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郯庐断裂带流体中氦的来源、空间分布及地质意义
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作者 管芦峰 刘伟 +4 位作者 曹春辉 张茂亮 徐胜 郑国东 yuji sano 《地球化学》 CAS CSCD 北大核心 2023年第5期570-581,共12页
郯庐断裂带是中国东部规模最大、构造运动强烈以及地震频发的活动断裂带,其深部结构与现今活动状态引人注目。对郯庐断裂带郯城段和庐江段温泉与深井地下水逸出和溶解气体进行He同位素组成和气体组分分析结果显示,郯庐断裂带流体 ^(3)He... 郯庐断裂带是中国东部规模最大、构造运动强烈以及地震频发的活动断裂带,其深部结构与现今活动状态引人注目。对郯庐断裂带郯城段和庐江段温泉与深井地下水逸出和溶解气体进行He同位素组成和气体组分分析结果显示,郯庐断裂带流体 ^(3)He/^(4)He测试值为大气参考值(记作1 Ra)的0.15~1.15倍。郯城段样品的 ^(3)He/^(4)He和4He/20Ne值分别为0.96~1.15 Ra和0.24~0.30,显示有大气和地下水氚衰变对He来源的贡献。庐江段样品的 ^(3)He/^(4)He空气校正值和4He/20Ne值分别为0.15~0.79 Ra和0.28~272,扣除大气贡献后He主要来源于地壳放射性元素衰变(90.4%~98.4%),局部受到地幔脱气作用的显著影响(幔源He占比最高为9.6%)。在空间上,庐江段幔源He占比呈现出随采样点远离断裂带而逐渐减小的趋势,反映了幔源流体运移过程中经历的稀释效应。幔源He空间分布与地震P波速度图像对比结果表明,庐江段深源流体可能受到地幔部分熔融作用的影响。全球典型走滑断裂带的流体 ^(3)He/^(4)He值和走滑速率之间呈正相关关系(R^(2)=0.8),表明断裂带活动性及其应力状态对幔源流体释放具有一定的控制作用。 展开更多
关键词 深部流体 HE同位素 气体地球化学 郯庐断裂带
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Development and Application of Laser Peening in Japan
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作者 yuji sano 《航空制造技术》 2006年第1期73-77,共5页
This paper reviews the current status of research and development on laser peening without protective coating(LPPC) in Japan. LPPC is an innovative process since it does not require any surface coating that is formed ... This paper reviews the current status of research and development on laser peening without protective coating(LPPC) in Japan. LPPC is an innovative process since it does not require any surface coating that is formed prior to laser irradiation in conventional laser peening for preventing the surface from melting. Surface residual stress of various metal materials was converted from tensile to compressive by LPPC. High cycle fatigue property was remarkably improved for steels, aluminum alloys and titanium alloys. Accelerating stress corrosion cracking (SCC) tests showed that LPPC completely prevents SCC of sensitized austenitic stainless steels, nickel-based alloys and their weld metals. LPPC has been utilized to combat against SCC in Japanese nuclear power reactors since 1999. 展开更多
关键词 激光敲击 应力疲劳 腐蚀裂化 金属处理 结构力学
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沁水盆地煤层气井排采水地球化学特征及来源示踪
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作者 方鲁加 陈碧莹 +2 位作者 能惠 sano yuji 徐胜 《天然气地球科学》 CAS 2024年第11期1935-1949,共15页
次生生物气与地下水之间存在一定的关系,特别是在煤层气等天然气储层中,了解地下水与次生生物成因甲烷之间的关系对于天然气勘探和开发具有重要意义。基于中国沁水盆地6个区块的57个煤层气井排采水和3个河水样品的化学组成、氢氧同位素... 次生生物气与地下水之间存在一定的关系,特别是在煤层气等天然气储层中,了解地下水与次生生物成因甲烷之间的关系对于天然气勘探和开发具有重要意义。基于中国沁水盆地6个区块的57个煤层气井排采水和3个河水样品的化学组成、氢氧同位素组成(δ18O_(H_(2)O))和δD_(H_(2)O)以及溶解无机碳(DIC)碳同位素组成(δ13C_(DIC)和Δ14C_(DIC)),深入剖析地下水与次生生物成因甲烷之间的复杂关系。结果表明:氢氧同位素分布在大气降水线附近,煤层气井排采水主要来源于大气降雨,硫酸盐微生物还原作用是郑庄和阳泉区块氘同位素富集的主要原因。研究区煤层气井排采水化学组成以Na⁃HCO_(3)型为主,其变化受到水—岩相互作用、阳离子交换等过程的控制。沁水盆地6个研究区块煤层气井排采水的稳定碳同位素呈现高δ13C_(DIC)值(-4.19‰~34.80‰,平均为16.51‰)且与溶解无机碳含量呈明显正相关关系可能是微生物产甲烷作用的结果。煤层气井排采水中δ13C_(DIC)与SO_(4)^(2-)的负相关性以及δ正漂移等指标也指向沁水盆地不同成熟度煤岩中次生生物成因甲烷的广泛存在。δ13C_(DIC)与镜质体反射率(R_(Omax))的负相关性进一步表明沁水盆地不同成熟度煤层中广泛存在次生生物成因甲烷,且在浅埋藏和成熟度较低的煤层中最为显著。地球化学与微生物学的结合将会进一步阐明次生生物甲烷的形成途径和机制。 展开更多
关键词 煤层气井排采水 水化学特征 碳同位素 次生生物甲烷 沁水盆地
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青藏高原东缘鲜水河-安宁河断裂带深源气体释放 被引量:9
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作者 徐胜 管芦峰 +6 位作者 张茂亮 钟君 刘伟 谢显刚 刘丛强 Naoto TAKAHATA yuji sano 《中国科学:地球科学》 CSCD 北大核心 2022年第2期291-308,共18页
青藏高原东南缘分布的大规模超壳走滑断裂带和中-高温地热区释放大量深源气体.鲜水河-安宁河断裂带温泉水和逸出气体的化学和同位素组成分析结果显示,该断裂带的水-岩相互作用显著,深源含碳流体强烈释放,是研究大陆碰撞造山带巨型走滑... 青藏高原东南缘分布的大规模超壳走滑断裂带和中-高温地热区释放大量深源气体.鲜水河-安宁河断裂带温泉水和逸出气体的化学和同位素组成分析结果显示,该断裂带的水-岩相互作用显著,深源含碳流体强烈释放,是研究大陆碰撞造山带巨型走滑断裂系统深源CO_(2)释放的重要地区.δ^(18)O_(H_(2)O)和δD_(H_(2)O)值显示温泉水主要来源于不同补给高度的大气降水循环;水-岩相互作用过程中,区域蒸发盐、碳酸盐和钠硅酸盐矿物的溶解作用导致温泉水显著富集Na^(+)和HCO_(3).温泉逸出气体^(3)He/^(4)He比值为大气的0.025~2.73倍,局部地区显示强烈的幔源He释放:^(3)He/^(4)He比值在断裂密集分布的康定地区最高,并以此为中心向断裂带延伸和垂直方向递减.溶解无机碳(Dissolved inorganic carbon,DIC)浓度变化范围为2~42mmol L^(-1),δ^(13)CDIC值为-4.0∼1.3‰,13C CO_(2)值为-7.2∼-3.6‰,Δ14CDIC值为-997∼-909‰.结合地球化学与区域地质资料,认为CO_(2)来源主要包括深部的上地幔和变质碳酸盐岩,以及近地表的海相碳酸盐岩和有机质.质量平衡混合模型计算结果显示,平均11±6%的溶解碳来源于浅层碳酸盐矿物的溶解作用,9±8%为沉积有机质热解成因,80±9%来自深部变质成因和幔源CO_(2).其中,安宁河断裂带深源CO_(2)主要为单一的变质成因碳;而在鲜水河断裂带深源CO_(2)中,约12%和88%分别源自地幔和变质成因碳.康定地热田平均深源CO_(2)通量为160t a^(-1),如果推算至青藏高原东南缘各类断裂带内的所有温泉,区域深源CO_(2)通量将达到10^(5)t a^(-1)量级.这一初步结果表明,非火山区深源CO_(2)释放量在全球范围深源碳释放总量中占有相当的份额,需要引起重视和深入研究. 展开更多
关键词 温泉 流体地球化学 深源碳释放 鲜水河-安宁河断裂带 青藏高原
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Degassing of deep-sourced CO_(2) from Xianshuihe-Anninghe fault zones in the eastern Tibetan Plateau 被引量:12
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作者 Sheng XU Lufeng GUAN +6 位作者 Maoliang ZHANG Jun ZHONG Wei LIU Xian'gang XIE Congqiang LIU Naoto TAKAHATA yuji sano 《Science China Earth Sciences》 SCIE EI CSCD 2022年第1期139-155,共17页
A large number of gases are releasing from the medium-high temperature geothermal fields distributed along the large-scale strike-slip fault zones in the southeastern margin of the Tibetan Plateau.In this study,11 hot... A large number of gases are releasing from the medium-high temperature geothermal fields distributed along the large-scale strike-slip fault zones in the southeastern margin of the Tibetan Plateau.In this study,11 hot spring water and the associated bubbling gas samples were collected along the Xianshuihe-Anninghe fault zones(XSH-ANHFZ)and analyzed for chemical and isotopic compositions.The δ^(18)_(H_(2)O) and δD_(H_(2)O) values indicate that hot spring waters are predominantly meteoric origin recharged from different altitudes.Most water samples are significantly enriched in Na^(+) and HCO_(3) due to the dissolution of regional evaporites,carbonates and Na-silicates.^(3)He/^(4)He ratios of the gas samples are 0.025-2.73 times the atmospheric value.The ^(3)He/^(4)He ratios are high in the Kangding region where the dense faults are distributed,and gradually decrease with increasing distance from Kangding towards both sides along the Xianshuihe fault zones(XSHFZ).Hydrothermal fluids have dissolved inorganic carbon(DIC)concentrations from 2 to 42 mmol L^(-1),δ^(13)C_(DIC) from -6.9‰ to 1.3‰,δ^(13)C_(CO_(2)) from -7.2‰ to -3.6‰ and Δ^(14)C from -997‰ to -909‰.Combining regional geochemical and geological information,the CO_(2)sources can be attributed to deep-sourced CO_(2)from mantle and metamorphism of marine carbonate,and shallow-sourced CO_(2)from the dissolution of marine carbonate and biogenic CO_(2).The mass balance model shows that 11±6% of the DIC is sourced from the dissolution of shallow carbonate minerals,9±8% formed by pyrolysis of sedimentary organic matter,80±9% derived from deep metamorphic origin and mantle-derived CO_(2).Among them,the deep-sourced CO_(2)in Anninghe fault zones(ANHFZ)is merely metamorphic carbon,whereas ca.12% and ca.88% of the deep-sourced CO_(2)in the XSHFZ are derived from the mantle and metamorphic carbon,respectively.The average deep-sourced CO_(2)flux in the Kangding geothermal field is estimated to be 160 ta^(-1).If all the hot springs in various fault zones in the southeastern margin of the Tibetan Plateau are taken into account,the regional deep-sourced CO_(2)flux would reach ca.10^(5) ta^(-1).These results show that the deep-sourced CO_(2)released from nonvolcanic areas might account for a considerable proportion of the total amount of global deep-sourced carbon degassing,which should be paid more attention to. 展开更多
关键词 Hot spring Fluid geochemistry Deep-sourced carbon Xianshuihe-Anninghe fault zones Tibetan Plateau
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Crustal Signature of δ^(13)C and Nitrogen Content in Microdiamonds from Erzgebirge, Germany: Ion Microprobe Studies 被引量:2
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作者 Larissa F Dobrzhinetskaya Harry W Green II +2 位作者 Naoto Takahata yuji sano Korato Shirai 《Journal of Earth Science》 SCIE CAS CSCD 2010年第5期623-634,共12页
The study of δ13CCpDB (Pee Dee Belemnite) and nitrogen contents in 1 to 5-pm-diameter microdinmonds included in garnets from the qnartz-feldspathic gneisses (Erzgehirge, Germany) was performed in situ with the Na... The study of δ13CCpDB (Pee Dee Belemnite) and nitrogen contents in 1 to 5-pm-diameter microdinmonds included in garnets from the qnartz-feldspathic gneisses (Erzgehirge, Germany) was performed in situ with the Nano-scale Secondary Ion Mass Spectrometer. The results revealed that there were two stages of diamond crystallization from a C-O-H supeeritical fluid rich in biogenic carbon and diverse minor elements of crustal origin. The δ13CCpDB Of the Erzgebirge diamond of the first stage falls in the range -17‰ to 19‰, with an average value of -17.8‰; the average content of nitrogen is 820 ppm. Diamonds of the second stage are characterized by δ13CPDB=-21.5‰ to -25.5‰, with an average value of -23.24‰; the average nitrogen content is non-homogeneously scattered from 740 ppm to 3 370 ppm among 6 diamonds situated in garnets within the same polished rock slide. Both diamond of the first stage and diamond of the second stage carbon reservoirs belong to biogenic matter, therefore confirming deep subduction of the continental crust sediments and their subsequent exhumation during the Variscan orogeny. 展开更多
关键词 metamorphic diamond carbon isotope nitrogen content geochemistry.
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