxies:clusters galaxies:clusters:intracluster medium galaxies:clusters:Abell 209
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The Year-scale X-Ray Variations in the Core of M87
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作者 yu-lin cheng Fei Xiang +5 位作者 Heng Yu Shu-Mei Jia Xiang-Hua Li cheng-Kui Li Yong Chen Wen-cheng Feng 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2023年第6期203-211,共9页
The analysis of light variation of M87 can help us understand the disk evolution.In the past decade,M87 has experienced several short-term light variabilities related to flares.We also find that there are year-scale X... The analysis of light variation of M87 can help us understand the disk evolution.In the past decade,M87 has experienced several short-term light variabilities related to flares.We also find that there are year-scale X-ray variations in the core of M87.Their light variability properties are similar to clumpy-ADAF.By re-analyzing 56Chandra observations from 2007 to 2019,we distinguish the“non-flaring state”from“flaring state”in the light variability.After removing flaring state data,we identify four gas clumps in the nucleus and all of them can be well fitted by the clumpy-ADAF model.The average mass accretion rate is~0.16M⊙yr^(-1).We analyze the photon index(Γ)-flux(2-10 keV)correlation between the non-flaring state and flaring state.For the non-flaring states,the flux is inversely proportional to the photon index.For the flaring states,we find no obvious correlation between the two parameters.In addition,we find that the flare always occurs at a high mass accretion rate,and after the luminosity of the flare reaches the peak,it will be accompanied by a sudden decrease in luminosity.Our results can be explained as that the energy released by magnetic reconnection destroys the structure of the accretion disk,thus the luminosity decreases rapidly and returns to normal levels thereafter. 展开更多
关键词 X-rays:galaxies galaxies:clusters:individual(M87) ACCRETION accretion disks
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磁控溅射和等离子体电解氧化双重工艺处理AZ31镁合金的耐蚀和耐磨性能 被引量:10
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作者 魏兵剑 程昱琳 +2 位作者 刘媛媛 朱准达 程英亮 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第8期2287-2306,共20页
为了提高AZ31镁合金的耐磨和耐腐蚀性能,通过磁控溅射法在合金表面涂覆约11μm的纯铝层,然后分别在铝酸盐和硅酸盐电解液中通过等离子电解氧化(PEO)进行表面处理。涂层的性能通过干滑动摩擦试验和电化学腐蚀试验进行研究。铝酸盐涂层在1... 为了提高AZ31镁合金的耐磨和耐腐蚀性能,通过磁控溅射法在合金表面涂覆约11μm的纯铝层,然后分别在铝酸盐和硅酸盐电解液中通过等离子电解氧化(PEO)进行表面处理。涂层的性能通过干滑动摩擦试验和电化学腐蚀试验进行研究。铝酸盐涂层在10和20 N的负载下均表现出良好的耐磨性能;硅酸盐涂层只在较低的载荷下(10 N)表现出良好的耐磨性能,在20 N下涂层被破坏。腐蚀测试表明,仅经磁控溅射处理的Al层不能对Mg衬底提供良好的腐蚀保护。但是,PEO/Al双层涂层能显著提高样品的耐蚀性能。根据电化学测试,铝酸盐和硅酸盐涂层的腐蚀电流密度分别为-1.6×10^(-6)和-1.1×10^(-6)A/cm^(2),该数值比未镀膜AZ31合金的腐蚀电流密度低两个数量级。此外,浸泡试验和电化学阻抗谱(EIS)表明,铝酸盐涂层表现出比硅酸盐涂层更好的长效腐蚀防护性能。 展开更多
关键词 AZ31镁合金 磁控溅射 等离子体电解氧化 干滑动摩擦 腐蚀
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氢氧化钠对中等浓度铝酸盐电解液中A356铝合金等离子体电解氧化的影响 被引量:3
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作者 程昱琳 谢焕钧 +1 位作者 曹金晖 程英亮 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第12期3677-3690,共14页
在32 g/L铝酸钠中加入不同浓度的氢氧化钠,对铸造A356铝合金进行等离子体电解氧化(PEO)处理。通过增加NaOH的浓度,铝酸盐溶液的稳定性大大提高。然而,由于氢氧化钠浓度的增加,PEO的行为发生相应的变化。在更高浓度的氢氧化钠电解液中,对... 在32 g/L铝酸钠中加入不同浓度的氢氧化钠,对铸造A356铝合金进行等离子体电解氧化(PEO)处理。通过增加NaOH的浓度,铝酸盐溶液的稳定性大大提高。然而,由于氢氧化钠浓度的增加,PEO的行为发生相应的变化。在更高浓度的氢氧化钠电解液中,对A356铝合金进行PEO处理时需要较厚的预生膜。结果表明,NaOH的最佳浓度为5 g/L,可将贮存电解液的稳定性提高至35天,并能获得高耐磨致密陶瓷膜层(磨损率为4.1×10^(−7)mm^(3)·N^(−1)·m^(−1))。 展开更多
关键词 等离子体电解氧化 耐磨性 铝酸钠 氢氧化钠 A356合金
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黄铜在含磷酸二氢钠或硅酸钠的铝酸盐电解液中的等离子电解氧化行为和耐腐蚀性能 被引量:2
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作者 程昱琳 冯恬 +2 位作者 吕佳慧 胡攀峰 程英亮 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第12期3985-3997,共13页
采用等离子电解氧化(PEO)技术对黄铜进行表面处理,研究其在铝酸盐电解液中分别加入NaH2PO4(S1)和Na2SiO3(S2)添加剂对涂层形成和耐腐蚀性能的影响。在S1电解液中进行PEO处理的初始阶段,黄铜表面形成AlPO4和Al2O3的混合涂层,导致快速产... 采用等离子电解氧化(PEO)技术对黄铜进行表面处理,研究其在铝酸盐电解液中分别加入NaH2PO4(S1)和Na2SiO3(S2)添加剂对涂层形成和耐腐蚀性能的影响。在S1电解液中进行PEO处理的初始阶段,黄铜表面形成AlPO4和Al2O3的混合涂层,导致快速产生等离子体火花放电现象并形成由Al2O3、CuO、Cu2O和ZnO组成的黑色涂层。然而,在S2电解液中,等离子体火花放电行为延迟产生。由于产生较多的Cu2O,S2涂层显示为深红棕色。Mott-Schottky测试表明,S1涂层为p型半导体;S2涂层具有n型和p型半导体可调性。动电位极化和电化学阻抗谱(EIS)测试表明,PEO处理能显著提高黄铜的耐腐蚀性,腐蚀防护效率可达91.50%,S1涂层电荷转移电阻最大可达59.95 kΩ·cm^(2)。 展开更多
关键词 等离子体电解氧化 黄铜 耐腐蚀性能 铝酸盐 磷酸二氢钠 硅酸钠
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Corrosion behavior of Cu/Al casting-rolled clad plates in different alkaline solution
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作者 Yi-fan Zhang Xiao-guang Yuan +2 位作者 Xiao-jiao Zuo Hong-jun Huang yu-lin cheng 《China Foundry》 SCIE CAS 2021年第5期513-520,共8页
The effect of pH value and different kinds of anions on the corrosion behavior of Cu/Al casting-rolled clad plates in the alkaline solution was evaluated by means of scanning electron microscopy(SEM),energy dispersive... The effect of pH value and different kinds of anions on the corrosion behavior of Cu/Al casting-rolled clad plates in the alkaline solution was evaluated by means of scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),X-ray diffraction(XRD),weight loss analysis,3D confocal laser scanning microscopy(CLSM)and electrochemical test.Results show the corrosion mainly occurs on the aluminum side.The corrosion resistance of the Cu/Al decreases as the pH value increases.When pH≥12,the dissolution of the film layer is faster than the passivation process.The addition of Cl^(-)ions reduces the corrosion resistance of the Cu/Al clad plates,which leads to pitting corrosion.The higher the concentration of Cl^(-)ions,the more prone the pitting to occur.The addition of SO_(4)^(2-)ions causes the denudation of the samples.The corrosion resistance of the Cu/Al is better in the alkaline solution containing NO_(3)^(-)ions than that in the solution containing Cl^(-)ions or SO_(4)^(2-)ions.When adding SO_(4)^(2-),NO^(3)^(-)and Cl^(-)to the pure alkaline solution,the corrosion resistance of the Cu/Al clad plates decreases. 展开更多
关键词 Cu/Al clad plates alkaline solution pH ANIONS ELECTROCHEMISTRY casting-rolled
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Chinese sunspot drawings and their digitization–(Ⅱ)accuracy analysis for digitized sunspot hand-drawing records of Yunnan Observatories
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作者 Yang Peng Xiao-Yu Luo +6 位作者 Shu-Guang Zeng Lin-Hua Deng Sheng Zheng Gang-Hua Lin yu-lin cheng Jin-Ping Tao Yong-Li Feng 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2020年第4期156-162,共7页
Sunspots are the most striking and easily observed magnetic structures of the Sun,and statistical analysis of solar historical data could reveal a wealth of information on the long-term variation of solar activity cyc... Sunspots are the most striking and easily observed magnetic structures of the Sun,and statistical analysis of solar historical data could reveal a wealth of information on the long-term variation of solar activity cycle.The hand-drawn sunspot records of Yunnan Observatories,Chinese Academy of Sciences have been accumulating for more than 60 years,and nearly 16000 images have been preserved.In the future,the observation mode of recording sunspots by hand-drawing will be replaced inevitably by digital images observed either at ground or in space.To connect the hand-drawn sunspot data and the purely digital sunspot data in future,it is necessary to analyze the systematic errors of the data which are observed by the two observation modes in the period of transition.In this paper,we choose 268 round sunspots(Htype in modified Zurich sunspot classification)from the drawing of Yunnan Observatories to compare their positions and areas with the CCD observations made by Helioseismic and Magnetic Imager(HMI)on board Solar Dynamic Observatory(SDO)and Global Oscillation Network Group(GONG).We find that the latitude and longitude accuracy of hand-drawn sunspot are within-0.127 and 2.29 degree respectively,and the area accuracy is about 16.36 sunspot unit(μHem).Systematic errors apparently decrease with large sunspot. 展开更多
关键词 SUNSPOTS methods:data analysis techniques:image processing
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Influence of DC Current on Corrosion Behaviour of Copper–Aluminium Composite Plates
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作者 yu-lin cheng Xiao-Jiao Zuo +2 位作者 Xiao-Guang Yuan Hong-Jun Huang Yi-Fan Zhang 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2021年第8期1142-1152,共11页
In this study, neutral salt spray accelerated corrosion test of copper–aluminium composite under 0–125 A DC current was carried out under 5% concentration. The effect of corrosion behaviour on copper–aluminium comp... In this study, neutral salt spray accelerated corrosion test of copper–aluminium composite under 0–125 A DC current was carried out under 5% concentration. The effect of corrosion behaviour on copper–aluminium composite by DC current was carried out by a scanning electron microscope(SEM) with energy-dispersive spectroscopy(EDS), X-ray diffraction(XRD) patterns, X-ray photoelectron spectroscopy(XPS), weight-loss method and electrochemical analysis. The results show that the current can accelerate the corrosion rate. Meanwhile, the current temperature effect can reduce the corrosion rate. The current caused directional migration of ions resulting in different corrosion products on positive and negative poles of specimen, and the corrosion degree on the positive pole was more serious. The galvanic corrosion mechanism at the copper–aluminium interface is different from the pitting corrosion mechanism far away from the interface, and the latter is more affected by DC current. 展开更多
关键词 Copper–aluminium composite CORROSION DC current Ionic migration Temperature effect
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