Nonspherical particles have attracted increasing interest because of their shape anisotropy.However,the current methods to prepare anisotropic particles suffer from complex generation processes and limited shape diver...Nonspherical particles have attracted increasing interest because of their shape anisotropy.However,the current methods to prepare anisotropic particles suffer from complex generation processes and limited shape diversity.Here,we develop a piezoelectric microfluidic system to generate complex flow configurations and fabricatejellyfish-like microparticles.In this delicate system,the piezoelectric vibration could evolve a jellyfish-like flow configuration in the microchannel and the in situ photopolymerization could instantly capture the flow architecture.The sizes and morphologies of the particles are precisely controlled by tuning the piezoelectric and microfluidic parameters.Furthermore,multi-compartmental microparticles with a dual-layer structure are achieved by modifying the injecting channel geometry.Moreover,such unique a shape endows the particles with flexible motion ability especially when stimuliresponsive materials are incorporated.On the basis of that,we demonstrate the capability of the jellyfish-like microparticles in highly efficient adsorption of organic pollutants under external control.Thus,it is believed that such jellyfish-like microparticles are highly versatile in potential applications and the piezoelectricintegrated microfluidic strategy could open an avenue for the creation of such anisotropic particles.展开更多
基金supported by the National Key Research and Development Program of China(2020YFB1313100)the National Natural Science Foundation of China(22002018,32271383,and 22202050)+1 种基金the Shenzhen Fundamental Research Program(JCYJ20190813152616459)the China Postdoctoral Science Foundation(2022M713103).
文摘Nonspherical particles have attracted increasing interest because of their shape anisotropy.However,the current methods to prepare anisotropic particles suffer from complex generation processes and limited shape diversity.Here,we develop a piezoelectric microfluidic system to generate complex flow configurations and fabricatejellyfish-like microparticles.In this delicate system,the piezoelectric vibration could evolve a jellyfish-like flow configuration in the microchannel and the in situ photopolymerization could instantly capture the flow architecture.The sizes and morphologies of the particles are precisely controlled by tuning the piezoelectric and microfluidic parameters.Furthermore,multi-compartmental microparticles with a dual-layer structure are achieved by modifying the injecting channel geometry.Moreover,such unique a shape endows the particles with flexible motion ability especially when stimuliresponsive materials are incorporated.On the basis of that,we demonstrate the capability of the jellyfish-like microparticles in highly efficient adsorption of organic pollutants under external control.Thus,it is believed that such jellyfish-like microparticles are highly versatile in potential applications and the piezoelectricintegrated microfluidic strategy could open an avenue for the creation of such anisotropic particles.
