Ce_(2)Fe_(17)N_(3-δ)composites have always been focused on electromagnetic wave(EMW)absorbing field because of their high resonance frequency and magnetic loss.However,the issues of preparation cost and impedance mis...Ce_(2)Fe_(17)N_(3-δ)composites have always been focused on electromagnetic wave(EMW)absorbing field because of their high resonance frequency and magnetic loss.However,the issues of preparation cost and impedance mismatching still limit the industrial conversion and practical application of Ce_(2)Fe_(17)N_(3-δ)composites.In this work,the composites of Ce_(2)Fe_(17)N_(3-δ)with a phosphate insulation layer(Ce_(2)Fe_(17)N_(3-δ)@FePO_(4))were prepared by a newly-developed reduction-diffusion(R/D)and phosphating processes using CeO_(2) as raw mate rials,and their microwave absorption properties were investigated.The composite filled with 30 vol%of the Ce_(2)Fe_(17)N_(3-δ)@FePO_(4) has a minimum reflection loss(RL)of-63 dB and an effective absorption bandwidth(EBW,RL<-10 dB)of 3.83 GHz at a thickness of 1.25 mm in the X-band,and the EBW reaches 5 GHz under 0.98 mm in the Ku-band.This study demonstrates that the Ce_(2)Fe_(17)N_(3-δ)@FePO_(4) composite s with low cost and excellent microwave absorption properties have a significant potential for industrial production and practical applications.展开更多
基金Project supported by the National Key R&D Program of China (2021YFB3501302)the National Natural Science Foundation of China (51731001)the State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization's Key Research and Development Projects。
文摘Ce_(2)Fe_(17)N_(3-δ)composites have always been focused on electromagnetic wave(EMW)absorbing field because of their high resonance frequency and magnetic loss.However,the issues of preparation cost and impedance mismatching still limit the industrial conversion and practical application of Ce_(2)Fe_(17)N_(3-δ)composites.In this work,the composites of Ce_(2)Fe_(17)N_(3-δ)with a phosphate insulation layer(Ce_(2)Fe_(17)N_(3-δ)@FePO_(4))were prepared by a newly-developed reduction-diffusion(R/D)and phosphating processes using CeO_(2) as raw mate rials,and their microwave absorption properties were investigated.The composite filled with 30 vol%of the Ce_(2)Fe_(17)N_(3-δ)@FePO_(4) has a minimum reflection loss(RL)of-63 dB and an effective absorption bandwidth(EBW,RL<-10 dB)of 3.83 GHz at a thickness of 1.25 mm in the X-band,and the EBW reaches 5 GHz under 0.98 mm in the Ku-band.This study demonstrates that the Ce_(2)Fe_(17)N_(3-δ)@FePO_(4) composite s with low cost and excellent microwave absorption properties have a significant potential for industrial production and practical applications.
