Revisiting the Concentration Observations and Source Apportionment of Atmospheric Ammonia

While China’s Air Pollution Prevention and Control Action Plan on particulate matter since 2013 has reduced sulfate significantly,aerosol ammonium nitrate remains high in East China.As the high nitrate abundances are strongly linked with ammonia,reducing ammonia emissions is becoming increasingly important to improve the air quality of China.Although satellite data provide evidence of substantial increases in atmospheric ammonia concentrations over major agricultural regions,long-term surface observation of ammonia concentrations are sparse.In addition,there is still no consensus on whether agricultural or non-agricultural emissions dominate the urban ammonia budget.Identifying the ammonia source by nitrogen isotope helps in designing a mitigation strategy for policymakers,but existing methods have not been well validated.Revisiting the concentration measurements and identifying source apportionment of atmospheric ammonia is thus an essential step towards reducing ammonia emissions.

Changes in air pollutants during the COVID-19 lockdown in Beijing:Insights from a machine-learning technique and implications for future control policy

The COVID-19 lockdowns led to abrupt reductions in human-related emissions worldwide and had an unintended impact on air quality improvement.However,quantifying this impact is difficult as meteorological conditions may mask the real effect of changes in emissions on the observed concentrations of pollutants.Based on the air quality and meteorological data at 35 sites in Beijing from 2015 to 2020,a machine learning technique was applied to decouple the impacts of meteorology and emissions on the concentrations of air pollutants.The results showed that the real(“deweathered”)concentrations of air pollutants(expect for O 3)dropped significantly due to lockdown measures.Compared with the scenario without lockdowns(predicted concentrations),the observed values of PM_(2.5),PM_(10),SO_(2),NO_(2),and CO during lockdowns decreased by 39.4%,50.1%,51.8%,43.1%,and 35.1%,respectively.In addition,a significant decline for NO_(2)and CO was found at the background sites(51%and 37.8%)rather than the traffic sites(37.1%and 35.5%),which is different from the common belief.While the primary emissions reduced during the lockdown period,episodic haze events still occurred due to unfavorable meteorological conditions.Thus,developing an optimized strategy to tackle air pollution in Beijing is essential in the future.