Recently discovered kagome metals AV_(3)Sb_(5)(A=K,Rb,and Cs)provide an ideal platform to study the correlation among nontrivial band topology,unconventional charge density wave(CDW),and superconductivity.The evolutio...Recently discovered kagome metals AV_(3)Sb_(5)(A=K,Rb,and Cs)provide an ideal platform to study the correlation among nontrivial band topology,unconventional charge density wave(CDW),and superconductivity.The evolution of electronic structures associated with the change of lattice modulations is crucial for understanding of the CDW mechanism,with the combination of angle-resolved photoemission spectroscopy(ARPES)measurements and density functional theory calculations,we investigate how band dispersions change with the increase of lattice distortions.In particular,we focus on the electronic states around M point,where the van Hove singularities are expected to play crucial roles in the CDW transition.Previous ARPES studies reported a spectral weight splitting of the van Hove singularity around M point,which is associated with the 3D lattice modulations.Our studies reveal that this“splitting”can be connected to the two van Hove singularities at k_(z)=0 and k_(z)=π/c in the normal states.When the electronic system enters into the CDW state,both van Hove singularities move down.Such novel properties are important for understanding of the CDW transition.展开更多
Using angle-resolved photoemission spectroscopy,we study electronic structures of a Kagome metal YCr6Ge6.Band dispersions along kz direction are significant,suggesting a remarkable interlayer coupling between neighbor...Using angle-resolved photoemission spectroscopy,we study electronic structures of a Kagome metal YCr6Ge6.Band dispersions along kz direction are significant,suggesting a remarkable interlayer coupling between neighboring Kagome planes.Comparing ARPES data with first-principles calculations,we find a moderate electron correlation in this material,since band calculations must be compressed in the energy scale to reach an excellent agreement between experimental data and theoretical calculations.Moreover,as indicated by band calculations,there is a flat band in the vicinity of the Fermi level at the Г–M–K plane in the momentum space,which could be responsible for the unusual transport behavior in YCr6Ge6.展开更多
Tuning the bandgap in layered transition metal dichalcogenides(TMDCs) is crucial for their versatile applications in many fields. The ternary formation is a viable method to tune the bandgap as well as other intrinsic...Tuning the bandgap in layered transition metal dichalcogenides(TMDCs) is crucial for their versatile applications in many fields. The ternary formation is a viable method to tune the bandgap as well as other intrinsic properties of TMDCs, because the multi-elemental characteristics provide additional tunability at the atomic level and advantageously alter the physical properties of TMDCs. Herein, ternary Ti_(x)Zr_(1-x)Se_(2) single crystals were synthesized using the chemical-vapor-transport method. The changes in electronic structures of ZrSe_(2) induced by Ti substitution were revealed using angle-resolved photoemission spectroscopy. Our data show that at a low level of Ti substitution, the bandgap of Ti_(x)Zr_(1-x)Se_(2) decreases monotonically, and the electronic system undergoes a transition from a semiconducting to a metallic state without a significant variation of dispersions of valence bands. Meanwhile, the size of spin-orbit splitting dominated by Se 4p orbitals decreases with the increase of Ti doping. Our work shows a convenient way to alter the bandgap and spin-orbit coupling in TMDCs at the low level of substitution of transition metals.展开更多
Charge density wave(CDW)is a phenomenon that occurs in materials,accompanied by changes in their intrinsic electronic properties.The study of CDW and its modulation in materials holds tremendous significance in materi...Charge density wave(CDW)is a phenomenon that occurs in materials,accompanied by changes in their intrinsic electronic properties.The study of CDW and its modulation in materials holds tremendous significance in materials research,as it provides a unique approach to controlling the electronic properties of materials.TiSe_(2) is a typical layered material with a CDW phase at low temperatures.Through V substitution for Ti in TiSe_(2),we tuned the carrier concentration in V_(x)Ti_(1-x)Se_(2) to study how its electronic structures evolve.Angle-resolved photoemission spectroscopy(ARPES)shows that the band-folding effect is sustained with the doping level up to 10%,indicating the persistence of the CDW phase,even though the band structure is strikingly different from that of the parent compound TiSe_(2).Though CDW can induce the band fold effect with a driving force from the perspective of electronic systems,our studies suggest that this behavior could be maintained by lattice distortion of the CDW phase,even if band structures deviate from the electron-driven CDW scenario.Our work provides a constraint for understanding the CDW mechanism in TiSe_(2),and highlights the role of lattice distortion in the band-folding effect.展开更多
The intercalation of metal is a promising method for the modulating electronic properties in transition metal dichalcogenides(TMDs).However,there still lacks enough knowledge about how the intercalated atoms directly ...The intercalation of metal is a promising method for the modulating electronic properties in transition metal dichalcogenides(TMDs).However,there still lacks enough knowledge about how the intercalated atoms directly impact the two-dimensional structural layers and modulate the band structures therein.Taking advantage of X-ray absorption fine structure and angle-resolved photoemission spectroscopy,we studied how Cu intercalation influences the host TaSe2 layers in Cu0.03TaSe2 crystals.The intercalated Cu atoms form bonds with Se of the host layers,and there is charge transfer from Cu to Se.By examining the changes of band dispersions,we show that the variation of electronic structures is beyond a simple rigid band model with merely charge doping effect.This work'reveals that the unusual change of band dispersions is associated with the formation of bonds between the intercalated metal elements and anion ions in the host layers,and provides a reference for the comprehensive understanding of the electronic structures in intercalated materials.展开更多
The two-dimensional(2 D)structure often leads to unusual phenomena for the impact of confined mean free path of carrier scattering.As a quasi-2 D layered material,Ag CrSe_(2)has a liquid-like phonon behavior for its u...The two-dimensional(2 D)structure often leads to unusual phenomena for the impact of confined mean free path of carrier scattering.As a quasi-2 D layered material,Ag CrSe_(2)has a liquid-like phonon behavior for its unstable Ag atoms at service temperature,leading to the promising candidate for thermoelectricity and fast ionic conductor.However,the inferior electronic performance constrains its application prospects as a functional semiconductor,which provides broad opportunity to tune its electric behaviors by defect chemistry.In this work,we revealed abundant electric transport behaviors of Ag CrSe_(2)with different types of intrinsic defects.For example,the Ag CrSe_(2)changes from Anderson insulator to metal when Se defects become prevailing and the magnetoresistance alters its sign depending on the relative ratio of Ag and Cr defects.Our results reported here can give salutary boosting on regulating the electric properties of ternary transition metal selenide by defect chemistry.展开更多
基金supported by the National Key R&D Program of China (Grant No.2017YFA0402901)the National Natural Science Foundation of China (Grant No.U2032153)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No.XDB25000000)the Users with Excellence Program of Hefei Science Center of the Chinese Academy of Sciences (Grant No.2021HSC-UE004)。
文摘Recently discovered kagome metals AV_(3)Sb_(5)(A=K,Rb,and Cs)provide an ideal platform to study the correlation among nontrivial band topology,unconventional charge density wave(CDW),and superconductivity.The evolution of electronic structures associated with the change of lattice modulations is crucial for understanding of the CDW mechanism,with the combination of angle-resolved photoemission spectroscopy(ARPES)measurements and density functional theory calculations,we investigate how band dispersions change with the increase of lattice distortions.In particular,we focus on the electronic states around M point,where the van Hove singularities are expected to play crucial roles in the CDW transition.Previous ARPES studies reported a spectral weight splitting of the van Hove singularity around M point,which is associated with the 3D lattice modulations.Our studies reveal that this“splitting”can be connected to the two van Hove singularities at k_(z)=0 and k_(z)=π/c in the normal states.When the electronic system enters into the CDW state,both van Hove singularities move down.Such novel properties are important for understanding of the CDW transition.
基金Supported by the National Key R&D Program of China(Grant Nos.2017YFA0402901,2016YFA0401004 and 2016YFA0300404)the National Natural Science Foundation of China(Grant Nos.11674296,11974354 and U1432138)+3 种基金the Key Research Program of the Chinese Academy of Sciences(Grant No.XDPB01)the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(Grant No.2018CXFX002)the Collaborative Innovation Program of Hefei Science Center,CAS(Grant No.2019HSC-CIP007)the High Magnetic Field Laboratory of Anhui Province.
文摘Using angle-resolved photoemission spectroscopy,we study electronic structures of a Kagome metal YCr6Ge6.Band dispersions along kz direction are significant,suggesting a remarkable interlayer coupling between neighboring Kagome planes.Comparing ARPES data with first-principles calculations,we find a moderate electron correlation in this material,since band calculations must be compressed in the energy scale to reach an excellent agreement between experimental data and theoretical calculations.Moreover,as indicated by band calculations,there is a flat band in the vicinity of the Fermi level at the Г–M–K plane in the momentum space,which could be responsible for the unusual transport behavior in YCr6Ge6.
基金supported by the National Key R&D Program of China (Grant No. 2017YFA0402901)the National Natural Science Foundation of China (Grant No. U2032153)+2 种基金the International Partnership Program (Grant No. 211134KYSB20190063)the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB25000000)the USTC Research Funds of the Double First-Class Initiative (Grant No. YD2310002004)。
文摘Tuning the bandgap in layered transition metal dichalcogenides(TMDCs) is crucial for their versatile applications in many fields. The ternary formation is a viable method to tune the bandgap as well as other intrinsic properties of TMDCs, because the multi-elemental characteristics provide additional tunability at the atomic level and advantageously alter the physical properties of TMDCs. Herein, ternary Ti_(x)Zr_(1-x)Se_(2) single crystals were synthesized using the chemical-vapor-transport method. The changes in electronic structures of ZrSe_(2) induced by Ti substitution were revealed using angle-resolved photoemission spectroscopy. Our data show that at a low level of Ti substitution, the bandgap of Ti_(x)Zr_(1-x)Se_(2) decreases monotonically, and the electronic system undergoes a transition from a semiconducting to a metallic state without a significant variation of dispersions of valence bands. Meanwhile, the size of spin-orbit splitting dominated by Se 4p orbitals decreases with the increase of Ti doping. Our work shows a convenient way to alter the bandgap and spin-orbit coupling in TMDCs at the low level of substitution of transition metals.
基金support from the National Key R&D Program of China(No.2017YFA0402901)the National Natural Science Foundation of China(Nos.U2032153,21727801,and 11621063)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB25000000)the International Partnership Program of Chinese Academy of Sciences(CAS)(No.211134KYSB20190063)the Collaborative Innovation Program of Hefei Science Center of CAS(No.2019HSC-CIP007).
文摘Charge density wave(CDW)is a phenomenon that occurs in materials,accompanied by changes in their intrinsic electronic properties.The study of CDW and its modulation in materials holds tremendous significance in materials research,as it provides a unique approach to controlling the electronic properties of materials.TiSe_(2) is a typical layered material with a CDW phase at low temperatures.Through V substitution for Ti in TiSe_(2),we tuned the carrier concentration in V_(x)Ti_(1-x)Se_(2) to study how its electronic structures evolve.Angle-resolved photoemission spectroscopy(ARPES)shows that the band-folding effect is sustained with the doping level up to 10%,indicating the persistence of the CDW phase,even though the band structure is strikingly different from that of the parent compound TiSe_(2).Though CDW can induce the band fold effect with a driving force from the perspective of electronic systems,our studies suggest that this behavior could be maintained by lattice distortion of the CDW phase,even if band structures deviate from the electron-driven CDW scenario.Our work provides a constraint for understanding the CDW mechanism in TiSe_(2),and highlights the role of lattice distortion in the band-folding effect.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB29040201)the National Natural Science Foundation of China(NSFC)(81901680)。
基金We acknowledge the financial support from the National Key R&D Program of China(No.2017YFA0402901,2016YFA0401004)National Natural Science Foundation of China(No.11674296,21727801 and 11621063)+1 种基金the Key Research Program of the Chinese Academy of Sciences(No.XDPB01)the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(No.2018CXFX002),NSFC-MAECI(51861135202).
文摘The intercalation of metal is a promising method for the modulating electronic properties in transition metal dichalcogenides(TMDs).However,there still lacks enough knowledge about how the intercalated atoms directly impact the two-dimensional structural layers and modulate the band structures therein.Taking advantage of X-ray absorption fine structure and angle-resolved photoemission spectroscopy,we studied how Cu intercalation influences the host TaSe2 layers in Cu0.03TaSe2 crystals.The intercalated Cu atoms form bonds with Se of the host layers,and there is charge transfer from Cu to Se.By examining the changes of band dispersions,we show that the variation of electronic structures is beyond a simple rigid band model with merely charge doping effect.This work'reveals that the unusual change of band dispersions is associated with the formation of bonds between the intercalated metal elements and anion ions in the host layers,and provides a reference for the comprehensive understanding of the electronic structures in intercalated materials.
基金supported by the National Natural Science Foundation of China(U1832142)the National Key R&D Program of China(2018YFB0703602)+3 种基金the Youth Innovation Promotion Association CAS(Y202092)the Fundamental Research Funds for the Central University(WK2340000094)China Postdoctoral Science Foundation(2019TQ0293,2020M671868)the National Synchrotron Radiation Laboratory Joint funds of University of Science and Technology of China(KY2340000114)。
文摘The two-dimensional(2 D)structure often leads to unusual phenomena for the impact of confined mean free path of carrier scattering.As a quasi-2 D layered material,Ag CrSe_(2)has a liquid-like phonon behavior for its unstable Ag atoms at service temperature,leading to the promising candidate for thermoelectricity and fast ionic conductor.However,the inferior electronic performance constrains its application prospects as a functional semiconductor,which provides broad opportunity to tune its electric behaviors by defect chemistry.In this work,we revealed abundant electric transport behaviors of Ag CrSe_(2)with different types of intrinsic defects.For example,the Ag CrSe_(2)changes from Anderson insulator to metal when Se defects become prevailing and the magnetoresistance alters its sign depending on the relative ratio of Ag and Cr defects.Our results reported here can give salutary boosting on regulating the electric properties of ternary transition metal selenide by defect chemistry.