Zirconia has been extensively used in aerospace,military,biomedical and industrial fields due to its unusual combination of high mechanical,electrical and thermal properties.However,the fundamental and critical phase ...Zirconia has been extensively used in aerospace,military,biomedical and industrial fields due to its unusual combination of high mechanical,electrical and thermal properties.However,the fundamental and critical phase transition process of zirconia has not been well studied because of its difficult first-order phase transition with formidable energy barrier.Here,we generated a machine learning interatomic potential with ab initio accuracy to discover the mechanism behind all kinds of phase transition of zirconia at ambient pressure.The machine learning potential precisely characterized atomic interactions among all zirconia allotropes and liquid zirconia in a wide temperature range.We realized the challenging reversible first-order monoclinic-tetragonal and cubicliquid phase transition processes with enhanced sampling techniques.From the thermodynamic information,we gave a better understanding of the thermal hysteresis phenomenon in martensitic monoclinic-tetragonal transition.The phase diagram of zirconia from our machine learning potential based molecular dynamics simulations corresponded well with experimental results.展开更多
Effects of a starter culture composed of Lactobacillus sakei,Pediococcus pentosaceus,Staphylococcus xylosus and S.carnosus at the ratios(m/m)of 1:1:1:1 on bacterial profile and biogenic amine accumulation in Chinese S...Effects of a starter culture composed of Lactobacillus sakei,Pediococcus pentosaceus,Staphylococcus xylosus and S.carnosus at the ratios(m/m)of 1:1:1:1 on bacterial profile and biogenic amine accumulation in Chinese Sichuan sausages were demonstrated.In starter culture-inoculated sausages,Lactobacillus spp.,Pediococcus spp.and Staphylococcus spp.were predominant bacterial genus and their relative abundances ranged from 70.14%to 25.98%,57.66%to 14.08%,and 15.71%to 13.40%during fermentation,respectively.Accordingly,Lactobacillus spp.and Weissella spp.were predominant bacterial genus and their relative abundances ranged from 63.14%to 24.70%and 49.40%to 11.96%during spontaneous fermentation,respectively.Furthermore,the abundances of undesirable microorganisms such as Yersinia spp.,Enterobacter spp.,Acietobacter spp.and Psychrobacter spp.were lower than that of the control.The levels of histamine,putrescine,tyramine and cadaverine in Chinese Sichuan sausages with starter cultures inoculation were significantly lower(P<0.05)than that of the control,and were decreased by 83.09%,69.38%,51.87%and 57.20%,respectively,at the end of the ripening.These results revealed that the starter cultures inoculation was a better alternative for microbial quality improvement and biogenic amine reduction of Chinese Sichuan sausages with good sensory attributes.展开更多
Ultralight ceramic aerogels are attractive thermal superinsulating materials,but display a formidable tradeoff between low and high temperature thermal conductivity(κ)due to their low-density features.Embedding carbo...Ultralight ceramic aerogels are attractive thermal superinsulating materials,but display a formidable tradeoff between low and high temperature thermal conductivity(κ)due to their low-density features.Embedding carbon species as infrared opacifier in ultralight ceramic aerogels can substantially reduce the thermal radiation heat transfer without compromising the ultralow solid conduction.However,the oxidation resistance of embedded carbon species still remains inadequate to prevent thermal etching at high temperatures.Herein,we report a carbonaceous design and synthesis of ceramic nanofibrous aerogels with amorphous carbon embedded in the yttrium-stabilized zircon nanofibers to achieve a high-temperature thermal superinsulating performance with robust thermomechanical stability.The aerogels display one of the lowestκof 95 mW·m^(−1)·K^(-1)at 1,000℃in air among ultralight material family,as well as robust mechanical flexibility with up to 95%compressive strain,30%non-linear fracture strain,and 99%bending strain,and high thermal stability with ultralow strength degradation less than 1%after sharp thermal shocks(240℃·s^(-1))and working temperature up to 1,200℃.The combined high-temperature thermal superinsulating and thermomechanical properties offer an attractive material system for robust thermal insulation under extreme conditions.展开更多
基金the Creative Research Groups of National Natural Science Foundation of China(Grant No.51921006)National Natural Science Foundation of China(Grant No.52322803)。
文摘Zirconia has been extensively used in aerospace,military,biomedical and industrial fields due to its unusual combination of high mechanical,electrical and thermal properties.However,the fundamental and critical phase transition process of zirconia has not been well studied because of its difficult first-order phase transition with formidable energy barrier.Here,we generated a machine learning interatomic potential with ab initio accuracy to discover the mechanism behind all kinds of phase transition of zirconia at ambient pressure.The machine learning potential precisely characterized atomic interactions among all zirconia allotropes and liquid zirconia in a wide temperature range.We realized the challenging reversible first-order monoclinic-tetragonal and cubicliquid phase transition processes with enhanced sampling techniques.From the thermodynamic information,we gave a better understanding of the thermal hysteresis phenomenon in martensitic monoclinic-tetragonal transition.The phase diagram of zirconia from our machine learning potential based molecular dynamics simulations corresponded well with experimental results.
基金supported by National Natural Science Foundation of China(31772093)Key innovation projects of Chengdu Science and Technology(2019-YF05-00066-SN)Key Laboratory of Collaborative Control and Remediation of Soil and Water Pollution(GHBK-003)。
文摘Effects of a starter culture composed of Lactobacillus sakei,Pediococcus pentosaceus,Staphylococcus xylosus and S.carnosus at the ratios(m/m)of 1:1:1:1 on bacterial profile and biogenic amine accumulation in Chinese Sichuan sausages were demonstrated.In starter culture-inoculated sausages,Lactobacillus spp.,Pediococcus spp.and Staphylococcus spp.were predominant bacterial genus and their relative abundances ranged from 70.14%to 25.98%,57.66%to 14.08%,and 15.71%to 13.40%during fermentation,respectively.Accordingly,Lactobacillus spp.and Weissella spp.were predominant bacterial genus and their relative abundances ranged from 63.14%to 24.70%and 49.40%to 11.96%during spontaneous fermentation,respectively.Furthermore,the abundances of undesirable microorganisms such as Yersinia spp.,Enterobacter spp.,Acietobacter spp.and Psychrobacter spp.were lower than that of the control.The levels of histamine,putrescine,tyramine and cadaverine in Chinese Sichuan sausages with starter cultures inoculation were significantly lower(P<0.05)than that of the control,and were decreased by 83.09%,69.38%,51.87%and 57.20%,respectively,at the end of the ripening.These results revealed that the starter cultures inoculation was a better alternative for microbial quality improvement and biogenic amine reduction of Chinese Sichuan sausages with good sensory attributes.
基金the Creative Research Groups of the National Natural Science Foundation of China(No.51921006)the Heilongjiang Touyan Innovation Team Program of China.X.X.acknowledges funding from the National Natural Science Foundation of China(No.51878227).
文摘Ultralight ceramic aerogels are attractive thermal superinsulating materials,but display a formidable tradeoff between low and high temperature thermal conductivity(κ)due to their low-density features.Embedding carbon species as infrared opacifier in ultralight ceramic aerogels can substantially reduce the thermal radiation heat transfer without compromising the ultralow solid conduction.However,the oxidation resistance of embedded carbon species still remains inadequate to prevent thermal etching at high temperatures.Herein,we report a carbonaceous design and synthesis of ceramic nanofibrous aerogels with amorphous carbon embedded in the yttrium-stabilized zircon nanofibers to achieve a high-temperature thermal superinsulating performance with robust thermomechanical stability.The aerogels display one of the lowestκof 95 mW·m^(−1)·K^(-1)at 1,000℃in air among ultralight material family,as well as robust mechanical flexibility with up to 95%compressive strain,30%non-linear fracture strain,and 99%bending strain,and high thermal stability with ultralow strength degradation less than 1%after sharp thermal shocks(240℃·s^(-1))and working temperature up to 1,200℃.The combined high-temperature thermal superinsulating and thermomechanical properties offer an attractive material system for robust thermal insulation under extreme conditions.