The quality of MAPbI3 film prepared by solvent engineering process highly depends on environment and antisolvent control.Here,we provided a simple methylamine chloride(MACl)solution treatment using a two-step process ...The quality of MAPbI3 film prepared by solvent engineering process highly depends on environment and antisolvent control.Here,we provided a simple methylamine chloride(MACl)solution treatment using a two-step process to enlarge the perovskite crystal grain sizes to more than 1 lm.Other than treatment on the film surface,the MACl solution diffuses into the MAPbI_(3) films to assist the recrystallization of small crystal at the bottom of perovskite film.The imitative contact between perovskite and substrate is formed.Meanwhile,the enlargement of grain size and ten times enhancement of crystalline reduce trap-assisted recombination of perovskite films.Thus,the significant improvement of cell efficiency of 20.89%as well as device stability is obtained with the MACl treatment.展开更多
基金financially supported by the National Key R&D Program of China (Grant No. 2020YFB1506404)the 111 Project (Grant No. B16016)+1 种基金the National Natural Science Foundation of China (Grant Nos. 51961165106, 51572080 and 61904053)the Fundamental Research Funds for the Central Universities (Grant Nos. 2019MS026, 2019MS027 and 2020MS080)。
文摘The quality of MAPbI3 film prepared by solvent engineering process highly depends on environment and antisolvent control.Here,we provided a simple methylamine chloride(MACl)solution treatment using a two-step process to enlarge the perovskite crystal grain sizes to more than 1 lm.Other than treatment on the film surface,the MACl solution diffuses into the MAPbI_(3) films to assist the recrystallization of small crystal at the bottom of perovskite film.The imitative contact between perovskite and substrate is formed.Meanwhile,the enlargement of grain size and ten times enhancement of crystalline reduce trap-assisted recombination of perovskite films.Thus,the significant improvement of cell efficiency of 20.89%as well as device stability is obtained with the MACl treatment.
