Degradation research of protective coating on AZ91D Mg alloy components via simulated contamination

Accelerated environmental(hygrothermal)exposure experiments are performed on organic paints coated on commercial die-cast AZ91D Mg alloys to investigate the effects of contamination on blistering.Specifically,artificial human perspiration spray is used to contaminate the substrate surface.Blistering occurred only for paints that are spread on surfaces with the perspiration present.More blisters gradually form at longer test times,and the volume of blistering increases.Scanning electron microscopy indicates that blistering is initiated by contamination and/or substrate corrosion at the interface of the organic paints and the substrate.Blistering is characterized for two samples exposed to the hygrothermal environments for various times,and is found to be initially empty in the early stages.Hydrophilic chloride contaminants from the perspiration lead to in situ adhesion loss.Simultaneously,the paints volume expands,and the associated compressive stress causes it to bulge.After long-term test exposure,chloride anions corrode the substrate under the films,and MgO,Mg(OH)_(2),and Mg_(2)(OH)_(3)Cl corrosion products fill the blisters.Finally,a model of blistering evolution is discussed.

Giant magneto-impedance effect of two paralleled amorphous microwires

Giant magneto-impedance （GMI） is effectively enhanced by the mutual magnetic interaction between two amorphous microwires. A comparative study on GMI properties of a single wire and two wires arranged in par- allel mode was reported in this work. Two-peak （TP） of impedance characteristic is presented when the dc external field changed from 0 to 320 A,m-＇ in two-wire system, which is attributed to successive magnetization process in two wires induced by their magnetic interaction. And the evolution of single peak to TP phenomenon, when the distance between two wires is upto 8 ram, evidences a distance dependence of transformation from successive magnetization to simultaneous via a corresponding dis- tance dependence of magnetostatic interactions. It is pro- posed that the recombination of magnetic interaction and the shielding effect results in a distance dependency of GMI response. When the distance is 8 ram, the magneti- zation process is close to synchronous between two wires, which give rises to higher circular permeability and better GMI response. The impedance ratio AZ/Z increases from 74.5 % of single wire to 172.4 % at 10 MHz. However, when the distance is upto 12 mm, the magnetic interaction is weak and magnetization process is completely independent, and GMI response decreases, relatively. This indicates that the GMI response could be effectively improved in a two-wire connection with an optical distance, which is promising and useful for the application of high-performance GMI sensors.