The interaction between support and noble metal plays a crucial role in heterogeneous catalysis design.However,how to tune metal support interactions to optimize the activity still needs further exploration.CeO_(2) wa...The interaction between support and noble metal plays a crucial role in heterogeneous catalysis design.However,how to tune metal support interactions to optimize the activity still needs further exploration.CeO_(2) was introduced to promote CO oxidation ove r Ir/TiO_(2) by adjusting the interaction strength between iridium(Ir)and CeO_(2).The strong interaction between Ir and CeO_(2) blocks CO adsorption and causes low CO oxidation activity.However,introducing CeO_(2) on Ir/TiO_(2) produces localized interaction between Ir and CeO_(2),which can tune the surface electronic state of Ir,so a"volcano curve"relationship between CO oxidation activity and electronic state is built.Limited amount of CeO_(2) on Ir/TiO_(2)(Ir/Ce_(0.2)Ti)leads to CO complete oxidization at 22℃,and a new pathway for CO oxidation was explored.The study demonstrates that the utilization of tuning interaction strength between active metal and support is a potential method to increase the catalytic activity.展开更多
基金Project supported by the Science Foundation of China Tobacco Zhejiang Industrial Co.LTD(ZJZY2021A013,ZJZY2023C001)the National Natural Science Foundation of China(21976057)。
文摘The interaction between support and noble metal plays a crucial role in heterogeneous catalysis design.However,how to tune metal support interactions to optimize the activity still needs further exploration.CeO_(2) was introduced to promote CO oxidation ove r Ir/TiO_(2) by adjusting the interaction strength between iridium(Ir)and CeO_(2).The strong interaction between Ir and CeO_(2) blocks CO adsorption and causes low CO oxidation activity.However,introducing CeO_(2) on Ir/TiO_(2) produces localized interaction between Ir and CeO_(2),which can tune the surface electronic state of Ir,so a"volcano curve"relationship between CO oxidation activity and electronic state is built.Limited amount of CeO_(2) on Ir/TiO_(2)(Ir/Ce_(0.2)Ti)leads to CO complete oxidization at 22℃,and a new pathway for CO oxidation was explored.The study demonstrates that the utilization of tuning interaction strength between active metal and support is a potential method to increase the catalytic activity.
