Recently,poly(ethylene oxide)(PEO)-based solid polymer electrolytes have been attracting great attention,and efforts are currently underway to develop PEO-based composite electrolytes for next generation high performa...Recently,poly(ethylene oxide)(PEO)-based solid polymer electrolytes have been attracting great attention,and efforts are currently underway to develop PEO-based composite electrolytes for next generation high performance all-solid-state lithium metal batteries.In this article,a novel sandwich structured solid-state PEO composite electrolyte is developed for high performance all-solid-state lithium metal batteries.The PEO-based composite electrolyte is fabricated by hot-pressing PEO,LiTFSI and Ti_(3)C_(2)T_(x) MXene nanosheets into glass fiber cloth(GFC).The as-prepared GFC@PEO-MXene electrolyte shows high mechanical properties,good electrochemical stability,and high lithium-ion migration number,which indicates an obvious synergistic effect from the microscale GFC and the nanoscale MXene.Such as,the GFC@PEO-1 wt%MXene electrolyte shows a high tensile strength of 43.43 MPa and an impressive Young's modulus of 496 MPa,which are increased by 1205%and 6048%over those of PEO.Meanwhile,the ionic conductivity of GFC@PEO-1 wt%MXene at 60℃ reaches 5.01×10^(-2) S m^(-1),which is increased by around 200%compared with that of GFC@PEO electrolyte.In addition,the Li/Li symmetric battery based on GFC@PEO-1 wt%MXene electrolyte shows an excellent cycling stability over 800 h(0.3 mA cm^(-2),0.3 mAh cm^(-2)),which is obviously longer than that based on PEO and GFC@PEO electrolytes due to the better compatibility of GFC@PEO-1 wt%MXene electrolyte with Li anode.Furthermore,the solid-state Li/LiFePO_(4) battery with GFC@PEO-1 wt%MXene as electrolyte demonstrates a high capacity of 110.2–166.1 mAh g^(-1) in a wide temperature range of 25–60C,and an excellent capacity retention rate.The developed sandwich structured GFC@PEO-1 wt%MXene electrolyte with the excellent overall performance is promising for next generation high performance all-solid-state lithium metal batteries.展开更多
Multifunctional and flexible wearable devices play a crucial role in a wide range of applications,such as heath monitoring,intelligent skins,and human-machine interactions.Developing flexible and conductive materials ...Multifunctional and flexible wearable devices play a crucial role in a wide range of applications,such as heath monitoring,intelligent skins,and human-machine interactions.Developing flexible and conductive materials for multifunctional wearable devices with low-cost and high efficiency methods are highly desirable.Here,a conductive graphene/microsphere/bamboo fiber(GMB)nanocomposite paper with hierarchical surface microstructures is successfully fabricated through a simple vacuum-assisted filtration followed by thermo-foaming process.The as-prepared microstructured GMB nanocomposite paper exhibits not only a high volume electrical conductivity of~45 S/m but also an excellent electrical stability(i.e.,relative changes in resistance are less than 3%under stretching,folding,and compressing loadings)due to its unique structure features.With this microstructured nanocomposite paper as active sensing layer,microstructured pressure sensors with a high sensitivity(-4 kPa^(-1)),a wide sensing range(0–5 kPa),and a rapid response time(about 140 ms)are realized.In addition,benefitting from the outstanding electrical stability and mechanical flexibility,the microstructured nanocomposite paper is further demonstrated as a low-voltage Joule heating device.The surface temperature of the microstructured nanocomposite paper rapidly reaches over 80℃ when applying a relatively low voltage of 7 V,indicating its potential in human thermotherapy and thermal management.展开更多
Thermal conductivity and thermal dissipation are of great importance for modern electronics due to the increased transistor density and operation frequency of contemporary integrated circuits.Due to its exceptionally ...Thermal conductivity and thermal dissipation are of great importance for modern electronics due to the increased transistor density and operation frequency of contemporary integrated circuits.Due to its exceptionally high thermal conductivity,graphene has drawn considerable interests worldwide for heat spreading and dissipation.However,maintaining high thermal conductivity in graphene laminates(the basic technological unit)is a significant technological challenge.Aiming at highly thermal conductive graphene films(GFs),this prospective review outlines the most recent progress in the production of GFs originated from graphene oxide due to its great convenience in film processing.Additionally,we also consider such issues as film assembly,defect repair and mechanical compression during the post-treatment.We also discuss the thermal conductivity in in-plane and through-plane direction and mechanical properties of GFs.Further,the current typical applications of GFs are presented in thermal management.Finally,perspectives are given for future work on GFs for thermal management.展开更多
Wearable devices that monitor the personalhealth,track the human motions,deliver drugs,and generate medical treatment are highly demand-ed in personalized healthcare.However,a desir-able feature missing in emerging we...Wearable devices that monitor the personalhealth,track the human motions,deliver drugs,and generate medical treatment are highly demand-ed in personalized healthcare.However,a desir-able feature missing in emerging wearable devices isthe ability to deliver advanced therapy at the展开更多
An intelligent wheelchair is devised, which is controlled by a coordinated mechanism based on a brain-computer interface(BCI) and speech recognition. By performing appropriate activities, users can navigate the wheelc...An intelligent wheelchair is devised, which is controlled by a coordinated mechanism based on a brain-computer interface(BCI) and speech recognition. By performing appropriate activities, users can navigate the wheelchair with four steering behaviors(start, stop, turn left, and turn right). Five healthy subjects participated in an indoor experiment. The results demonstrate the efficiency of the coordinated control mechanism with satisfactory path and time optimality ratios, and show that speech recognition is a fast and accurate supplement for BCI-based control systems. The proposed intelligent wheelchair is especially suitable for patients suffering from paralysis(especially those with aphasia) who can learn to pronounce only a single sound(e.g., ‘ah').展开更多
Central vein catheter (CVC) placement, which is widely utilized in clinical departments, is also highly important in preoperative preparations for radiofrequency catheter ablation (RFCA). The internal jugular vein...Central vein catheter (CVC) placement, which is widely utilized in clinical departments, is also highly important in preoperative preparations for radiofrequency catheter ablation (RFCA). The internal jugular vein or subclavian vein is the routine target. Arterial injury is not uncommon during the procedure but is potentially devastating in spite of the safety and advantages of the Seldinger technique. Compressing of the airway by a hematoma, as well as hemothorax, pseudoaneurysm, arteriovenous fistula, stroke, and even death, has been well-described.展开更多
Radiofrequency catheter ablation (RFCA),albeit an effective therapy for drug-refractory atrial fibrillation (AF),can be associated with complications in 3.9-22.0% of cases, of which cerebrovascular embolization,ca...Radiofrequency catheter ablation (RFCA),albeit an effective therapy for drug-refractory atrial fibrillation (AF),can be associated with complications in 3.9-22.0% of cases, of which cerebrovascular embolization,cardiac tamponade,and pulmonary vein stenosis are more common,and atrial hematoma is more rare.Here,we presented a case describing an elderly woman diagnosed with an intramural left atrial hematoma after AF ablation.展开更多
To the Editor: Moderator band (MB) is a part of the septomarginal trabeculation, which not only supports the anterior papillary muscle (APM) of the tricuspid valve but also connects it to the flee wall. Neverthel...To the Editor: Moderator band (MB) is a part of the septomarginal trabeculation, which not only supports the anterior papillary muscle (APM) of the tricuspid valve but also connects it to the flee wall. Nevertheless, with the advent of intracardiac echocardiography (ICE), electrophysiologists are now aware of the arrhythmogenic role of MB besides its mechanical function. MB-originated ventricular tachycardia or ventricular fibrillation (VT/VF) is a kind of idiopathic malignant arrhythmia in the absence of structural heart disease, which is frequently triggered by a premature ventricular contraction (PVC) from the same site.展开更多
基金support of the Fundamental Research Funds for the Central Universities(No.2022CDJQY-004)the Fund for Innovative Research Groups of Natural Science Foundation of Hebei Province(No.A2020202002).
文摘Recently,poly(ethylene oxide)(PEO)-based solid polymer electrolytes have been attracting great attention,and efforts are currently underway to develop PEO-based composite electrolytes for next generation high performance all-solid-state lithium metal batteries.In this article,a novel sandwich structured solid-state PEO composite electrolyte is developed for high performance all-solid-state lithium metal batteries.The PEO-based composite electrolyte is fabricated by hot-pressing PEO,LiTFSI and Ti_(3)C_(2)T_(x) MXene nanosheets into glass fiber cloth(GFC).The as-prepared GFC@PEO-MXene electrolyte shows high mechanical properties,good electrochemical stability,and high lithium-ion migration number,which indicates an obvious synergistic effect from the microscale GFC and the nanoscale MXene.Such as,the GFC@PEO-1 wt%MXene electrolyte shows a high tensile strength of 43.43 MPa and an impressive Young's modulus of 496 MPa,which are increased by 1205%and 6048%over those of PEO.Meanwhile,the ionic conductivity of GFC@PEO-1 wt%MXene at 60℃ reaches 5.01×10^(-2) S m^(-1),which is increased by around 200%compared with that of GFC@PEO electrolyte.In addition,the Li/Li symmetric battery based on GFC@PEO-1 wt%MXene electrolyte shows an excellent cycling stability over 800 h(0.3 mA cm^(-2),0.3 mAh cm^(-2)),which is obviously longer than that based on PEO and GFC@PEO electrolytes due to the better compatibility of GFC@PEO-1 wt%MXene electrolyte with Li anode.Furthermore,the solid-state Li/LiFePO_(4) battery with GFC@PEO-1 wt%MXene as electrolyte demonstrates a high capacity of 110.2–166.1 mAh g^(-1) in a wide temperature range of 25–60C,and an excellent capacity retention rate.The developed sandwich structured GFC@PEO-1 wt%MXene electrolyte with the excellent overall performance is promising for next generation high performance all-solid-state lithium metal batteries.
基金We gratefully acknowledge the National Natural Science Foundation of China(Nos.11872132,51803016 and U1837204)the China Postdoctoral Science Foundation(No.2020M673124)+1 种基金the Natural Science Foundation of Chongqing(No.cstc2020jcyj-bshX0001)the Competitive Internal Research Award of Khalifa University(CIRA-2018-16).
文摘Multifunctional and flexible wearable devices play a crucial role in a wide range of applications,such as heath monitoring,intelligent skins,and human-machine interactions.Developing flexible and conductive materials for multifunctional wearable devices with low-cost and high efficiency methods are highly desirable.Here,a conductive graphene/microsphere/bamboo fiber(GMB)nanocomposite paper with hierarchical surface microstructures is successfully fabricated through a simple vacuum-assisted filtration followed by thermo-foaming process.The as-prepared microstructured GMB nanocomposite paper exhibits not only a high volume electrical conductivity of~45 S/m but also an excellent electrical stability(i.e.,relative changes in resistance are less than 3%under stretching,folding,and compressing loadings)due to its unique structure features.With this microstructured nanocomposite paper as active sensing layer,microstructured pressure sensors with a high sensitivity(-4 kPa^(-1)),a wide sensing range(0–5 kPa),and a rapid response time(about 140 ms)are realized.In addition,benefitting from the outstanding electrical stability and mechanical flexibility,the microstructured nanocomposite paper is further demonstrated as a low-voltage Joule heating device.The surface temperature of the microstructured nanocomposite paper rapidly reaches over 80℃ when applying a relatively low voltage of 7 V,indicating its potential in human thermotherapy and thermal management.
基金National Natural Science Foundation of China(Nos.51803016,11872132,U1837204 and 11672049)the Start-up Funding of Chongqing University(Nos.0241001104454,0903005203352 and 0241001104417).
文摘Thermal conductivity and thermal dissipation are of great importance for modern electronics due to the increased transistor density and operation frequency of contemporary integrated circuits.Due to its exceptionally high thermal conductivity,graphene has drawn considerable interests worldwide for heat spreading and dissipation.However,maintaining high thermal conductivity in graphene laminates(the basic technological unit)is a significant technological challenge.Aiming at highly thermal conductive graphene films(GFs),this prospective review outlines the most recent progress in the production of GFs originated from graphene oxide due to its great convenience in film processing.Additionally,we also consider such issues as film assembly,defect repair and mechanical compression during the post-treatment.We also discuss the thermal conductivity in in-plane and through-plane direction and mechanical properties of GFs.Further,the current typical applications of GFs are presented in thermal management.Finally,perspectives are given for future work on GFs for thermal management.
文摘Wearable devices that monitor the personalhealth,track the human motions,deliver drugs,and generate medical treatment are highly demand-ed in personalized healthcare.However,a desir-able feature missing in emerging wearable devices isthe ability to deliver advanced therapy at the
基金Project supported by the National High-Tech R&D Program(863)of China(No.2012AA011601)the National Natural Science Foundation of China(No.91120305)+3 种基金the University High Level Talent Program of Guangdong,China(No.N9120140A)the Foundation and Theoretical Science Project supported by Jiangmen Research Program(No.2014(17)the Fundamental Research Funds for the Central Universities,South China University of Technology(No.2014ZB0031)the Science Foundation for Young Teachers of Wuyi University(No.2013zk08)
文摘An intelligent wheelchair is devised, which is controlled by a coordinated mechanism based on a brain-computer interface(BCI) and speech recognition. By performing appropriate activities, users can navigate the wheelchair with four steering behaviors(start, stop, turn left, and turn right). Five healthy subjects participated in an indoor experiment. The results demonstrate the efficiency of the coordinated control mechanism with satisfactory path and time optimality ratios, and show that speech recognition is a fast and accurate supplement for BCI-based control systems. The proposed intelligent wheelchair is especially suitable for patients suffering from paralysis(especially those with aphasia) who can learn to pronounce only a single sound(e.g., ‘ah').
文摘Central vein catheter (CVC) placement, which is widely utilized in clinical departments, is also highly important in preoperative preparations for radiofrequency catheter ablation (RFCA). The internal jugular vein or subclavian vein is the routine target. Arterial injury is not uncommon during the procedure but is potentially devastating in spite of the safety and advantages of the Seldinger technique. Compressing of the airway by a hematoma, as well as hemothorax, pseudoaneurysm, arteriovenous fistula, stroke, and even death, has been well-described.
文摘Radiofrequency catheter ablation (RFCA),albeit an effective therapy for drug-refractory atrial fibrillation (AF),can be associated with complications in 3.9-22.0% of cases, of which cerebrovascular embolization,cardiac tamponade,and pulmonary vein stenosis are more common,and atrial hematoma is more rare.Here,we presented a case describing an elderly woman diagnosed with an intramural left atrial hematoma after AF ablation.
文摘To the Editor: Moderator band (MB) is a part of the septomarginal trabeculation, which not only supports the anterior papillary muscle (APM) of the tricuspid valve but also connects it to the flee wall. Nevertheless, with the advent of intracardiac echocardiography (ICE), electrophysiologists are now aware of the arrhythmogenic role of MB besides its mechanical function. MB-originated ventricular tachycardia or ventricular fibrillation (VT/VF) is a kind of idiopathic malignant arrhythmia in the absence of structural heart disease, which is frequently triggered by a premature ventricular contraction (PVC) from the same site.