A new approach to fullerene ferrocenyl derivative has been made. [60]Fullerene reacts with ferrocenylmethyl azide to give N-ferrocenylmethyl imino[60]fullerene in 42% yield.
p-tert-Butylcalix[4]diazacrown-4 telomer, which contains hard and soft ion binding sites, was synthesized. It exhibited high selectivity toward cesium ions. The binding sites may complex alkali metal ions selectively.
Nano CaCO3 was used as a condensation agent in the ring-opening reaction of p-tert-butylcalix[4]arene with epichlorohydrin to afford 5,11,17,23-tetra-tert-butyl-26,27,28-trihyd- roxy-25-(1-chloro-2-hydroxy-3-propyl)ca...Nano CaCO3 was used as a condensation agent in the ring-opening reaction of p-tert-butylcalix[4]arene with epichlorohydrin to afford 5,11,17,23-tetra-tert-butyl-26,27,28-trihyd- roxy-25-(1-chloro-2-hydroxy-3-propyl)calix[4]arene regioselectively in 52% yield. The yield was less than 2% by using normal CaCO3 instead of nano one under the same conditions.展开更多
A bisphosphate-bridged tetrahomodioxacalix[6]arene with a C2v symmetry at the ambient temperature was obtained by the reaction of tetrahomodioxacalix[6]arene with POCl3.
By 1,4-bridging of p-tert-butylcalix [6] arene with 2,6-bis (bromomethyl)-4-methyl- anisole, a new type of bis-calix [5] arene analogue was obtained in high yield..
The synthesis and characterization of the first example of lower-rim-connected double-calix[6]arene are reported, in which a 1,2,4-triply bridged calix[6]arene subunit is connected to a calix[6]arene subunit via a pol...The synthesis and characterization of the first example of lower-rim-connected double-calix[6]arene are reported, in which a 1,2,4-triply bridged calix[6]arene subunit is connected to a calix[6]arene subunit via a polyether chain.展开更多
文摘A new approach to fullerene ferrocenyl derivative has been made. [60]Fullerene reacts with ferrocenylmethyl azide to give N-ferrocenylmethyl imino[60]fullerene in 42% yield.
基金Financial supports from the National Natural Science Foundation of China(No.20602015)are gratefully acknowledged.
文摘p-tert-Butylcalix[4]diazacrown-4 telomer, which contains hard and soft ion binding sites, was synthesized. It exhibited high selectivity toward cesium ions. The binding sites may complex alkali metal ions selectively.
基金he Natural Science Foundation of Hubei Province (No. 2000J026) for the financial support.
文摘Nano CaCO3 was used as a condensation agent in the ring-opening reaction of p-tert-butylcalix[4]arene with epichlorohydrin to afford 5,11,17,23-tetra-tert-butyl-26,27,28-trihyd- roxy-25-(1-chloro-2-hydroxy-3-propyl)calix[4]arene regioselectively in 52% yield. The yield was less than 2% by using normal CaCO3 instead of nano one under the same conditions.
文摘A bisphosphate-bridged tetrahomodioxacalix[6]arene with a C2v symmetry at the ambient temperature was obtained by the reaction of tetrahomodioxacalix[6]arene with POCl3.
基金Financial supports from the National Natural Science Foundation of China and Hubei province are gratefully acknowledged.
文摘By 1,4-bridging of p-tert-butylcalix [6] arene with 2,6-bis (bromomethyl)-4-methyl- anisole, a new type of bis-calix [5] arene analogue was obtained in high yield..
文摘The synthesis and characterization of the first example of lower-rim-connected double-calix[6]arene are reported, in which a 1,2,4-triply bridged calix[6]arene subunit is connected to a calix[6]arene subunit via a polyether chain.
