Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt(4,4′-(N-(4-butylphenyl))](TFB),one of the most popular and widely used hole-transport layer(HTL)materials,has been successfully applied in high performance spin-coated quantum...Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt(4,4′-(N-(4-butylphenyl))](TFB),one of the most popular and widely used hole-transport layer(HTL)materials,has been successfully applied in high performance spin-coated quantum dots-based light-emitting diodes(QLEDs)due to its suitable energy level and high mobility.However,there are still many challenging issues in inkjet-printed QLED devices when using TFB as HTL.TFB normally suffers from the interlayer mixing and erosion,and low surface energy against the good film formation.Here,a novel environment-friendly binary solvent system was established for formulating quantum dot(QD)inks,which is based on mixing halogen-free alkane solvents of decalin and n-tridecane.The optimum volume ratio for the mixture of decalin and n-tridecane was found to be 7:3,at which a stable ink jetting flow and coffee-ring free QD films could be formed.To research the influence of substrate surface on the formation of inkjet-printed QD films,TFB was annealed at different temperatures,and the optimum annealing temperature was found to enable high quality inkjet-printed QD film.Inkjet-printed red QLED was ultimately manufactured.A maximum 18.3%of external quantum efficiency(EQE)was achieved,reaching 93%of the spin-coated QLED,which is the best reported high efficiency inkjet-printed red QLEDs to date.In addition,the inkjet-printed QLED achieved similar T75 operational lifetime(27 h)as compared to the spin-coated reference QLED(28 h)at 2,000 cd·m−2.This work demonstrated that the novel orthogonal halogen-free alkane co-solvents can improve the interfacial contact and facilitate high-performance inkjet printing QLEDs with high EQE and stability.展开更多
An acceptor-donor-acceptor （A-D-A） three-dimensional （3D） small molecule acceptor （SFTTIC）, using spiro- bifluorene as the core unit linking with four thieno[3,2-b]thiophenes （TT） and end-capped with 2-（3-oxo...An acceptor-donor-acceptor （A-D-A） three-dimensional （3D） small molecule acceptor （SFTTIC）, using spiro- bifluorene as the core unit linking with four thieno[3,2-b]thiophenes （TT） and end-capped with 2-（3-oxo-2,3-dihy- dro-lH-inden-l-ylidene）malononitrile （INCN） was developed for solution processed organic solar cells. SFTTIC has a high absorption coefficient up to 3.12 × 105 mol-1,cm-1, good thermal stability and appropriate energy levels. The optimized power conversion efficiency （PCE） of 5.66% and 4.65% was achieved for the devices with PBDB-T：SFTTIC and PTB7-Th：SFTTIC, respectively.展开更多
基金financially supported by the National Key Research and Development Program of China (2022YFB3606500)the Natural Science Foundation of Jiangsu Province (BK20210125)。
基金This work was supported by the National Key Research and Development Program of China(No.2016YFB0401600)the National Natural Science Foundation of China(No.U1605244)China Postdoctoral Science Foundation(No.2020M681726).
文摘Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt(4,4′-(N-(4-butylphenyl))](TFB),one of the most popular and widely used hole-transport layer(HTL)materials,has been successfully applied in high performance spin-coated quantum dots-based light-emitting diodes(QLEDs)due to its suitable energy level and high mobility.However,there are still many challenging issues in inkjet-printed QLED devices when using TFB as HTL.TFB normally suffers from the interlayer mixing and erosion,and low surface energy against the good film formation.Here,a novel environment-friendly binary solvent system was established for formulating quantum dot(QD)inks,which is based on mixing halogen-free alkane solvents of decalin and n-tridecane.The optimum volume ratio for the mixture of decalin and n-tridecane was found to be 7:3,at which a stable ink jetting flow and coffee-ring free QD films could be formed.To research the influence of substrate surface on the formation of inkjet-printed QD films,TFB was annealed at different temperatures,and the optimum annealing temperature was found to enable high quality inkjet-printed QD film.Inkjet-printed red QLED was ultimately manufactured.A maximum 18.3%of external quantum efficiency(EQE)was achieved,reaching 93%of the spin-coated QLED,which is the best reported high efficiency inkjet-printed red QLEDs to date.In addition,the inkjet-printed QLED achieved similar T75 operational lifetime(27 h)as compared to the spin-coated reference QLED(28 h)at 2,000 cd·m−2.This work demonstrated that the novel orthogonal halogen-free alkane co-solvents can improve the interfacial contact and facilitate high-performance inkjet printing QLEDs with high EQE and stability.
文摘An acceptor-donor-acceptor （A-D-A） three-dimensional （3D） small molecule acceptor （SFTTIC）, using spiro- bifluorene as the core unit linking with four thieno[3,2-b]thiophenes （TT） and end-capped with 2-（3-oxo-2,3-dihy- dro-lH-inden-l-ylidene）malononitrile （INCN） was developed for solution processed organic solar cells. SFTTIC has a high absorption coefficient up to 3.12 × 105 mol-1,cm-1, good thermal stability and appropriate energy levels. The optimized power conversion efficiency （PCE） of 5.66% and 4.65% was achieved for the devices with PBDB-T：SFTTIC and PTB7-Th：SFTTIC, respectively.
基金supported by the Ministry of Science and Technology(2016YFA0200200)the National Natural Science Foundation of China(91633301 and 51773095)+1 种基金the Natural Science Foundation of Tianjin City(17JCJQJC44500 and 17CZDJC31100)111 Project(B12015)
