Emission thermal quenching is commonly observed in quasi-2D perovskite emitters,which causes the severe drop in luminescence eficiency for the quasi-2D perovskite light-emitting diodes(Pel EDs)during practical operati...Emission thermal quenching is commonly observed in quasi-2D perovskite emitters,which causes the severe drop in luminescence eficiency for the quasi-2D perovskite light-emitting diodes(Pel EDs)during practical operations.However,this issue is often neglected and rarely studied,and the root cause of the thermal quenching has not been completely revealed now.Here,we develop a passivation strategy via the 2,7-dibromo-9,9-bis(3'-diethoxylphosphorylpropyl-fluorene to investigate and suppress the thermal quenching.The agent can effectively passivate coordination-unsaturated Pb2+defects of both surface and bulk of the flm without affecting the perovskite crysaliation,which helps to more truly demonstrate the important role of defects in thermal quenching.And our results reveal the root cause that the quenching will be strengthened by the defect promoted exciton-phonon coupling.Ultimately,the PeL EDs with defect passivation achieve an improved external quantum efficiengy(EQE)over 22%and doubled operation lifetime at room temperature,and can maintain about 85%of the initial EQE at 85℃,much higher than 17%of the control device.These findings provide an important basis for fabricating practical PeLEDs for lighting and displays.展开更多
基金the National Natural Science Foundation of China(No.22075277,22109156)the China Postdoctoral Science Foundation(2021M703129).
文摘Emission thermal quenching is commonly observed in quasi-2D perovskite emitters,which causes the severe drop in luminescence eficiency for the quasi-2D perovskite light-emitting diodes(Pel EDs)during practical operations.However,this issue is often neglected and rarely studied,and the root cause of the thermal quenching has not been completely revealed now.Here,we develop a passivation strategy via the 2,7-dibromo-9,9-bis(3'-diethoxylphosphorylpropyl-fluorene to investigate and suppress the thermal quenching.The agent can effectively passivate coordination-unsaturated Pb2+defects of both surface and bulk of the flm without affecting the perovskite crysaliation,which helps to more truly demonstrate the important role of defects in thermal quenching.And our results reveal the root cause that the quenching will be strengthened by the defect promoted exciton-phonon coupling.Ultimately,the PeL EDs with defect passivation achieve an improved external quantum efficiengy(EQE)over 22%and doubled operation lifetime at room temperature,and can maintain about 85%of the initial EQE at 85℃,much higher than 17%of the control device.These findings provide an important basis for fabricating practical PeLEDs for lighting and displays.
