Comprehensive Summary The EDA complex-mediated reactions involving oxime esters have been few studied.Herein,an EDA complex formed by thiophenolate anion and oxime ester is reported for photoinduced divergent synthesi...Comprehensive Summary The EDA complex-mediated reactions involving oxime esters have been few studied.Herein,an EDA complex formed by thiophenolate anion and oxime ester is reported for photoinduced divergent synthesis of thioethers,depending on different types of oxime esters.Operational simplicity,mild reaction conditions,and flexible options of leaving group demonstrate the generality and synthetic utility of this approach.Such an approach can also enable an interesting thiol-catalysis for the synthesis of phenanthridines.展开更多
基金support from the National Natural Science Foundation of China(22171177)the Guangdong-Hong Kong Joint Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province(2023B1212120011)+3 种基金the Guangdong Basic and Applied Basic Research Foundation(2023A1515110791)the Chemistry and Chemical Engineering Guangdong Laboratory(2312002)the Guangdong Major Project of Basic and Applied Basic Research(2019B030302009)the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme 2019(GDUPS2019).
文摘Comprehensive Summary The EDA complex-mediated reactions involving oxime esters have been few studied.Herein,an EDA complex formed by thiophenolate anion and oxime ester is reported for photoinduced divergent synthesis of thioethers,depending on different types of oxime esters.Operational simplicity,mild reaction conditions,and flexible options of leaving group demonstrate the generality and synthetic utility of this approach.Such an approach can also enable an interesting thiol-catalysis for the synthesis of phenanthridines.
