The catalytic hydrogenation of 2-nitro-4-acetylamino anisole(NMA)is a less-polluting and efficient method to produce 2-amino-4-acetamino anisole(AMA).However,the kinetics of catalytic hydrogenation of NMA to AMA remai...The catalytic hydrogenation of 2-nitro-4-acetylamino anisole(NMA)is a less-polluting and efficient method to produce 2-amino-4-acetamino anisole(AMA).However,the kinetics of catalytic hydrogenation of NMA to AMA remains obscure.In this work,the kinetic models including power-law model and Langmuir-Hinshelwood-Hougen-Watson(LHHW)model of NMA hydrogenation to AMA catalyzed by Raney nickel catalyst were investigated.All experiments were carried out under the elimination of mass transfer resistance within the temperature range of 70–100°C and the hydrogen pressure of 0.8–1.5 MPa.The reaction was found to follow 0.52-order kinetics with respect to the NMA concentration and 1.10-order kinetics in terms of hydrogen pressure.Based on the LHHW model,the dual-site dissociation adsorption of hydrogen was analyzed to be the rate determining step.The research of intrinsic kinetics of NMA to AMA provides the guidance for the reactor design and inspires the catalyst modification.展开更多
Assume that X and Y are real Banach spaces with the same finite dimension.In this paper we show that if a standard coarse isometry f:X→Y satisfies an integral convergence condition or weak stability on a basis,then t...Assume that X and Y are real Banach spaces with the same finite dimension.In this paper we show that if a standard coarse isometry f:X→Y satisfies an integral convergence condition or weak stability on a basis,then there exists a surjective linear isometry U:X→Y such that∥f(x)−Ux∥=o(∥x∥)as∥x∥→∞.This is a generalization about the result of Lindenstrauss and Szankowski on the same finite dimensional Banach spaces without the assumption of surjectivity.As a consequence,we also obtain a stability result forε-isometries which was established by Dilworth.展开更多
基金the National Natural Science Foun-dation of China(22022802 and 22288102).
文摘The catalytic hydrogenation of 2-nitro-4-acetylamino anisole(NMA)is a less-polluting and efficient method to produce 2-amino-4-acetamino anisole(AMA).However,the kinetics of catalytic hydrogenation of NMA to AMA remains obscure.In this work,the kinetic models including power-law model and Langmuir-Hinshelwood-Hougen-Watson(LHHW)model of NMA hydrogenation to AMA catalyzed by Raney nickel catalyst were investigated.All experiments were carried out under the elimination of mass transfer resistance within the temperature range of 70–100°C and the hydrogen pressure of 0.8–1.5 MPa.The reaction was found to follow 0.52-order kinetics with respect to the NMA concentration and 1.10-order kinetics in terms of hydrogen pressure.Based on the LHHW model,the dual-site dissociation adsorption of hydrogen was analyzed to be the rate determining step.The research of intrinsic kinetics of NMA to AMA provides the guidance for the reactor design and inspires the catalyst modification.
基金Supported by National Natural Science Foundation of China(11731010 and 12071388)。
文摘Assume that X and Y are real Banach spaces with the same finite dimension.In this paper we show that if a standard coarse isometry f:X→Y satisfies an integral convergence condition or weak stability on a basis,then there exists a surjective linear isometry U:X→Y such that∥f(x)−Ux∥=o(∥x∥)as∥x∥→∞.This is a generalization about the result of Lindenstrauss and Szankowski on the same finite dimensional Banach spaces without the assumption of surjectivity.As a consequence,we also obtain a stability result forε-isometries which was established by Dilworth.
